Granted Patent B2

US 8,753,479 · App. 13/526,710 · Granted Jun 17, 2014

Inventors: Anton Esser (Limburgerhof, DE); Hans-Joachim Haehnle (Neustadt, DE)

Assignee: BASF SE

Abstract

Claims (62)

1. A process for producing paper, card and board, the process comprising draining a filler-containing paper stock comprising at least one water-soluble amphoteric copolymer with sheet formation in the wire section and then pressing the paper in the press section to form a product,

wherein:

a paper stock having a fibrous concentration in the range from 20 to 40 g/l has the at least one water-soluble amphoteric copolymer added to it, then the paper stock is diluted to a fibrous concentration in the range from 5 to 15 g/l, the diluted paper stock is drained to form a sheet, and the sheet is pressed in the press section to a solids content G(x) wt % or greater and G(x) computes according to:

G ( x )=48+( x −15)·0.4,

where x is a filler content of the product (in wt %) and G(x) is a minimal solids content (in wt %) to which the sheet is pressed;

the water-soluble amphoteric copolymer is obtained by polymerizing a mixture of

a) 20 to 60 mol % of acrylamide, based on a total number of moles of monomers in the polymerizing,

b) 20 to 60 mol %, based on the total number of moles of monomers in the polymerizing, of at least one cationic monomer,

c) 20 to 60 mol %, based on the total number of moles of monomers in the polymerizing, of at least one anionic monomer selected from the group consisting of a monoethylenically unsaturated C 3 to C 5 carboxylic acid, a monoethylenically unsaturated C 3 to C 5 dicarboxylic acid, a sulfonic acid, a phosphonic acid, and salts thereof,

d) 0 to 30 mol %, based on the total number of moles of monomers in the polymerizing, of one or more monoethylenically unsaturated monomers other than said monomers (a), (b) and (c), and

e) 0 to 5 mol %, based on the total number of moles of monomers in the polymerizing, of one or more compounds comprising two or more ethylenically unsaturated double bonds;

a difference between the fractions of the cationic monomer and the anionic monomer in mol %, based on the total number of moles of monomers in the polymerizing, is not more than 10 mol %;

the at least one cationic monomer b) is selected from the group consisting of an ester of an α,β-ethylenically unsaturated monocarboxylic acid with an amino alcohol, an ester of an α,β-ethylenically unsaturated dicarboxylic acid with an amino alcohol, an amide of an α,β-ethylenically unsaturated monocarboxylic acid with a diamine, an amide of an α,β-ethylenically dicarboxylic acid with a diamine, an N—C 1 -C 8 -monoalkylated or N—C 1 -C 8 -dialkylated derivative thereof, and quaternary compounds thereof; and

the product has an initial wet web strength index of ≧2.9 Nm/g.

2. A process for producing paper, card and board, the process comprising draining a filler-containing paper stock comprising at least one water-soluble amphoteric copolymer with sheet formation in the wire section and then pressing the paper in the press section to form a product,

wherein:

a paper stock having a fibrous concentration in the range from 20 to 40 g/l has the at least one water-soluble amphoteric copolymer added to it, then the paper stock is diluted to a fibrous concentration in the range from 5 to 15 g/l, the diluted paper stock is drained to form a sheet, and the sheet is pressed in the press section to a solids content ≧48 wt %;

the water-soluble amphoteric copolymer is obtainable by polymerizing a mixture of

a) 20 to 60 mol % of acrylamide, based on the total number of moles of monomers in the polymerizing,

b) 20 to 60 mol %, based on the total number of moles of monomers in the polymerizing, of at least one cationic monomer,

c) 20 to 60 mol %, based on the total number of moles of monomers in the polymerizing, of at least one anionic monomer selected from the group consisting of a monoethylenically unsaturated C 3 to C 5 monocarboxylic acid, a monoethylenically unsaturated C 3 to C 5 dicarboxylic acid, a sulfonic acid, a phosphonic acid, and salts thereof,

d) 0 to 30 mol %, based on the total number of moles of monomers in the polymerizing, of one or more monoethylenically unsaturated monomers other than said monomers (a), (b) and (c), and

e) 0 to 5 mol %, based on the total number of moles of monomers in the polymerizing, of one or more compounds comprising two or more ethylenically unsaturated double bonds;

a difference between the fractions of the cationic monomer and the anionic monomer in mol %, based on a total number of moles of monomers in the polymerizing, is not more than 10 mol %;

the at least one cationic monomer b) is selected from the group consisting of an ester of an α,β-ethylenically unsaturated monocarboxylic acid with an amino alcohol, an ester of an α,β-ethylenically unsaturated dicarboxylic acid with an amino alcohol, an amide of an α,β-ethylenically unsaturated monocarboxylic acid with a diamine, an amide of an α,β-ethylenically dicarboxylic acid with a diamine, an N—C 1 -C 8 -monoalkylated or N—C 1 -C 8 -dialkylated derivative thereof, and quaternary compounds thereof; and

the product has an initial wet web strength index of ≧2.9 Nm/g.

3. The process according to claim 1 or 2 wherein the paper stock comprises a fibrous material having a freeness of ≦30° SR.

4. The process according to claim 1 or claim 2 , wherein the water-soluble amphoteric copolymer is added to the paper stock having a fibrous concentration in the range from 20 to 40 g/l and before adding a filler.

5. The process according to claim 1 or claim 2 , wherein the water-soluble amphoteric copolymer is added in an amount of 0.05 to 5.00 wt %, based on fibrous material.

6. The process according to claim 1 or claim 2 , wherein the water-soluble amphoteric copolymer is obtainable by polymerizing a mixture comprising at least one cationic monomer selected from the group consisting of an ester of an α,β-ethylenically unsaturated monocarboxylic acid with an amino alcohol, an ester of an α,β-ethylenically unsaturated dicarboxylic acid with an amino alcohol, an amide of an α,β-ethylenically unsaturated monocarboxylic acid with a diamine, an amide of an α,β-ethylenically unsaturated dicarboxylic acid with a diamine, and an N—C 1 -C 8 -monoalkylated or N—C 1 -C 8 -dialkylated derivative thereof.

7. The process according to claim 1 or claim 2 , wherein the water-soluble amphoteric copolymer is obtainable by polymerizing a mixture comprising at least one anionic monomer selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, itaconic acid, acrylamido-2-methylpropanesulfonic acid, and salts thereof.

8. The process according to claim 1 or claim 2 , wherein the water-soluble amphoteric copolymer is obtainable by polymerizing a mixture of

a) 20 to 50 mol % of the acrylamide, based on the total number of moles of monomers in the polymerizing,

b) 25 to 40 mol %, based on the total number of moles of monomers in the polymerizing, of the at least one cationic monomer,

c) 25 to 40 mol %, based on the total number of moles of monomers in the polymerizing, of the at least one anionic monomer selected from the group consisting of a monoethylenically unsaturated C 3 to C 5 monocarboxylic acid, a monoethylenically unsaturated C 3 to C 5 dicarboxylic acid, a sulfonic acid, a phosphonic acid, and salts thereof,

d) 0 to 30 mol %, based on the total number of moles of monomers in the polymerizing, of the one or more monoethylenically unsaturated monomers other than said monomers (a), (b) and (c), and

e) 0 to 5 mol %, based on the total number of moles of monomers in the polymerizing, of the one or more compounds comprising two or more ethylenically unsaturated double bonds,

wherein the difference between the fractions of the cationic monomer and the anionic monomer in mol %, based on the total number of moles of monomers in the polymerizing, is not more than 10 mol %.

9. The process according to claim 2 , wherein:

the product is a paper, a card, or a board, having a filler content of 17 to 32 wt %; and

the process comprises pressing in the press section to at least a solids content in the range from 49 to 55 wt %.

10. The process according to claim 2 , wherein:

the product is a paper, a card, or a board, having a filler content of 5 to 15 wt %; and

the process comprises pressing in the press section to a solids content of at least 48 wt %.

11. The process of claim 1 , wherein the at least one cationic monomer b) is selected from the group consisting of N-methylaminomethyl(meth)acrylate, N-methylaminoethyl(meth)acrylate, N,N-dimethylaminomethyl (meth)acrylate, N,N-dimethylaminoethyl(meth)acrylate, N,N-diethylaminoethyl(meth)acrylate, N,N-dimethylaminopropyl(meth)acrylate, N,N-diethylaminopropyl(meth)acrylate, N,N-dimethylaminocyclohexyl(meth)acrylate, N[2-(dimethylamino)ethyl]acrylamide, N-[2-(dimethylamino)ethyl]methacrylamide, N-[3-(dimethylamino)propyl]acrylamide, N-[3-(dimethylamino)propyl]methacrylamide, N[4-(dimethylamino)butyl]acrylamide, N-[4-(dimethylamino)butyl]methacrylamide, N-[2-(diethylamino)ethyl]acrylamide, N-[2-(diethylamino)ethyl]methacrylamide, and the quaternary compounds thereof.

12. The process of claim 2 , wherein the at least one cationic monomer b) is selected from the group consisting of N-methylaminomethyl(meth)acrylate, N-methylaminoethyl(meth)acrylate, N,N-dimethylaminomethyl(meth)acrylate, N,N-dimethylaminoethyl(meth)acrylate, N,N-diethylaminoethyl(meth)acrylate, N,N-dimethylaminopropyl(meth)acrylate, N,N-diethylaminopropyl(meth)acrylate, N,N-dimethylaminocyclohexyl(meth)acrylate, N[2-(dimethylamino)ethyl]acrylamide, N-[2-(dimethylamino)ethyl]methacrylamide, N-[3-(dimethylamino)propyl]acrylamide, N-[3-(dimethylamino)propyl]methacrylamide, N-[4-(dimethylamino)butyl]acrylamide, N-[4-(dimethylamino)butyl]methacrylamide, N-[2-(diethylamino)ethyl]acrylamide, N-[2-(diethylamino)ethyl]methacrylamide, and the quaternary compounds thereof.

13. The process of claim 1 , wherein the water-soluble amphoteric copolymer is obtainable by polymerizing a mixture comprising:

a) 30 to 50 mol % of acrylamide, based on the total number of moles of monomers in the polymerizing;

b) 25 to 32 mol %, based on the total number of moles of monomer in the polymerizing, of the at least one cationic monomer; and

c) 20-40 mol %, based on the total number of moles of monomers in the polymerizing, of sodium acrylate.

14. The process of claim 2 , wherein the water-soluble amphoteric copolymer is obtainable by polymerizing a mixture comprising:

a) 30 to 50 mol % of acrylamide, based on the total number of moles of monomers in the polymerizing;

b) 25 to 32 mol %, based on the total number of moles of monomer in the polymerizing, of the at least one cationic monomer; and

c) 20-40 mol %, based on the total number of moles of monomers in the polymerizing, of sodium acrylate.

15. The process of claim 1 , wherein the water-soluble amphoteric copolymer is obtainable by polymerizing a mixture comprising:

a) 30 to 50 mol % of acrylamide, based on the total number of moles of monomers in the polymerizing;

b) 25 to 32 mol %, based on the total number of moles of monomer in the polymerizing, of acryloyloxyethyltrimethylammonium chloride; and

c) 20-40 mol %, based on the total number of moles of monomers in the polymerizing, of sodium acrylate.

16. The process of claim 2 , wherein the water-soluble amphoteric copolymer is obtainable by polymerizing a mixture comprising:

a) 30 to 50 mol % of acrylamide, based on the total number of moles of monomers in the polymerizing;

b) 25 to 32 mol %, based on the total number of moles of monomer in the polymerizing, of acryloyloxyethyltrimethylammonium chloride; and

c) 20-40 mol %, based on the total number of moles of monomers in the polymerizing, of sodium acrylate.

Assignments (12)

Continuity (2)