Blends of ethylene copolymers and propylene based plastomers in multilayer films for low noise and RF welding
View Patent ↗Compositions comprising from about 30% to about 95% of one or more RF-active functionalized ethylene copolymers and one or more propylene based plastomers are described. When formed into films or thin layers, the films exhibit a combination of low noise properties and good RF weldability characteristics. Also described are multilayer assemblies using such films and various articles incorporating such. Also described are methods of determining minimum thicknesses of an RF weldable layer in a multilayer film using the compositions.
1. A welded film assembly comprising:
an outer skin layer including at least one RF-active agent;
wherein the RF active agent is a functionalized ethylene copolymer;
a second layer immediately adjacent to the skin layer, the second layer including a blend of at least one RF-active functionalized ethylene copolymer and at least one propylene based plastomer; and
wherein the functionalized ethylene copolymer of each layer is selected from the group consisting ethylene vinyl acetate (EVA), ethyl methyl acrylate (EMA); ethyl butyl acrylate (EBA), and combinations thereof.
2. The welded film assembly of claim 1 wherein the outer skin layer and the second layer are welded together and exhibit a T-peel bond strength of at least about 16 N/in.
3. The welded film assembly of claim 1 wherein the second layer includes from about 30% to about 95% of RF-active functionalized ethylene copolymer.
4. The welded film assembly of claim 2 wherein the second layer includes from about 30% to about 95% of RF-active functionalized ethylene copolymer.
5. The welded film assembly of claim 1 wherein the functionalized ethylene copolymer is ethylene vinyl acetate (EVA).
6. A film comprising at least one layer including:
from about 30% to about 95% of at least one RF-active functionalized ethylene copolymer; and
at least one propylene based plastomer
wherein the at least one layer including the at least one RF-active functionalized ethylene copolymer is an RF weldable layer, the film further including:
at least one barrier layer comprising at least one cyclic olefin copolymer (COC).
7. The film of claim 6 wherein the functionalized ethylene copolymer is selected from the group consisting of ethylene vinyl acetate (EVA), ethyl methyl acrylate (EMA), ethyl butyl acrylate (EBA), and combinations thereof.
8. The film of claim 6 wherein the propylene based plastomer has a molecular weight distribution of less than 3.5.
9. The film of claim 6 wherein the propylene based plastomer has a density of less than about 0.89 g/cc.
10. The film of claim 6 wherein the propylene based plastomer has a heat of fusion less than 90 J/gm.
11. The film of claim 10 wherein the propylene based plastomer has a heat of fusion less than 70 J/gm.
12. The film of claim 6 , wherein the at least one barrier layer includes:
a first barrier layer comprising at least one cyclic olefin copolymer (COC);
a second barrier layer comprising ethylene vinyl alcohol (EVOH); and
a third barrier layer comprising at least one cyclic olefin copolymer (COC).
13. The film of claim 12 wherein the second barrier layer is disposed between the first barrier layer and the third barrier layer.
14. The film of claim 12 wherein at least one of the first barrier layer, the second barrier layer, and the third barrier layer comprises a plastomer different than the propylene based plastomer.
15. An article including a film comprising at least one layer having from about 30% to about 95% of at least one RF-active functionalized ethylene copolymer, and at least one propylene based plastomer;
wherein the film includes at least one barrier layer comprising at least one barrier agent selected from the group consisting of (i) cyclic olefin copolymer (COC).
16. The article of claim 15 wherein the functionalized ethylene copolymer is selected from the group consisting of ethylene vinyl acetate (EVA), ethyl methyl acrylate (EMA), ethyl butyl acrylate (EBA), and combinations thereof.
17. The article of claim 15 wherein the at least one barrier layer includes (i) a first barrier layer comprising at least one cyclic olefin copolymer (COC), (ii) a second barrier layer comprising ethylene vinyl alcohol (EVOH), and (iii) a third barrier layer comprising at least one cyclic olefin copolymer (COC).
18. The article of claim 17 wherein the second barrier layer is disposed between the first barrier layer and the third barrier layer.
19. The article of claim 17 wherein at least one of the first barrier layer, the second barrier layer, and the third barrier layer comprises a plastomer different than the propylene based plastomer.
20. The article of claim 15 wherein the propylene based plastomer has a molecular weight distribution of less than 3.5.
21. The article of claim 15 wherein the propylene based plastomer has a density of less than about 0.89 g/cc.
22. The article of claim 15 wherein the propylene based plastomer has a heat of fusion less than 90 J/gm.
23. The article of claim 22 wherein the propylene based plastomer has a heat of fusion less than 70 J/gm.