Common solvent process for producing high molecular weight halogenated rubber
View Patent ↗The invention relates to an energy efficient, environmentally favorable process for the preparation of halogenated rubbers, in particular chloro- and bromobutyl rubber, that uses a common aliphatic medium of specific composition for both solution polymerization and subsequent halogenation of the rubber. More particularly, the invention relates to a process that employs a common aliphatic medium for both solution polymerization and halogenation of rubber with intermediate removal of un-reacted monomers.
1. A process for the preparation of halogenated rubbers, the process comprising:
a) providing a reaction medium comprising
a common aliphatic medium comprising at least 50 wt.-% of one or more aliphatic hydrocarbons having a boiling point of 45° C. to 80° C. at a pressure of 1013 hPa, whereby the common aliphatic medium further comprises a content of cyclic aliphatic hydrocarbons of less than 25 wt.-% and
a monomer mixture comprising at least one isoolefin monomer, at least one multiolefin monomer and either no or at least one other co-polymerizable monomer
in a mass ratio of monomer mixture to common aliphatic medium of from 40:60 to 99:1,
b) polymerizing the monomer mixture within the reaction medium to form a rubber solution comprising a rubber polymer which is at least substantially dissolved in the medium comprising the common aliphatic medium and residual monomers of the monomer mixture;
c) separating residual monomers of the monomer mixture from the rubber solution to form a separated rubber solution comprising the rubber and the common aliphatic medium, and
d) halogenating the rubber in the separated rubber solution using a halogenating agent.
2. The process according to claim 1 , wherein the rubber is a butyl rubber.
3. The process according to claim 1 , wherein the monomer mixture comprises 80.0% to 99.9% by weight of the at least one isoolefin monomer and 0.1% to 20.0% by weight of the at least one multiolefin monomer.
4. The process according to one of the claims 1 , wherein the isoolefin monomer is isobutene and the multiolefin monomer is isoprene.
5. The process according to one of the claims 1 , wherein the common aliphatic medium comprises at least 80 wt.-% of one or more aliphatic hydrocarbons having a boiling point of 45° C. to 80° C. at a pressure of 1013 hPa.
6. The process according to one of the claims 1 , wherein the common aliphatic medium has a content of cyclic aliphatic hydrocarbons of less than 20 wt.-%.
7. The process according to one of the claims 1 , wherein the common aliphatic medium has a content of cyclohexane of less than 2.5 wt.-%.
8. The process according to one of the claims 1 , wherein the common aliphatic medium contains at least 30 wt.-% branched, non-cyclic aliphatic hydrocarbons having a boiling point of 45° C. to 80° C. at a pressure of 1013 hPa.
9. The process according to one of the claims 1 , wherein the reaction is performed in a polymerization reactor, and wherein the viscosity of the solution at the discharge of the polymerization reactor is less than 2000 cP.
10. The process according to one of the claims 1 , wherein the solids content of the rubber solution obtained following step b) is 3 to 25% by weight.
11. The process according to one of the claims 1 , wherein the halogenating agent is molecular bromine or chlorine.
12. The process according to one of the claims 1 , wherein the amount of halogenating agent is 0.1 to 20% by weight of the rubber.
13. The process according to one of the claims 1 , wherein the halogenating agent is a brominating agent and is used in combination with an oxidizing agent.
14. The process according to one of the claims 1 , further comprises curing the halogenated rubber obtained in step d).