IP Library Granted Patent US 9,593,211
Granted Patent B2
US 9,593,211 · App. 13/526,124 · Granted Mar 14, 2017

Asphalt binder modifier composition

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,593,211
App. No.
13/526,124
Granted
Mar 14, 2017
Kind
B2
Abstract

Asphalt binder modifiers derived from the thermo-catalytic conversion of biomass are provided. The asphalt binder modifiers are useful as anti-stripping agents and in increasing tensile strength ratios for asphalt concrete, asphalt-containing roofing materials, and other asphalt applications.

Claims (57)

1. A water insoluble asphalt binder modifier, comprising a high molecular weight fraction of a biomass T-C oil having a boiling point of at least 343° C., wherein the high molecular weight fraction comprises a non-hydrotreated portion and a portion that has been at least partially hydrotreated, and wherein the high molecular weight fraction is produced by:

(a) heating a biomass in the presence of a catalyst at a temperature between 200 and 1000° C. to produce said biomass T-C oil;

(b) separating said biomass T-C oil by a fractionation process into said high molecular weight fraction and a lower molecular weight fraction;

(c) the at least partially hydrotreated portion of the high molecular weight fraction has an oxygen content less than about 10 wt %; and

d) the non-hydrotreated portion of the high molecular weight fraction has an oxygen content less than about 20 wt %,

wherein said water insoluble asphalt binder modifier comprises from about 2 weight percent to about 10 weight percent oxygen.

2. The asphalt binder modifier of claim 1 wherein said biomass is a lignocellulosic material, and said thermo-catalytic conversion occurs in a riser reactor in the presence of a heterogeneous acid catalyst.

3. The asphalt binder modifier of claim 1 , wherein when the asphalt binder modifier is present in an asphalt concrete comprising: 1) aggregate, and 2) an asphalt binder comprising asphalt and said asphalt binder modifier, the stripping of said asphalt binder from said aggregate is reduced when contacted with water as compared to asphalt concrete without the asphalt binder modifier.

4. The asphalt binder modifier of claim 1 comprising:

(i) at least about 10 weight percent furan and phenol compounds, and

(ii) less than about 5 weight percent anhydro sugars.

5. The asphalt binder modifier of claim 4 comprising:

(i) from about 10 weight percent to about 40 weight percent furan and phenol compounds, and

(ii) less than 1 weight percent anhydro sugars.

6. The asphalt binder modifier of claim 1 wherein said fractionation process is vacuum distillation.

7. An asphalt binder comprising asphalt and a water insoluble asphalt binder modifier, wherein said water insoluble asphalt binder modifier comprises a high molecular weight fraction of a biomass T-C oil having a boiling point of at least 343° C., wherein the high molecular weight fraction comprises a non-hydrotreated portion and a portion that has been at least partially hydrotreated, and wherein the high molecular weight fraction is produced by:

(a) heating a biomass in the presence of a catalyst at a temperature between 200 and 1000° C. to produce said biomass T-C oil;

(b) separating said biomass T-C oil by a fractionation process into said high molecular weight fraction and a lower molecular weight fraction;

(c) the at least partially hydrotreated portion of the high molecular weight fraction has an oxygen content less than about 10 wt %; and

d) the non-hydrotreated portion of the high molecular weight fraction has an oxygen content less than about 20 wt %,

wherein said water insoluble asphalt binder modifier comprises from about 2 weight percent to about 10 weight percent oxygen.

8. The asphalt binder of claim 7 wherein said biomass is a lignocellulosic material, and said thermo-catalytic conversion occurs in a riser reactor and in the presence of a heterogeneous acid catalyst.

9. The asphalt binder of claim 8 wherein said high molecular weight fraction comprises:

(i) at least about 10 weight percent furan and phenol compounds, and

(ii) less than about 5 weight percent anhydro sugars.

10. The asphalt binder of claim 8 wherein said high molecular weight fraction comprises:

(i) from about 10 weight percent to about 40 weight percent furan and phenol compounds, and

(ii) less than about 1 weight percent anhydro sugars.

11. The asphalt binder of claim 8 wherein said fractionation process is vacuum distillation.

12. The asphalt binder of claim 7 wherein said asphalt binder comprises from about 1 weight percent to about 15 weight percent of said asphalt binder modifier.

13. The asphalt binder of claim 12 wherein said asphalt binder comprises from about 3 weight percent to about 7 weight percent of said asphalt binder modifier.

14. An asphalt concrete composition comprising:

(i) an aggregate, and

(ii) an asphalt binder comprising asphalt and a water insoluble asphalt binder modifier, wherein said water insoluble asphalt binder modifier comprises a high molecular weight fraction of a biomass T-C oil having a boiling point of at least 343° C., wherein the high molecular weight fraction comprises a non-hydrotreated portion and a portion that has been at least partially hydrotreated, and wherein the high molecular weight fraction is produced by:

(a) heating a biomass in the presence of a catalyst at a temperature between 200 and 1000° C. to produce said biomass T-C oil;

(b) separating said biomass T-C oil by a fractionation process into said high molecular weight fraction and a lower molecular weight fraction;

(c) the at least partially hydrotreated portion of the high molecular weight fraction has an oxygen content less than about 10 wt %; and

d) the non-hydrotreated portion of the high molecular weight fraction has an oxygen content less than about 20 wt %,

wherein said water insoluble asphalt binder modifier comprises from about 2 weight percent to about 10 weight percent oxygen.

15. The asphalt concrete composition of claim 14 wherein said biomass is a lignocellulosic material, and said thermo-catalytic conversion occurs in a riser reactor in the presence of a heterogeneous acid catalyst.

16. The asphalt concrete composition of claim 15 wherein said high molecular weight fraction comprises:

(i) at least about 10 weight percent furan and phenol compounds, and

(ii) less than about 5 weight percent anhydro sugars.

17. The asphalt concrete composition of claim 16 wherein said high molecular weight fraction comprises:

(i) from about 10 weight percent to about 40 weight percent furan and phenol compounds, and

(ii) less than about 1 weight percent anhydro sugars.

18. The asphalt concrete composition of claim 15 wherein said fractionation process is vacuum distillation.

19. The asphalt concrete composition of claim 14 wherein said asphalt binder comprises from about 1 weight percent to about 15 weight percent of said asphalt binder modifier.

20. The asphalt concrete composition of claim 14 wherein said asphalt binder comprises from about 3 weight percent to about 7 weight percent of said asphalt binder modifier.

21. The asphalt concrete composition of claim 14 wherein said asphalt binder modifier is mixed with said asphalt prior to said asphalt being mixed with said aggregate.

22. The asphalt concrete composition of claim 14 wherein said asphalt binder modifier is mixed with said aggregate prior to said asphalt being mixed with said aggregate.

23. The asphalt concrete composition of claim 14 wherein said aggregate comprises one or more of the following: sand, gravel, limestone, dolomite, diabase, quartz, feldspar, stone chips, recycled asphalt pavement, recycled shingles, crumb rubber.

24. The asphalt concrete composition of claim 14 wherein said asphalt concrete composition comprises at least about 95 wt % of said aggregate and at least about 5 wt % of said asphalt binder.

25. A roofing material comprising felt and a mixture of granules and said asphalt binder of claim 7 .

26. The roofing material of claim 25 wherein said felt is selected from the group consisting of cellulosic fibers, glass fibers, and combinations thereof; and wherein said granules are mineral granules.

27. The roofing material of claim 26 wherein at least a portion of said granules are in the form of fines.

28. The roofing material of claim 25 having improved anti-stripping properties as compared to an asphalt-containing roofing material that does not include said asphalt binder of claim 7 .

Assignments (7)
CHANGE OF NAME Recorded Aug 18, 2020
From: INAERIS TECHNOLOGIES, LLC
To: MARD, INC.
Reel/Frame 054213/0032 →
CHANGE OF NAME Recorded Apr 7, 2016
From: KIOR, LLC
To: INAERIS TECHNOLOGIES, LLC
Reel/Frame 038380/0344 →
CORRECTIVE ASSIGNMENT TO CORRECT THE FULL NAME OF THE CONVEYING PARTY DATA PREVIOUSLY RECORDED AT REEL: 028395 FRAME: 0735. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Dec 4, 2015
From: TREWELLA, JEFFREY C.
To: KIOR, INC.
Reel/Frame 037591/0217 →
NUNC PRO TUNC ASSIGNMENT Recorded Sep 29, 2015
From: KIOR, INC.
To: KIOR, LLC
Reel/Frame 036717/0262 →
SECURITY INTEREST Recorded Jul 22, 2014
From: KIOR, INC.
To: KFT TRUST, VINOD KHOSLA, TRUSTEE, AS FIRST LIEN AGENT
Reel/Frame 033390/0423 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 18, 2012
From: TREWALLA, JEFFREY C.
To: KIOR, INC.
Reel/Frame 028395/0735 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 18, 2012
From: STROPE, DAN
To: KIOR, INC.
Reel/Frame 028395/0788 →