IP Library Granted Patent US 9,234,104
Granted Patent B2
US 9,234,104 · App. 13/519,748 · Granted Jan 12, 2016

Composite metal oxide particles and methods of making and using the same

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Quick Facts
Patent No.
US 9,234,104
App. No.
13/519,748
Granted
Jan 12, 2016
Kind
B2
Abstract

Composite inorganic particles and compositions containing silica particles are disclosed. Methods of making silica particles and methods of using composite inorganic particles are also disclosed.

Claims (9)

1. A dispersion of composite inorganic particles comprising:

a liquid; and

composite inorganic particles dispersed throughout said liquid, said composite inorganic particles comprising (i) a silica core 1 and (ii) a coating comprising a metal phosphate formed thereon, wherein the metal phosphate comprises calcium phosphate, magnesium phosphate, or mixtures thereof, wherein the dispersion comprises from about 1 to about 40 wt % solids based on a total weight of the dispersion and the dispersion has a pH of from 9 to 14.

2. The dispersion of claim 1 , wherein the metal phosphate comprises calcium phosphate.

3. The dispersion of claim 1 , wherein the metal oxide comprises nano-particles.

4. The dispersion of claim 1 , wherein the composite inorganic particles comprise a weight ratio of (i) metal of said metal phosphate to (ii) weight of silica of about 0.001 to about 0.5.

5. The dispersion of claim 1 , wherein the dispersion has a pH of from 9.3 to 9.5.

6. The dispersion of claim 1 , wherein the composite inorganic particles have a median particle size ranging from about 0.001 μm to about 50 μm.

7. The dispersion of claim 1 , wherein the metal phosphate comprises magnesium phosphate.

Assignments (9)
NOTES SECURITY INTEREST Recorded Jan 29, 2026
From: W. R. GRACE & CO.-CONN.; ADVANCED REFINING TECHNOLOGIES LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 074532/0229 →
SECURITY AGREEMENT (NOTES) Recorded Aug 19, 2025
From: W. R. GRACE & CO.-CONN.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 072520/0653 →
SECURITY INTEREST Recorded Feb 17, 2023
From: W.R. GRACE & CO.-CONN.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 062792/0510 →
RELEASE OF SECURITY INTEREST Recorded Sep 23, 2021
From: GOLDMAN SACHS BANK USA
To: W. R. GRACE & CO.-CONN.
Reel/Frame 057594/0026 →
TERM LOAN SECURITY AGREEMENT Recorded Sep 23, 2021
From: W. R. GRACE & CO.-CONN.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 057594/0104 →
NOTES SECURITY AGREEMENT Recorded Sep 23, 2021
From: W. R. GRACE & CO.-CONN.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 057594/0156 →
RELEASE OF SECURITY AGREEMENT RECORDED AT REEL/FRAME NO.: 032159/0384 Recorded Apr 3, 2018
From: GOLDMAN SACHS BANK USA, AS THE COLLATERAL AGENT
To: W.R. GRACE & CO.-CONN.
Reel/Frame 045832/0887 →
SECURITY INTEREST Recorded Apr 3, 2018
From: W. R. GRACE & CO.-CONN.
To: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
Reel/Frame 045828/0683 →
SECURITY AGREEMENT Recorded Feb 4, 2014
From: W.R. GRACE & CO.-CONN.
To: GOLDMAN SACHS BANK USA, AS THE COLLATERAL AGENT
Reel/Frame 032159/0384 →