X-ray tube and X-ray fluorescence analyser utilizing selective excitation radiation

1. An X-ray tube, comprising:

a cathode,

an anode with an electron receiving surface, and

a window facing the electron receiving surface of the anode;

wherein the anode comprises:

on the electron receiving surface of the anode, a layer of anode material, and

deeper in the anode than said layer of anode material in the arrival direction of the electrons, a block of attenuator material, a lower surface of the layer of anode material being directly on top of an upper surface of the block of attenuator material, and

wherein the atomic number of said attenuator material is less than one third of the atomic number of the anode material.

2. The X-ray tube according to claim 1 , wherein the atomic number of said attenuator material is less than one fifth of the atomic number of the anode material.

3. The X-ray tube according to claim 1 , wherein the atomic number of said attenuator material is less than one tenth of the atomic number of the anode material.

4. The X-ray tube according to claim 1 , wherein said attenuator material is beryllium.

5. The X-ray tube according to claim 1 , wherein:

a thickness of said layer of anode material in the propagation direction of electrons from the cathode to the anode is between 4 and 8 micrometers, and

a combined thickness of said layer of anode material and said block of attenuator material in the propagation direction of electrons from the cathode to the anode is larger than a maximum penetration depth of the electrons in the combined stack of said layer of anode material and said block of attenuator material at a nominal acceleration voltage of the X-ray tube.

6. The X-ray tube according to claim 1 , wherein:

a thickness of said block of attenuator material the propagation direction of electrons from the cathode to the anode is between 50 and 100 micrometers,

said block of attenuator material resides in a holder made of a third material.

7. The X-ray tube according to claim 1 , wherein the atomic number of said anode material is 42 or larger.

8. An X-ray fluorescence analyser device, comprising an X-ray tube according to claim 1 and a detector of fluorescent radiation.

9. The X-ray fluorescence analyser device according to claim 8 , wherein:

the X-ray fluorescence analyser device comprises a support frame for maintaining a known spatial relationship between the X-ray tube and a sample to be analyzed and between said sample to be analyzed and the detector,

an excitation beam propagation direction out of the X-ray tube and towards said sample to be analyzed is at an essentially right angle to the propagation direction of accelerated electrons within the X-ray tube, and

a fluorescence beam propagation direction from said sample to said detector of fluorescent radiation is at an essentially right angle to said excitation beam propagation direction.

10. The X-ray fluorescence analyser device according to claim 8 , comprising a primary filter between the X-ray tube and the sample, wherein said primary filter is configured to essentially absorb characteristic X-ray peaks of the anode material of the X-ray tube.

11. The X-ray fluorescence analyser device according to claim 10 , wherein the anode material of the X-ray tube is tungsten and the primary filter comprises gadolinium.

12. The X-ray fluorescence analyser device according to claim 8 , comprising an X-ray filter, referred to as a secondary X-ray filter, of low-pass type between the sample to be analyzed and said detector.

13. The X-ray fluorescence analyser device according to claim 8 , wherein said detector has a detector layer made of germanium, and a dimension of the detector layer in the propagation direction of fluorescent X-rays from the sample to be analyzed is less than the thickness of germanium needed to absorb 50% of X-rays at the energies of the excitation beam.

14. The X-ray fluorescence analyser device according to claim 9 , comprising a primary filter between the X-ray tube and the sample, wherein said primary filter is configured to essentially absorb characteristic X-ray peaks of the anode material of the X-ray tube, and comprising an X-ray filter, referred to as a secondary X-ray filter, of low-pass type between the sample to be analyzed and said detector.

15. The X-ray fluorescence analyser device according to claim 10 , comprising a secondary X-ray filter of low-pass type between the sample to be analyzed and said detector.

16. The X-ray fluorescence analyser device according to claim 9 , wherein said detector has a detector layer made of germanium, and a dimension of the detector layer in the propagation direction of fluorescent X-rays from the sample to be analyzed is less than the thickness of germanium needed to absorb 50% of X-rays at the energies of the excitation beam.

17. The X-ray fluorescence analyser device according to claim 10 , wherein said detector has a detector layer made of germanium, and a dimension of the detector layer in the propagation direction of fluorescent X-rays from the sample to be analyzed is less than the thickness of germanium needed to absorb 50% of X-rays at the energies of the excitation beam.

18. The X-ray fluorescence analyser device according to claim 11 , wherein said detector has a detector layer made of germanium, and a dimension of the detector layer in the propagation direction of fluorescent X-rays from the sample to be analyzed is less than the thickness of germanium needed to absorb 50% of X-rays at the energies of the excitation beam.

19. The X-ray fluorescence analyser device according to claim 1 , wherein a thickness of the layer of anode material is sufficiently thin such that a majority of hard bremsstrahlung generated by the anode will be generated in the layer of anode material and most of the electrons that do not lose a large majority of kinetic energy in one interaction leave the layer of anode material and continue into the block of attenuator material.

20. The X-ray fluorescence analyser device according to claim 1 , wherein a thickness of the layer of anode material is between 4 and 8 micrometers and a thickness of the block of attenuator material is larger than 50 micrometers.

21. An X-ray tube having a structure decreasing an amount of soft bremsstrahlung that reaches a sample to be analysed, comprising:

a cathode that provides a source of electrons with kinetic energy;

an anode with an electron receiving surface that, in use, generates hard bremsstrahlung where the electrons hit the electron receiving surface, the electron receiving surface being a layer of anode material that generates hard bremsstrahlung, the anode comprising the layer of anode material directly on top of a block of attenuator material deeper in the anode than said layer of anode material in the arrival direction of the electrons, wherein the atomic number of said attenuator material is less than one third of the atomic number of the anode material; and

a window facing the electron receiving surface of the anode so that at least some of the generated hard bremsstrahlung from the surface of the anode where the electrons hit have a direct propagation path to and out of the window to the sample to be analysed,

wherein a thickness of the layer of anode material is sufficiently thin such that a majority of the hard bremsstrahlung will be generated in the layer of anode material and most of the electrons that do not lose a large majority of the kinetic energy in one interaction leave the layer of anode material and continue into the block of attenuator material.