Organic electroluminescent element including a condensed aromatic heterocyclic ring compound
View Patent ↗Provided is an organic electroluminescent element comprising a substrate having thereon an anode, a cathode, and a plurality of organic layers sandwiched between the anode and the cathode, wherein the plurality of organic layers comprise: a light emitting layer containing a phosphorescence emitting compound; and an electron transport layer containing a compound represented by Formula (1), (Ar1)n1−Y1 Formula (1) wherein n1 is an integer of 1 or more; Y 1 is a substituent when n1 is 1, and Y 1 is a single bond or a linking group of n1 valences when n1 is two or more; Ar1 is a group represented by Formula (A), a plurality of Ar1 may be the same or different with each other when n1 is two or more; and the compound represented by Formula (1) contains at least two condensed aromatic heterocyclic rings each comprising 3 or more rings condensed with each other:
1. An organic electroluminescent element comprising a substrate having thereon an anode, a cathode, and a plurality of organic layers sandwiched between the anode and the cathode,
wherein the plurality of organic layers comprise:
a light emitting layer containing a phosphorescence emitting compound; and
an electron transport layer containing a compound represented by Formula (1):
(Ar1)n1−Y1 Formula (1)
wherein n1 is an integer of 1; Y1 is a substituted or unsubstituted condensed heteroaryl group selected from the group consisting of a dibenzofuran group, a dibenzothiophene group, and a carbolinyl group, provided that a substituent of the substituted condensed heteroaryl group is selected from the group consisting of a carbazole group, a phenyl group, a pyridyl group, and a dibenzofuran group; Ar1 is a group represented by Formula (A-1):
wherein X is —N(R)—, —O—, or —S—; E1 to E8 each are —C(R1)= or —N═; R, and R1 each are a hydrogen atom or a substituent; Y2 is a single bond; E11 to E20 each are —C(R2)= or —N═, and at least one of E11 to E20 is —N═, R2 is a hydrogen atom, a substituent or a linking site,
provided that at least one of E11 and E12 is —C(R2)=, and R2 is a linking site; when E11 to E15 each are —C(R2)=, R2 is a hydrogen atom or a linking site;
n2 is an integer of 1 to 4; and (*) is a bonding site to Y1 of Formula (1).
2. The organic electroluminescent element of claim 1 , wherein at least one of E16 to E20 is —N═.
3. The organic electroluminescent element of claim 1 , wherein all of E11 to E15 are —C(R2)=, R2 is a hydrogen atom or a linking site.
4. The organic electroluminescent element of claim 1 , wherein n2 of Formula (A-1) is an integer of 1 to 2.
5. The organic electroluminescent element of claim 1 , wherein Y1 of Formula (I) is the carbolinyl group.
6. The organic electroluminescent element of claim 1 , wherein at least 6 of E1 to E8 of Formula (A) are —C(R1)=.
7. The organic electroluminescent element of claim 6 , wherein one of E16 to E20 is —N═.