IP Library Granted Patent US 10,525,290
Granted Patent B2
US 10,525,290 · App. 13/519,736 · Granted Jan 7, 2020

Compositions for forming films having a desired degree of obscuration and methods of making and using the same

Inventors: Demetrius Michos (Clarksville, MD); James Neil Pryor (West Friendship, MD)
Assignee: W. R. Grace & Co.-Conn.
A61Q19/08A61K8/25A61K8/31A61K8/8129A61K8/891A61K8/894A61Q19/00
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Quick Facts
Patent No.
US 10,525,290
App. No.
13/519,736
Granted
Jan 7, 2020
Kind
B2
Abstract

Compositions suitable for use as skin care products (e.g., skin cream) are disclosed. Methods of making and using compositions suitable for use as skin care products are also disclosed.

Claims (30)

1. A composition comprising:

particulate material having a particulate material refractive index ranging from about 1.2 to about 1.8, said particulate material consisting of alumina, boron nitride, or silica particles, said particulate material being precipitated particles or gel particles; and

a fluid phase in an amount of from about 10.0 wt % to about 98.0 wt % based on a total weight of the composition, said fluid phase comprising:

from about 1.0 wt % to about 60 wt % of at least one non-volatile fluid component, based on a total weight of the fluid phase, said at least one non-volatile fluid component having a non-volatile fluid component refractive index ranging from about 1.2 to about 1.8, and

from about 99.0 wt % to about 40 wt % of at least one volatile fluid component based on a total weight of the fluid phase;

wherein the composition, after being dried on a substrate, forms a continuous, transparent film (a) that exhibits less than 50% intra-film light scattering and greater than about 50% surface light scattering based on a total amount of light scattering by the film, and (b) has an optical performance ratio of at least 4.0.

2. The composition of claim 1 , wherein said particulate material consists of precipitated silica particles or silica gel particles.

3. The composition of claim 1 , wherein said optical performance ratio is at least about 4.5.

4. A dried film formed from the composition of claim 1 .

5. The dried film of claim 4 , wherein said dried film comprises a transparent continuous film having an outermost rough surface.

6. The dried film of claim 5 , wherein said dried film comprises from about 19 wt % to about 26 wt % of total particulate material based on a total weight of (i) all particulate material and (ii) said at least one non-volatile fluid component within the continuous, transparent film.

7. A method of hiding skin imperfections, said method comprising:

applying the composition of claim 1 onto an outer skin surface.

8. The composition of claim 1 , wherein a given optical performance ratio comprises a ratio of (i) a diffusion transmission value divided by (ii) a total reflection value for a given composition.

9. The composition of claim 1 , wherein said particulate material consists of precipitated silica particles or silica gel particles; said at least one non-volatile fluid component comprises one or more components selected from oils, waxes, glycerin, and any combination thereof; and said at least one volatile fluid component comprises one or more components selected from silicones, deionized water, solvents, fragrances, and any combination thereof.

10. The composition of claim 1 , wherein said particulate material has a particulate material refractive index ranging from about 1.4 to about 1.6, and said at least one non-volatile fluid component has a non-volatile fluid component refractive index ranging from about 1.4 to about 1.6.

11. The composition of claim 1 , wherein the composition, after being dried on a substrate, forms a continuous, transparent film that exhibits less than 25% intra-film light scattering and greater than about 75% surface light scattering based on a total amount of light scattering by the film.

12. The composition of claim 1 , wherein the composition, after being dried on a substrate, forms a continuous, transparent film that comprises from about 19 wt % to about 26 wt % of total particulate material based on a total weight of (i) all particulate material and (ii) said at least one non-volatile fluid component within the continuous, transparent film.

13. The composition of claim 1 , wherein said composition consists of said particulate material and said fluid phase.

14. The composition of claim 1 , wherein (1) said particulate material consists of precipitated silica particles or silica gel particles, and (2) said fluid phase comprises from about 1.0 wt % to about 40.0 wt % of said at least one non-volatile fluid component, based on a total weight of the fluid phase, and from about 99.0 wt % to about 60.0 wt % of said at least one volatile fluid component based on a total weight of the fluid phase.

15. A transparent coating for hiding skin imperfections, said transparent coating comprising:

particulate material having a particulate material refractive index ranging from about 1.2 to about 1.8, said particulate material consisting of alumina, boron nitride, or silica particles, said particulate material being precipitated particles or gel particles; and

a fluid phase in an amount of from about 10.0 wt % to about 98.0 wt % based on a total weight of the composition, said fluid phase comprising:

from about 1.0 wt % to about 60.0 wt % of at least one non-volatile fluid component, based on a total weight of the fluid phase, said at least one non-volatile fluid component having a non-volatile fluid component refractive index ranging from about 1.2 to about 1.8, and

from about 99.0 wt % to about 40.0 wt % of at least one volatile fluid component based on a total weight of the fluid phase;

wherein the transparent coating, after being dried on a substrate, forms a continuous, transparent film (a) that exhibits less than 50% intra-film light scattering and greater than about 50% surface light scattering based on a total amount of light scattering by the film, and (b) has an optical performance ratio of at least 4.0.

16. The transparent coating of claim 15 , wherein said particulate material has a particulate material refractive index ranging from about 1.4 to about 1.6, and said at least one non-volatile fluid component has a non-volatile fluid component refractive index ranging from about 1.4 to about 1.6.

17. The transparent coating of claim 15 , wherein the transparent coating, after being dried on a substrate, forms a continuous, transparent film that exhibits less than 25% intra-film light scattering and greater than about 75% surface light scattering based on a total amount of light scattering by the film.

18. The transparent coating of claim 15 , wherein the transparent coating, after being dried on a substrate, forms a continuous, transparent film that comprises from about 19 wt % to about 26 wt % of total particulate material based on a total weight of (i) all particulate material and (ii) said at least one non-volatile fluid component within the continuous, transparent film.

19. The transparent coating of claim 15 , wherein (1) said particulate material consists of precipitated silica particles or silica gel particles, and (2) said fluid phase comprises from about 1.0 wt % to about 40.0 wt % of said at least one non-volatile fluid component, based on a total weight of the fluid phase, and from about 99.0 wt % to about 60.0 wt % of said at least one volatile fluid component based on a total weight of the fluid phase.

Assignments (10)
NOTES SECURITY INTEREST Recorded Jan 29, 2026
From: W. R. GRACE & CO.-CONN.; ADVANCED REFINING TECHNOLOGIES LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 074532/0229 →
SECURITY AGREEMENT (NOTES) Recorded Aug 19, 2025
From: W. R. GRACE & CO.-CONN.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 072520/0653 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 10, 2023
From: MICHOS, DEMETRIUS; PRYOR, JAMES NEIL
To: W.R. GRACE & CO.-CONN.
Reel/Frame 062949/0234 →
SECURITY INTEREST Recorded Feb 17, 2023
From: W.R. GRACE & CO.-CONN.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 062792/0510 →
RELEASE OF SECURITY INTEREST Recorded Sep 23, 2021
From: GOLDMAN SACHS BANK USA
To: W. R. GRACE & CO.-CONN.
Reel/Frame 057594/0026 →
NOTES SECURITY AGREEMENT Recorded Sep 23, 2021
From: W. R. GRACE & CO.-CONN.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 057594/0156 →
TERM LOAN SECURITY AGREEMENT Recorded Sep 23, 2021
From: W. R. GRACE & CO.-CONN.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 057594/0104 →
SECURITY INTEREST Recorded Apr 3, 2018
From: W. R. GRACE & CO.-CONN.
To: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
Reel/Frame 045828/0683 →
RELEASE OF SECURITY AGREEMENT RECORDED AT REEL/FRAME NO.: 032159/0384 Recorded Apr 3, 2018
From: GOLDMAN SACHS BANK USA, AS THE COLLATERAL AGENT
To: W.R. GRACE & CO.-CONN.
Reel/Frame 045832/0887 →
SECURITY AGREEMENT Recorded Feb 4, 2014
From: W.R. GRACE & CO.-CONN.
To: GOLDMAN SACHS BANK USA, AS THE COLLATERAL AGENT
Reel/Frame 032159/0384 →