Granted Patent B2

US 8,691,937 · App. 13/518,154 · Granted Apr 8, 2014

Abstract

Claims (28)

1. A method of preparing a polymer composition, comprising;

polymerizing one or more monomers in a free radical polymerization in the presence of a chain transfer agent to produce a first polymer latex, wherein the chain transfer agent is a linear alkyl thiol;

treating the first polymer latex with an inorganic oxidizing agent to oxidize residual chain transfer agent to decomposition products capable of removal by steam stripping; and

subjecting the reaction mixture to steam stripping to remove at least some of said decomposition products from the reaction mixture.

2. A method as claimed in claim 1 , wherein the free radical polymerization is an emulsion polymerization.

3. A method as claimed in claim 1 , wherein the one or more monomers comprise a monovinylidene monomer and a conjugated diene.

4. A method as claimed in claim 1 , wherein the polymer latex is a styrene/butadiene latex.

5. A method as claimed in claim 1 , wherein the inorganic oxidizing agent is hydrogen peroxide.

6. A method as claimed in claim 1 , wherein the chain transfer agent is n-octylmercaptan, n-decylmercaptan, n-tetradecylmercaptan or n-dodecylmercaptan.

7. A method as claimed in claim 1 , wherein the chain transfer agent is used in an amount of from 0.1 to 2 wt. %, based on the total monomer employed.

8. A method as claimed in claim 1 , wherein the oxidation is carried out at a temperature of from 85 to 115° C.

9. A method as claimed in claim 1 , and including the step of adjusting the pH of the polymer latex pH to a value of from 5 to 10, by the addition of a base and optionally a salt buffer.

10. A method as claimed in claim 8 , wherein the base is sodium hydroxide or potassium hydroxide.

11. A method as claimed in claim 8 , wherein the salt buffer is sodium bicarbonate or sodium acetate.

12. A method as claimed in claim 6 , wherein the chain transfer agent is n-dodecylmercaptan (n-DDM).

13. A method as claimed in claim 1 , wherein the monomer mixture also includes an ethylenically unsaturated carboxylic acid.

14. A method as claimed in claim 1 , wherein the monomer mixture includes acrylonitrile.

15. A method as claimed in claim 1 , wherein the preparation method includes a step in which the latex is treated at a temperature of at least 50 C.

16. A method of preparing a polymer composition, comprising;

polymerizing one or more monomers in a free radical polymerization in the presence of a chain transfer agent to produce a first polymer latex, wherein the chain transfer agent is a linear alkyl thiol;

treating the first polymer latex with an oxidizing agent to oxidize residual chain transfer agent to decomposition products capable of removal by steam stripping, wherein the oxidizing agent is added in an amount from 0.6 to 1.1 wt. parts, based on a total monomer content; and

subjecting the reaction mixture to steam stripping to remove at least some of said decomposition products from the reaction mixture.

17. The method of claim 16 , wherein the oxidizing agent is an inorganic oxidizing agent.

18. A method of preparing a polymer composition, comprising;

polymerizing one or more monomers in a free radical polymerization in the presence of a chain transfer agent to produce a first polymer latex, wherein the chain transfer agent is a linear alkyl thiol;

treating the first polymer latex with a composition to oxidize residual chain transfer agent to decomposition products capable of removal by steam stripping, wherein the composition consists of an oxidizing agent; and

subjecting the reaction mixture to steam stripping to remove at least some of said decomposition products from the reaction mixture.

19. The method of claim 18 , wherein the oxidizing agent is an inorganic oxidizing agent.

Assignments (9)