(Meth)acrylate polymers for improving the viscosity index
View Patent ↗The invention relates to a (meth)acrylate polymer for improving the viscosity index, which comprises a) from 5 to 60 wt % of repeating units that are derived from (meth)acrylates of formula (I), where R represents hydrogen or methyl and R1 is an alkyl radical having from 1 to 6 carbon atoms, b) from 5 to 80 wt % of repeating units that are derived from (meth)acrylates of formula (II), where R is hydrogen or methyl and R2 is an alkyl radical having from 7 to 30 carbon atoms, and c) from 15 to 90 wt % of repeating units that are derived from (meth)acrylates of formula (III), where R is hydrogen or methyl, n is an integer in the range of 2 to 500 and A is C2-C4 alkylene and R3 is a hydrogen atom or an alkyl radical having from 1 to 4 carbon atoms. The invention further relates to novel lubricating oil compositions, to a method for producing the above-mentioned (meth)acrylate polymers and to the use thereof for improving the viscosity index of lubricating oil compositions that comprise at least one polar base oil.
1. A (meth)acrylate polymer, comprising:
a) 5% to 60% by weight of a repeating unit derived from at least one (meth)acrylate of formula (I):
wherein R represents hydrogen or methyl, and R 1 represents an alkyl radical having 1 to 6 carbon atoms;
b) 5% to 65% by weight of a repeating unit derived from at least one (meth)acrylate of formula (II):
wherein R represents hydrogen or methyl, and R 2 represents an alkyl radical having 7 to 30 carbon atoms; and
c) 60% to 90% by weight of a repeating unit derived from at least one (meth)acrylate of formula (III):
wherein R represents hydrogen or methyl, n represents a number in the range from 2 to 500, A represents C 2 -C 4 alkylene, and R 3 represents a hydrogen atom or an alkyl radical having 1 to 4 carbon atoms.
2. The (meth)acrylate polymer of claim 1 , comprising a repeating unit derived from at least one dispersing monomer selected from the group consisting of a heterocyclic vinyl compound, an aminoalkyl (meth)acrylate, an aminoalkyl(meth)acrylamide, and a heterocyclic (meth)acrylate.
3. The (meth)acrylate polymer of claim 1 , comprising 0.5% to 10% by weight of a repeating unit derived from at least one dispersing monomer.
4. The (meth)acrylate polymer of claim 1 , wherein the repeating unit of formula (III) is ETGMA.
5. The (meth)acrylate polymer of claim 1 , wherein the repeating unit of formula (III) is selected from the group consisting of DMAPMA, DMAEMA, MOEMA and OEMA.
6. A lubricating oil composition, comprising:
a polar base oil comprising a polyalkylene glycol and the (meth)acrylate polymer of claim 1 .
7. The (meth)acrylate polymer of claim 1 , having a weight average molecular weight of from 40,000 to 100,000 g/mol.
8. A (meth)acrylate polymer, comprising:
a) 20% to 30% by weight of a repeating unit derived from at least one (meth)acrylate of formula (I):
wherein R represents hydrogen or methyl, and R 1 represents an alkyl radical having 1 carbon atom;
b) 20% to 60% by weight of a repeating unit derived from at least one (meth)acrylate of formula (II):
wherein R represents hydrogen or methyl, and R 2 represents an alkyl radical having 7 to 30 carbon atoms; and
c) 30% to 60% by weight of a repeating unit derived from at least one (meth)acrylate of formula (III):
wherein R represents hydrogen or methyl, n represents a number in the range from 2 to 500, A represents C 2 -C 4 alkylene, and R 3 represents a hydrogen atom or an alkyl radical having 1 to 4 carbon atoms.
9. The (meth)acrylate polymer of claim 8 , comprising a repeating unit derived from at least one dispersing monomer selected from the group consisting of a heterocyclic vinyl compound, an aminoalkyl (meth)acrylate, an aminoalkyl(meth)acrylamide, and a heterocyclic (meth)acrylate.
10. The (meth)acrylate polymer of claim 8 , comprising 0.5% to 10% by weight of a repeating unit derived from at least one dispersing monomer.
11. A lubricating oil composition, comprising a polar base oil and 1% to 30% by weight of the (meth)acrylate polymer of claim 8 .
12. The lubricating oil composition of claim 11 , wherein the polar base oil comprises a polyalkylene glycol.
13. The (meth)acrylate polymer of claim 8 , wherein the repeating unit of formula (III) is selected from the group consisting of ETGMA.
14. The (meth)acrylate polymer of claim 9 , wherein the repeating unit derived from at least one dispersing monomer is selected from the group consisting of DMAPMA, DMAEMA, MOEMA and OEMA.
15. The (meth)acrylate polymer of claim 8 , having a weight average molecular weight of from 40,000 to 100,000 g/mol.
16. A lubricating oil composition, comprising:
a polar base oil comprising a polyalkylene glycol and the (meth)acrylate polymer of claim 8 .