Copolymer having carbosiloxane dendrimer structure, and composition and cosmetic containing the same
The present invention relates to a copolymer having a specified carbosiloxane dendrimer structure and a long-chain alkyl group with 14 to 22 carbon atoms in a specified ratio, and a cosmetic comprising the copolymer as a cosmetic raw material. The cosmetic raw material has good miscibility with other cosmetic raw materials, and therefore, can improve stability of the formulation in a cosmetic, as well as can provide good water resistance, sebum resistance, glossiness, tactile sensation and/or adhesive properties to the hair and/or skin to a cosmetic, and also provide a cosmetic formed by blending the aforementioned cosmetic raw material, which exhibits superior surface protective properties, outer appearance and/or sensation during use.
1. A copolymer of at least,
(A) an unsaturated monomer having a carbosiloxane dendrimer structure represented by the following formula (1):
wherein
Z is a divalent organic group;
p is 0 or 1;
each of R 1 and R 2 independently represents an alkyl group, an aryl group or an aralkyl group, having 1 to 10 carbon atoms; and
L 1 is a silylalkyl group, in the case of i=1, represented by the following formula (2):
wherein
Z and p are the same as defined above;
R 1 and R 2 are the same as defined above;
i is an integer ranging from 1 to 10, which specifies the total number of generations of said silylalkyl group;
L i +1 is a group selected from the group consisting of a hydrogen atom, alkyl, aryl and aralkyl groups, having 1 to 10 carbon atoms and said silylalkyl group, with the proviso that in the case of i =c, in which c is an integer ranging from 1 to 10, and specifies generation of said silylalkyl group, L i+1 is a hydrogen atom, or an alkyl, aryl or aralkyl group, having 1 to 10 carbon atoms; and in the case of i<c, L i+1 is said silylalkyl group; and
a i is an integer ranging from 0 to 3, and
(B) a (C 14-22 alkyl) (meth)acrylate, and
(C) at least two unsaturated monomers having no long-chain alkyl group with 14 to 22 carbon atoms, in addition to components (A) and (B),
wherein the copolymer is obtained by copolymerizing said unsaturated monomer having the carbosiloxane dendrimer structure (A), said (C 14-22 alkyl) (meth)acrylate (B), and said at least two unsaturated monomers having no long-chain alkyl groups with 14 to 22 carbon atoms (C) in a weight ratio satisfying conditions of {(weight of component (A))/(weight of all the monomers)}:{(weight of component (B))/(weight of all the monomers)}:{(weight of component (C))/(weight of all the monomers)} in the range of (0.4 to 0.9):(0.05 to 0.4):(0.05 to 0.65).
2. The copolymer according to claim 1 , wherein said unsaturated monomer having the carbosiloxane dendrimer structure (A) has a group selected from the group consisting of an acryl or methacryl group-containing organic group represented by the following general formula:
wherein R 4 is a hydrogen atom or a methyl group; and R 5 is an alkylene group having 1 to 10 carbon atoms,
or
wherein R 4 and R 5 are the same as defined above,
an alkenylaryl group-containing organic group represented by the following general formula:
wherein R 6 is a hydrogen atom or a methyl group; R 7 is an alkyl group having 1 to 10 carbon atoms; R 8 is an alkylene group having 1 to 10 carbon atoms; b is an integer ranging from 0 to 4; and c is 0 or 1,
and an alkenyl group having 2 to 10 carbon atoms.
3. A copolymer composition comprising the copolymer as recited in claim 1 , in an amount of 100 parts by weight; and at least one oil agent, in an amount of 5 to 1,000 parts by weight.
4. The copolymer composition according to claim 3 , wherein said oil agent is a liquid at 5 to 100° C., and is at least one selected from silicone oils, hydrocarbon oils and fatty acid ester oils.
5. A cosmetic raw material comprising the copolymer composition as recited in claim 3 .
6. A cosmetic comprising the copolymer as recited in claim 1 .
7. A cosmetic comprising the copolymer composition as recited in claim 3 .
8. The cosmetic according to claim 6 , further comprising at least one oil agent.
9. The cosmetic according to claim 8 , wherein said oil agent is a silicone oil.
10. The cosmetic according to claim 9 , wherein said silicone oil is a hydrophobic silicone oil having a viscosity at 25° C. ranging from 0.65 to 100,000 mm 2 /s.
11. The cosmetic according to claim 9 , wherein said silicone oil is an organopolysiloxane represented by the following formula (3) or (4):
wherein
R 9 is a hydrogen atom, a hydroxyl group or a group selected from monovalent non-substituted or fluorine- or amino-substituted C 1-30 alkyl groups, aryl groups, alkoxy groups and groups represented by (CH 3 ) 3 SiO{(CH 3 ) 2 SiO} l Si(CH 3 ) 2 CH 2 CH 2 —, wherein l is an integer ranging from 0 to 1,000;
a′ is an integer ranging from 0 to 3;
b′ is an integer ranging from 0 to 1,000; and
c′ is an integer ranging from 0 to 1,000, with the proviso that 1≤b′+c′≤2,000,
wherein
R 9 is the same as defined above;
d is an integer ranging from 0 to 8; and
e is an integer ranging from 0 to 8, with the proviso that 3≤d+e≤8.
12. The cosmetic according to claim 6 , further comprising at least one surfactant selected from the group consisting of anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants and semi-polar surfactants.
13. The cosmetic according to claim 6 , further comprising at least one powder and/or at least one coloring agent.
14. The cosmetic according to claim 13 , wherein said powder is selected from the group consisting of inorganic pigment powders, organic pigment powders and resin powders, having an average particle size ranging from 1 nm to 20 μm.
15. The cosmetic according to claim 13 , wherein at least one part of said powder and/or coloring agent is subjected to a hydrophobic treatment.
16. The cosmetic according to claim 6 , further comprising at least one selected from the group consisting of water-soluble polymers, oil-soluble gelling agents and organo-modified clay minerals.
17. The cosmetic according to claim 6 , further comprising at least one selected from the group consisting of silicone resins, silicone elastomers and organo-modified silicones.
18. The cosmetic according to claim 6 , further comprising at least one UV-ray protective component.
19. A skin care product, a hair product, an antiperspirant product, a deodorant product, a makeup product or a UV-ray protective product comprising the cosmetic as recited in claim 6 .
20. The copolymer according to claim 1 , wherein at least one of said at least two unsaturated monomers having no long-chain alkyl group with 14 to 22 carbon atoms (C) is methyl methacrylate or n-butyl acrylate.