Faujasite zeolite preparation process
View Patent ↗Disclosed is a process for the preparation of a faujasite zeolite. A starting zeolite of the faujasite structure having a silica to alumina ratio of from 4.5 to 6.5 and an alkali level of less than 1.5% wt is steam calcined to produce an intermediate zeolite. The intermediate zeolite is treated with an acidified solution having specificately defined characteristics.
1. A process for the preparation of a zeolite having a unit cell size in the range of from 24.42 to 24.52 Å; a bulk silica to alumina molar ratio (SAR) in the range of from 10 to 15; and a surface area of from 910 to 1020 m 2 /g, which process comprises:
a) providing a starting zeolite of the faujasite structure having a silica to alumina ratio of from 4.5 to 6.5 and an alkali level of less than 1.5% wt;
b) steam calcination by treating said starting zeolite at a temperature in the range of from 550 to 750° C. and at a partial pressure of steam in the range of from 5 to 50 vol %, basis total gas present, for a time effective to produce an intermediate zeolite having a unit cell size of from 24.40 to 24.50 Å;
c) contacting the intermediate zeolite with an acidified solution comprising of from 4 to 9 mmole of acid having a pKa below 0 per gram of zeolite and optionally an ammonium salt under conditions effective to produce a zeolite having a unit cell size in the range of from 24.42 Å to 24.52 Å; a SAR in the range of from 10 to 15; and a surface area of from 910 to 1020 m 2 /g; and
d) recovering said zeolite.
2. A process as claimed in claim 1 , wherein the intermediate zeolite obtained in step b) is treated with an ammonium salt containing aqueous solution before being contacted with the acidified solution of c).
3. A Process for preparing a hydrocracking catalyst carrier composition, which process comprises:
(i) preparing a faujasite zeolite by a process as claimed in claim 2 , and
(ii) mixing the zeolite with amorphous binder component.
4. A process for preparing a hydrocracking catalyst composition which process comprises preparing a catalyst carrier composition according to claim 3 , and further
(iii) incorporating at least one hydrogenation component.
5. A process for converting a hydrocarbonaceous feedstock into lower boiling materials, which comprises contacting the feedstock at elevated temperature and pressure with a hydrocracking catalyst composition obtained in a process as claimed in claim 4 .
6. A process as claimed in claim 1 , wherein the zeolite obtained in step c) is treated with an ammonium salt containing aqueous solution, and optionally washed and dried.
7. A Process for preparing a hydrocracking catalyst carrier composition, which process comprises:
(i) preparing a faujasite zeolite by a process as claimed in claim 6 , and
(ii) mixing the zeolite with amorphous binder component.
8. A process for preparing a hydrocracking catalyst composition which process comprises preparing a catalyst carrier composition according to claim 7 , and further
(iii) incorporating at least one hydrogenation component.
9. A process for converting a hydrocarbonaceous feedstock into lower boiling materials, which comprises contacting the feedstock at elevated temperature and pressure with a hydrocracking catalyst composition obtained in a process as claimed in claim 8 .
10. A process as claimed in any one of claim 1 , wherein the amount of acid having a pKa below 0 is of from 5 to 8 mmole per gram of zeolite.
11. A Process for preparing a hydrocracking catalyst carrier composition, which process comprises:
(i) preparing a faujasite zeolite by a process as claimed in claim 10 , and
(ii) mixing the zeolite with amorphous binder component.
12. A process for preparing a hydrocracking catalyst composition which process comprises preparing a catalyst carrier composition according to claim 11 , and further
(iii) incorporating at least one hydrogenation component.
13. A process for converting a hydrocarbonaceous feedstock into lower boiling materials, which comprises contacting the feedstock at elevated temperature and pressure with a hydrocracking catalyst composition obtained in a process as claimed in claim 12 .
14. A process as claimed in any one of claim 1 , wherein the pH of the acidified solution is at most 4.
15. A Process for preparing a hydrocracking catalyst carrier composition, which process comprises:
(i) preparing a faujasite zeolite by a process as claimed in claim 14 , and
(ii) mixing the zeolite with amorphous binder component.
16. A process for preparing a hydrocracking catalyst composition which process comprises preparing a catalyst carrier composition according to claim 15 , and further
(iii) incorporating at least one hydrogenation component.
17. A process for converting a hydrocarbonaceous feedstock into lower boiling materials, which comprises contacting the feedstock at elevated temperature and pressure with a hydrocracking catalyst composition obtained in a process as claimed in claim 16 .
18. A process for preparing a hydrocracking catalyst carrier composition, which process comprises:
(i) preparing a faujasite zeolite by a process as claimed in claim 1 , and
(ii) mixing the zeolite with amorphous binder component.
19. A process for preparing a hydrocracking catalyst composition which process comprises preparing a catalyst carrier composition according to claim 18 , and further
(iii) incorporating at least one hydrogenation component.
20. A process for converting a hydrocarbonaceous feedstock into lower boiling materials, which comprises contacting the feedstock at elevated temperature and pressure with a hydrocracking catalyst composition obtained in a process as claimed in claim 19 .