Polarizing plate, method for producing same and image display device comprising same
The present invention relates to a polarizing plate, a method for producing the same, and an image display device comprising the same, and more specifically to a polarizing plate which is characterized by comprising: a) a polarizer, b) a hardening resin layer which is provided on at least one side of the polarizer and formed from a photocurable composition comprising: 4 to 95 parts by weight of (A) a photocurable acrylic polymer, 4 to 95 parts by weight of (B) a poly-functional acrylic monomer, and 1 to 20 parts by weight of (C) a photo-polymerization initiator, based on 100 parts by weight of the photocurable composition, a method for manufacturing the same, and an image display device using the same. According to the present invention, a polarizing plate, which exhibits excellent polarizing properties and durability, has high surface hardness, and may be formed as a thin plate, may be provided.
1. A polarizing plate, comprising:
a) a polyvinyl alcohol polarizer and
b) a hardening resin layer which is provided on at least one side of the polyvinyl alcohol polarizer and formed from a photocurable composition comprising: 4 to 95 parts by weight of (A) a photocurable acrylic polymer, 4 to 95 parts by weight of (B) a poly-functional acrylic monomer, and 1 to 20 parts by weight of (C) a photo-polymerization initiator, based on 100 parts by weight of the photocurable composition,
wherein (A) the photocurable acrylic polymer comprises (a) an acrylate-based monomer, (b) an aromatic vinyl-based monomer, (c) an N-substituted maleimide-based monomer, and an acryloyl functional group,
wherein (A) the photocurable acrylic polymer comprises 30 to 98 parts by weight of (a) the acrylate-based monomer based on 100 parts by weight of (A) the photocurable acrylic polymer,
wherein (A) the photocurable acrylic polymer comprises 1 to 30 parts by weight of (b) the aromatic vinyl-based monomer based on 100 parts by weight of (A) the photocurable acrylic polymer, and
wherein (A) the photocurable acrylic polymer comprises 1 to 40 parts by weight of (c) the N-substituted maleimide-based monomer based on 100 parts by weight of (A) the photocurable acrylic polymer.
2. The polarizing plate of claim 1 , wherein the hardening resin layer is formed from 4 to 90 parts by weight of (A) a photocurable acrylic polymer, 4 to 90 parts by weight of (B) a poly-functional acrylic monomer, and 1 to 20 parts by weight of (C) a photo-polymerization initiator, and 0 to 50 parts by weight of (D) a photocurable oligomer based on 100 parts by weight of the photocurable composition.
3. The polarizing plate of claim 2 , wherein (D) the photocurable oligomer has a weight average molecular weight of 1,000 g/mol to 100,000 g/mol.
4. The polarizing plate of claim 1 , wherein (A) the photocurable acrylic polymer has a weight average molecular weight of 10,000 g/mol to 200,000 g/mol.
5. The polarizing plate of claim 1 , wherein (A) the photocurable acrylic polymer comprises 5 to 90 parts by weight of the acryloyl functional group based on 100 parts by weight of the (A) photocurable acrylic polymer.
6. The polarizing plate of claim 1 , wherein (a) the acrylate-based monomer is selected from the group consisting of alkyl acrylate, alkyl methacrylate, and mixtures thereof.
7. The polarizing plate of claim 1 , wherein (b) the aromatic vinyl-based monomer is selected from the group consisting of styrene, methyl styrene, and mixtures thereof.
8. The polarizing plate of claim 1 , wherein (c) the N-substituted maleimide-based monomer is selected from the group consisting of N-methyl maleimide, N-ethyl maleimide, N-n-propyl maleimide, N-isopropyl maleimide, N-n-butyl maleimide, N-s-maleimide, N-t-maleimide, N-n-hexyl maleimide, N-n-dodecyl maleimide, N-allyl maleimide, N-benzyl maleimide, N-cyclohexyl maleimide, N-phenyl maleimide, N-nitrophenyl maleimide, N-hydroxymaleimide, N-methoxymaleimide, N-ethoxymaleimide, N-monochlorophenyl maleimide, N-dichlorophenyl maleimide, N-monomethylphenyl maleimide, N-dimethylphenyl maleimide, and N-ethylphenyl maleimide.
9. The polarizing plate of claim 1 , wherein (c) the N-substituted maleimide-based monomer is selected from the group consisting of N-cyclohexyl maleimide and N-phenyl maleimide.
10. The polarizing plate of claim 1 , wherein the polarizing plate has a thickness of 60 μm to 70 μm.
11. The polarizing plate of claim 1 , wherein the polarizing plate further comprises an adhesive layer between the polyvinyl alcohol polarizer and the hardening resin layer.
12. The polarizing plate of claim 1 , wherein the hardening resin layer is formed directly on the polyvinyl alcohol polarizer.
13. An image display device comprising the polarizing plate of claim 1 .
14. A method for manufacturing a polarizing plate, comprising:
a) preparing (A) a photocurable acrylic polymer comprising (a) an acrylate-based monomer, (b) an aromatic vinyl-based monomer, and (c) an N-substituted maleimide-based monomer comprising an acryloyl functional group;
b) preparing a photocurable composition comprising: 4 to 95 parts by weight of (A) the photocurable acrylic polymer, 4 to 95 parts by weight of (B) a poly-functional acrylic monomer, and 1 to 20 parts by weight of (C) a photo-polymerization initiator, based on 100 parts by weight of the photocurable composition; and
c) using the prepared photocurable composition to directly form a hardening resin layer on at least one side of a polyvinyl alcohol polarizer,
wherein (A) the photocurable acrylic polymer comprises 30 to 98 parts by weight of (a) the acrylate-based monomer based on 100 parts by weight of (A) the photocurable acrylic polymer,
wherein (A) the photocurable acrylic polymer comprises 1 to 30 parts by weight of (b) the aromatic vinyl-based monomer based on 100 parts by weight of (A) the photocurable acrylic polymer, and
wherein (A) the photocurable acrylic polymer comprises 1 to 40 parts by weight of (c) the N-substituted maleimide-based monomer based on 100 parts by weight of (A) the photocurable acrylic polymer.
15. A method for manufacturing a polarizing plate, comprising:
a) preparing a photocurable acrylic polymer comprising (A) (a) an acrylate-based monomer, (b) an aromatic vinyl-based monomer, and (c) an N-substituted maleimide-based monomer comprising an acryloyl functional group;
b) preparing a photocurable composition comprising: 4 to 95 parts by weight of (A) the photocurable acrylic polymer, 4 to 95 parts by weight of (B) a poly-functional acrylic monomer, and 1 to 20 parts by weight of (C) a photo-polymerization initiator, based on 100 parts by weight of the photocurable composition; and
c) including an adhesive layer to form a hardening resin layer prepared from the prepared photocurable composition on at least one side of a polyvinyl alcohol polarizer,
wherein (A) the photocurable acrylic polymer comprises 30 to 98 parts by weight of (a) the acrylate-based monomer based on 100 parts by weight of (A) the photocurable acrylic polymer,
wherein (A) the photocurable acrylic polymer comprises 1 to 30 parts by weight of (b) the aromatic vinyl-based monomer based on 100 parts by weight of (A) the photocurable acrylic polymer, and
wherein (A) the photocurable acrylic polymer comprises 1 to 40 parts by weight of (c) the N-substituted maleimide-based monomer based on 100 parts by weight of (A) the photocurable acrylic polymer.