Process for the preparation of indium chlordialkoxides
View Patent ↗The present invention relates to a process for the preparation of indium(III) halodialkoxides of the generic formula InX(OR) 2 where X=F, Cl, Br, I and R=alkyl radical, alkoxyalkyl radical, in which a composition (A) comprising an indium trihalide InX 3 , where X=F, Cl, Br and/or I, and at least one alcohol of the generic formula ROH, where R=alkyl radical, alkyloxyalkyl radical, is reacted with a composition (B) comprising at least one secondary amine of the generic formula R′ 2 NH, where R′=alkyl radical, to the indium(III) halodialkoxides which can be prepared by the process and to their use.
1. A process for preparing an indium(III) halodialkoxide, the process comprising:
reacting a composition (A) with a composition (B) to obtain the indium (III) halodialkoxide,
wherein the indium (III) halodialkoxide is of formula:
InX(OR) 2
each X is independently F, Cl, Br, or I,
R is an alkyl radicalor an alkyloxyalkyl radical, the composition (A) comprises an indium trihalide of formula InX 3 and an alcohol of formula ROH,
the composition (B) comprises a secondary amine of formula R′ 2 NH, and
R′ is an alkyl radical.
2. The process of claim 1 , wherein the indium trihalide is selected from the group consisting of InF 3 , InCl 3 , InBr 3 , and InI 3 .
3. The process of claim 1 , wherein a proportion of the indium trihalide is from 0.1 to 50% by weight, based on a total mass of the composition (A).
4. The process of claim 1 , wherein R in the alcohol is a C 1 - to C 15 -alkyl radical or a C 1 - to C 15 -alkoxyalkyl radical.
5. The process of claim 1 , wherein a proportion of the alcohol is from 50 to 99.9% by weight, based on a total mass of the composition (A).
6. The process of claim 1 , wherein the composition (A) further comprises a liquid solvent or a dispersing medium which is inert with respect to the reacting.
7. The process of claim 1 , wherein each R′ is a C 1 -C 10 -alkyl.
8. The process of claim 1 , wherein a stoichiometric amount of the secondary amine is at least twice a stoichiometric amount of the indium trihalide.
9. A process for producing an indium oxide-containing coating, the process comprising preparing an indium (III) halodialkoxide according to the process of claim 1 ;
applying a composition comprising said indium (III) halodialkoxide to a substrate to form a coating film;
treating said coating film with UV radiation; and
thermally converting said coating film to produce an indium oxide-containing coating.
10. The process of claim 1 , wherein the composition (A) comprises only one alcohol.
11. The process of claim 1 , wherein each R is independently selected from the group consisting of —CH 3 , —CH 2 CH 3 , —CH 2 CH 2 OCH 3 , —CH(CH 3 ) 2 and —C(CH 3 ) 3 .
12. The process of claim 5 , wherein the proportion of the alcohol is from 75% to 99% by weight.
13. The process of claim 6 , wherein the liquid solvent or dispersing medium comprises an aprotic solvent.
14. The process of claim 1 , wherein a temperature of the reacting is from 25 to 250° C.