POLYURETHANE DISPERSIONS FOR SEALING THE TEATS OF THE MAMMARY GLANDS IN MILKING ANIMALS
The present invention relates to aqueous polyurethane dispersions for sealing teats of animal mammary glands.
1 - 15 . (canceled)
16 . An aqueous polyurethane dispersion for sealing teats of animal mammary glands.
17 . The aqueous polyurethane dispersion of claim 16 , wherein the polyurethane dispersion is anionically and/or nonionically hydrophilized.
18 . The aqueous polyurethane dispersion of claim 16 , wherein the polyurethane dispersion is obtained by preparing
A) isocyanate-functional prepolymers from
A1) organic polyisocyanates,
A2) polymeric polyols having number-average molecular weights of 400 to 8000 g/mol, and OH functionalities of 1.5 to 6, and
A3) optionally hydroxy-functional compounds having molecular weights of 62 to 399 g/mol, and also
A4) optionally isocyanate-reactive, anionic or potentially anionic and/or optionally nonionic hydrophilizing agents, and
B) then reacting some or all of the free NCO groups of said prepolymers
B1) optionally with amino-functional compounds having molecular weights of 32 to 400 g/mol and
B2) with amino-functional, anionic or potentially anionic hydrophilizing agents with chain extension, and dispersing the prepolymers in water before, during or after step B).
19 . The aqueous polyurethane dispersion of claim 18 , wherein components A1) to A4) and B1) to B2) are used in the following amounts, wherein the sum of the individual amounts total 100% by weight:
from 5% to 40% by weight of component A1),
from 55% to 90% by weight of A2),
from 0.5% to 20% by weight of the sum of components A3) and B1), and
from 0.1% to 25% by weight of the sum of components A4) and B2),
and using, based on the total amounts of components A1) to A4) and B1) to B2), 0.1% to 5% by weight of anionic and/or potentionally anionic hydrophilizing agents from A4) and/or B2).
20 . The aqueous polyurethane dispersion of claim 16 , wherein the number-average particle size of the particles in the polyurethane dispersions, as determined by means of laser correlation spectroscopy, is less than 750 nm.
21 . The aqueous polyurethane dispersion of claim 16 , wherein the polyurethane dispersion has solids contents of 10% to 70% by weight, based on the polyurethane contained therein.
22 . The aqueous polyurethane dispersion of claim 16 , wherein the polyurethane dispersion contains less than 5% by weight, based on the total dispersion, of unbound organic amines.
23 . The aqueous polyurethane dispersion of claim 16 , wherein there are no volatile amines and no ammonia in the polyurethane dispersion.
24 . The aqueous polyurethane dispersion of claim 16 , wherein in the polyurethane dispersion there is less than 2% by weight of organic solvents.
25 . The aqueous polyurethane dispersion of claim 16 , wherein there is at least one active biocidal ingredient in the polyurethane dispersion.
26 . The aqueous polyurethane dispersion of claim 16 , wherein the active biocidal ingredient is pesticidal, fungicidal, algicidal, insecticidal, herbicidal, spermicidal, parasiticidal, antibacterial, bacteriostatic, antibiotic, antimycotic, antiviral, virostatic and/or antimicrobial.
27 . The aqueous polyurethane dispersion of claim 16 , wherein the coating is applied to teats of the udder of dairy cows.
28 . The aqueous polyurethane dispersion of claim 27 , wherein the polyurethane dispersion is applied to the teats during the dry phase of the dairy cows.
29 . The aqueous polyurethane dispersion of claim 18 , wherein A2) are polymeric polyols having number-average molecular weights of 400 to 6000 g/mol, and OH functionalities of 1.8 to 3.
30 . The aqueous polyurethane dispersion of claim 18 , wherein A2) are polymeric polyols having number-average molecular weights of 600 to 3000 g/mol, and OH functionalities of 1.9 to 2.1.
31 . The aqueous polyurethane dispersion of claim 20 , wherein the number-average particle size of the particles in the polyurethane dispersions, as determined by means of laser correlation spectroscopy, is less than 500 nm.
32 . The aqueous polyurethane dispersion of claim 21 , wherein the polyurethane dispersion has solids contents of 30% to 70% by weight, based on the polyurethane contained therein.
33 . The aqueous polyurethane dispersion of claim 21 , wherein the polyurethane dispersion has solids contents of 30% to 65% by weight, based on the polyurethane contained therein.
34 . The aqueous polyurethane dispersion of claim 22 , wherein the polyurethane dispersion contains less than 0.2% by weight, based on the total dispersion, of unbound organic amines.
35 . The aqueous polyurethane dispersion of claim 24 , wherein in the polyurethane dispersion there is less than 1.5% by weight of organic solvents.
36 . The aqueous polyurethane dispersion of claim 24 , wherein in the polyurethane dispersion there is less than 1% by weight of organic solvents.
37 . The aqueous polyurethane dispersion of claim 24 , wherein in the polyurethane dispersion there is less than 0.5% by weight of organic solvents.