Lead-acid battery formulations containing discrete carbon nanotubes
View Patent ↗Compositions of discrete carbon nanotubes for improved performance lead acid batteries. Further disclosed is a method to form a lead-acid battery with discrete carbon nanotubes.
1. A lead-acid battery paste, comprising a battery blend prepared from a battery mixture comprising:
lead oxide;
a plurality of discrete individual carbon nanotube fibers, not entangled as a mass, having an aspect ratio of from about 10 to about 500;
an organic material;
an inorganic salt; and
a non-fiber carbon moiety, wherein the discrete carbon nanotube fibers have an oxidation level from about 1 weight percent to about 15 weight percent.
2. The battery mixture of claim 1 , wherein the inorganic salt is selected from the group consisting of: barium sulfate, lead sulfate, calcium sulfate, tin oxide, and mixture thereof.
3. The battery mixture of claim 1 , wherein the non-fiber carbon moiety is selected from the group consisting of: carbon black, graphite, graphene, and mixture thereof.
4. A lead-acid battery paste comprising a battery blend prepared from a battery mixture comprising:
lead oxide;
a plurality of discrete individual carbon nanotube fibers, not entangled as a mass, having an aspect ratio of from about 10 to about 500; and
an organic material, wherein the discrete carbon nanotube fibers have an oxidation level from about 1 weight percent to about 15 weight percent.
5. The battery mixture of claim 1 , wherein the discrete carbon nanotube fibers are coated with a conductive polymer.
6. The battery mixture of claim 4 , wherein the discrete carbon nanotube fibers are coated with a conductive polymer.
7. The battery mixture of claim 5 , wherein the conducting polymer is selected from the group consisting of: polyaniline, polyphenylene vinylene, polyvinylpyrollidone, polyacetylene polythiophene, polyphenylene sulfide, and blends, copolymers, and derivatives thereof.
8. The battery mixture of claim 6 , wherein the conducting polymer is selected from the group consisting of: polyaniline, polyphenylene vinylene, polyvinylpyrollidone, polyacetylene polythiophene, polyphenylene sulfide, and blends, copolymers, and derivatives thereof.
9. The battery mixture of claim 1 , further comprises at least one surfactant or dispersing aid.
10. The battery mixture of claim 4 , further comprises at least one surfactant or dispersing aid.
11. The battery mixture of claim 9 , wherein the surfactant or dispersing aid is a sulfonated polymer selected from the group consisting of: ligno-sulfonate, sulfonated polystyrene, and combinations thereof.
12. The battery mixture of claim 10 , wherein the surfactant or dispersing aid is a sulfonated polymer selected from the group consisting of: ligno-sulfonate, sulfonated polystyrene, and combinations thereof.
13. The battery mixture of claim 1 , further comprising water, wherein the discrete carbon nanotube fibers are dispersed in the water.
14. The battery mixture of claim 4 , further comprising water, wherein the discrete carbon nanotube fibers are dispersed in the water.
15. The lead-acid battery paste of claim 1 , wherein the lead-acid battery paste has a concentration gradient through the thickness of the acid-battery battery paste.
16. The lead-acid battery blend of claim 4 , wherein the lead-acid battery paste has a concentration gradient through the thickness of the battery paste.
17. The lead-acid battery paste of claim 1 , wherein the lead-acid battery paste has a highest concentration at a surface of a current collector or at a surface of a separator.
18. The lead-acid battery paste of claim 4 , wherein the lead-acid battery paste has a highest concentration at a surface of a current collector or at a surface of a separator.
19. The battery mixture of claim 1 , wherein the carbon nanotubes comprise at least about 70 percent, by weight, of discrete carbon nanotubes.
20. The battery mixture of claim 4 , wherein the carbon nanotubes comprise at least about 70 percent, by weight, of discrete carbon nanotubes.
21. The battery mixture of claim 1 , wherein the discrete carbon nanotubes are oxidized.
22. The battery mixture of claim 4 , wherein the discrete carbon nanotubes are oxidized.
23. The battery mixture of claim 1 further comprising an inorganic salt.
24. The battery mixture of claim 4 further comprising an inorganic salt.
25. The battery mixture of claim 1 further comprising a non-fiber carbon moiety.
26. The battery mixture of claim 4 further comprising a non-fiber carbon moiety.