Methods to fabricate variations in porosity of lithium ion battery electrode films
View Patent ↗A method and apparatus for forming lithium-ion batteries and battery cell components, and more specifically, to a system and method for fabricating such batteries and battery cell components using deposition processes that form three-dimensional porous structures are provided. One method comprises texturing a conductive substrate by calendering the conductive substrate between opposing wire mesh structures, forming a first layer of cathodically active material having a first porosity on the surface of the textured conductive substrate, and forming a second layer of cathodically active material having a second porosity on the first layer, wherein the second porosity is greater than the first porosity.
1. A method for forming a graded cathode structure, comprising:
forming a patterned layer of cathodically active material on a conductive metallic current collector by spraying the cathodically active material through openings of a patterned mask positioned above the conductive metallic current collector, wherein the patterned layer comprises a plurality of cathodically active features having one or more channels disposed therebetween;
forming a blanket layer of the cathodically active material over the patterned layer of cathodically active material;
compressing the as-deposited patterned layer and blanket layer to form a plurality of first regions comprising the plurality of cathodically active features with the cathodically active material of the blanket layer deposited thereon and one or more second regions comprising the cathodically active material of the blanket layer deposited in the one or more channels disposed between the cathodically active features, wherein the plurality of first regions has an average first porosity and the one or more second regions has an average second porosity that is greater than the average first porosity; and
depositing a separator layer directly on the compressed as-deposited patterned layer and blanket layer, wherein the separator layer is a dielectric, porous, fluid-permeable layer.
2. The method of claim 1 , wherein the plurality of first regions and the one or more second regions form a lateral porosity gradient relative to a surface of the conductive metallic current collector.
3. The method of claim 2 , wherein forming a blanket layer comprises spraying the cathodically active material over the patterned layer.
4. The method of claim 3 , wherein the patterned mask comprises a wire mesh structure with wires having a diameter between about 50 micrometers and 100 micrometers and the wire mesh structure has openings between about 5 micrometers and about 200 micrometers.
5. The method of claim 1 , wherein compressing the as-deposited patterned layer comprises calendaring the as-deposited patterned layer and blanket layer.
6. The method of claim 1 , wherein the average first porosity is between about 20% and about 35% as compared to a solid film formed from the same material and the average second porosity is between about 40% and about 70% as compared to a solid film formed from the same material.
7. The method of claim 1 , wherein the conductive metallic current collector comprises aluminum and the first cathodically active material and the second cathodically active material are LiNixCo 1-2x MnO 2 .
8. The method of claim 1 , wherein the one or more channels expose a surface of the conductive metallic current collector.
9. The method of claim 1 , wherein the conductive metallic current collector consists of a material selected from the group consisting of: aluminum, stainless steel, nickel, copper, and combinations thereof.
10. The method of claim 9 , wherein the conductive metallic current collector is in the form of a foil.
11. The method of claim 1 , further comprising heating the as-deposited patterned layer and blanket layer while compressing the as-deposited patterned layer and blanket layer.
12. The method of claim 1 , wherein the separator layer is deposited by an electrospinning process or an electrospraying process.