Concentrated storage-stable aqueous optical brightening solutions
View Patent ↗Concentrated storage stable aqueous solutions (S) comprising components (a), (b) and (c), wherein component (a) is at least one optical brightening agent of formula (1), in which the anionic charge on the brightener is balanced by a cationic charge composed of one or more cations selected from the group consisting of hydrogen, alkali metal cation, alkaline earth metal cation, ammonium, ammonium which is mono-, di- or trisubstituted by a C 1-4 linear or branched alkyl radical and ammonium which is mono-, di- or trisubstituted by a C 1-4 linear or branched hydroxyalkyl radical, and the concentration of component (a) is 0.08 to 0.3 mol per kg, based on the total weight of the concentrated storage-stable aqueous solutions (S), component (b) is at least one inorganic salt (SA), in a concentration of 2 to 15% by weight, based on the total weight of the concentrated storage-stable aqueous solutions (S), and component (c) is water, in a concentration of 10% to 88% by weight, based on the total weight of the concentrated storage-stable aqueous solutions (S).
1. A concentrated storage-stable aqueous solution (S) comprising components (a), (b) and (c),
wherein
component (a) is at least one optical brightening agent of formula (1),
wherein
the anionic charge on the optical brightening agent is balanced by a cationic charge composed of one or more cations selected from the group consisting of hydrogen, alkali metal cation, alkaline earth metal cation, ammonium, ammonium which is mono-, di- or trisubstituted by a C 1-4 linear or branched alkyl radical and ammonium which is mono-, di- or trisubstituted by a C 1-4 linear or branched hydroxyalkyl radical,
and
the concentration of component (a) is 0.08 to 0.3 mol per kg, based on the total weight of the concentrated storage-stable aqueous solution (S),
component (b) is at least one inorganic salt (SA), in a concentration of 2 to 15% by weight, based on the total weight of the concentrated storage-stable aqueous solution (S),
and
component (c) is water, in a concentration of 10% to 88% by weight, based on the total weight of the concentrated storage-stable aqueous solution (S).,
wherein the concentrated storage-stable aqueous solution (S) shows no precipitation after two weeks at 5° C.
2. The concentrated storage-stable aqueous solution (S) according to claim 1 , further comprising polyethyleneglycol in an amount of 2 to 40% by weight, %, based on the total weight of the concentrated storage-stable aqueous solution (S).
3. The concentrated storage-stable aqueous solution (S) according to claim 1 , further comprising polyvinylalcohol in an amount of from 0.01 to 10% by weight, based on the total weight of the concentrated storage-stable aqueous solution (S).
4. The concentrated storage-stable aqueous solution (S) according to claim 1 , wherein the anionic charge on the optical brightening agent of formula (1) is balanced by a cationic charge composed of one or more cations selected from the group consisting of Li +, Na +, K +, Ca 2 +, Mg 2 + and ammonium which is mono-, di- or trisubstituted by a C 1-4 linear or branched hydroxyalkyl radical.
5. The concentrated storage-stable aqueous solution (S) according to claim 1 , wherein the concentration of component (a) is 0.08 to 0.2 mol per kg of concentrated storage-stable aqueous solution (S).
6. The concentrated storage-stable aqueous solution (S) according to claim 1 , wherein the concentration of the inorganic salt (SA)/component (b) is 2.5 to 14% by weight, based on the total weight of the concentrated aqueous solution (S) and that the salts (SA) are the by-products of the manufacturing process.
7. The concentrated storage-stable aqueous solution (S) according to claim 1 , wherein the at least one inorganic salt (SA) is an alkali metal salt, alkaline earth metal salts or a combination thereof.
8. A process for the preparation of a concentrated storage-stable aqueous solution (S) according to claim 1 , comprising the stepwise reaction of a cyanuric halide with
a) an amine of formula (2)
in the free acid, partial- or full salt form,
(b) a diamine of formula (3)
in the free acid, partial- or full salt form,
and
c) a di-n-propylamine of formula (4),
in the presence of water and using a base (B).
9. The process according to claim 8 , wherein the cyanuric halide is fluoride, chloride or bromide.
10. The process according to claim 8 , wherein the cyanuric halide is suspended in water, or in an aqueous/organic medium.
11. The process according to claim 8 , wherein the aromatic amines (2) and (3) are reacted stoichiometrically or in slight excess and the di-n-propylamine (4) is employed in an excess of 0.1-30% over stoichiometry.
12. The process according to claim 8 , wherein the first reaction step is carried out at a temperature in the range from 0 to 20° C., the second reaction step is carried out at a temperature in the range from 20 to 60° C. and the third reaction step is carried out at a temperature in the range from 60 to 102° C.
13. The process according to claim 1 , wherein the first reaction step is carried out under acidic to neutral conditions, the second reaction step is carried out under weakly acidic to weakly alkaline conditions and the third reaction step is carried out under weakly acidic to alkaline conditions.
14. The process according to claim 8 , wherein the base (B) is an alkali metal, alkaline earth metal hydroxide, carbonate, bicarbonate, an aliphatic tertiary amine or a combination thereof.
15. A brightened cellulosic substrate, textile or non-woven material brightened by the concentrated storage stable solution as claimed in claim 1 .
16. The brightened cellulosic substrate, textile or non woven material according to claim 15 , wherein the concentrated storage stable solution (S) is employed in an amount of 0.01 to 2.5% by weight based on the weight of the cellulosic substrate, textile or non-woven material.
17. A method for the treatment of paper in size-press, sizing solutions or suspensions comprising applying a concentrated storage stable solution as claimed in claim 1 in a concentration of 0.5 to 125 grams per liter of sizing solution or suspension.
18. A sizing solution or suspension for the treatment of paper, comprising a concentrated storage-stable solution (S) according to claim 1 .
19. The sizing solution or suspension according to claim 18 , wherein the concentrated storage stable solution solution (S) is contained in a concentration of 0.5 to 125 grams per liter of sizing solution or suspension.
20. The sizing solution according to claim 18 , further comprising one or more binding agents, selected from the following group consisting of: native starch, enzymatically modified starch, chemically modified starch or-and mixtures thereof.
21. The sizing solution according to claim 18 , further comprising a divalent metal salt or a mixture of divalent metal salts, which are different from the salt (SA).
22. The sizing solution according to claim 18 , further comprising one or more binders, water and optionally other optical brighteners, which are structurally different from formula (1).
23. Pigmented coating composition comprising a concentrated storage-stable solution (S) according to claim 1 .
24. The concentrated storage-stable aqueous solution (S) according to claim 1 , wherein the concentration of component (a) is 0.09 to 0.18 mol per kg of concentrated storage-stable aqueous solution (S).
25. The concentrated storage-stable aqueous solution (S) according to claim 1 , wherein the concentration of the inorganic salt (SA)/component (b) is 2.5 to 12% by weight based on the total weight of the concentrated aqueous solution (S) and that the salts (SA) are the by-products of the manufacturing process.
26. The concentrated storage-stable aqueous solution (S) according to claim 1 , wherein the at least one inorganic salt (SA) is a lithium, sodium, potassium, calcium, or magnesium salt, or a mixture of said compounds.