Methods of fabricating polycrystalline diamond elements and compacts using SP2-carbon-containing particles
View Patent ↗In an embodiment, a polycrystalline diamond compact includes a polycrystalline diamond table having nanocrystalline diamond present in an amount greater than zero weight percent to about 5 weight percent of the polycrystalline diamond table. The polycrystalline diamond table including a catalyst material distributed throughout at least a portion thereof. The polycrystalline diamond compact includes a substrate bonded to the polycrystalline diamond table.
1. A polycrystalline diamond compact, comprising:
a polycrystalline diamond table including:
nanocrystalline diamond present in an amount greater than zero weight percent to less than about 45 weight percent of the polycrystalline diamond table, the nanocrystalline diamond exhibiting an average diamond grain size of about 1 nm to about 50 nm;
an amount of polycrystalline diamond grains including:
a first amount of polycrystalline diamond grains present in an amount of about 75 weight percent to about 99 weight percent, the first amount of polycrystalline diamond grains exhibiting an average diamond grain size of about 10 μm to about 40 μm;
a second amount of polycrystalline diamond grains forming the balance of the polycrystalline diamond grains, the second amount of polycrystalline diamond grains exhibiting an average grain size of about 1 μm to about 10 μm; and
a catalyst material distributed throughout at least a portion thereof; and
a substrate bonded to the polycrystalline diamond table.
2. The polycrystalline diamond compact of claim 1 wherein the nanocrystalline diamond comprises greater than zero weight percent to about 0.1 weight percent of the polycrystalline diamond table.
3. The polycrystalline diamond compact of claim 1 wherein the nanocrystalline diamond comprises about 0.1 weight percent to about 0.5 weight percent of the polycrystalline diamond table.
4. The polycrystalline diamond compact of claim 1 wherein the nanocrystalline diamond comprises greater than zero weight percent to about 1 weight percent of the polycrystalline diamond table.
5. The polycrystalline diamond compact of claim 1 wherein the nanocrystalline diamond comprises greater than zero weight percent to about 1.5 weight percent of the polycrystalline diamond table.
6. The polycrystalline diamond compact of claim 1 wherein the nanocrystalline diamond comprises greater than zero weight percent to about 2 weight percent of the polycrystalline diamond table.
7. The polycrystalline diamond compact of claim 1 wherein the nanocrystalline diamond comprises ultra-dispersed diamond grain structures.
8. The polycrystalline diamond compact of claim 1 wherein the nanocrystalline diamond comprises a residual amount of at least one member selected from the group consisting of amorphous carbon and carbon onion.
9. The polycrystalline diamond compact of claim 1 wherein a region of the polycrystalline diamond table is substantially free of the catalyst material.
10. The polycrystalline diamond compact of claim 1 wherein the polycrystalline diamond table is capable of cutting a distance of at least 1868 linear feet in a granite workpiece during a vertical turret lathe thermal stability test.
11. The polycrystalline diamond compact of claim 1 wherein the catalyst material comprises a metal-solvent catalyst.
12. The polycrystalline diamond compact of claim 1 wherein substrate comprises a cemented carbide substrate.
13. A rotary drill bit, comprising:
a bit body adapted to engage a subterranean formation during drilling; and
a plurality of polycrystalline diamond cutting elements affixed to the bit body, wherein at least one of the polycrystalline diamond cutting elements comprises the polycrystalline diamond compact according to claim 1 .
14. The rotary drill bit of claim 13 wherein a region of the polycrystalline diamond table is substantially free of the catalyst material.
15. The rotary drill bit of claim 13 wherein the polycrystalline diamond table is capable of cutting a distance of at least 1868 linear feet in a granite workpiece during a vertical turret lathe thermal stability test.
16. A polycrystalline diamond compact, comprising:
a polycrystalline diamond body including:
nanocrystalline diamond present in an amount greater than zero weight percent to less than about 45 weight percent of the polycrystalline diamond body, the nanocrystalline diamond exhibiting an average diamond grain size of about 1 nm to about 50 nm;
an amount of polycrystalline diamond grains including:
a first amount of polycrystalline diamond grains present in an amount of about 75 weight percent to about 99 weight percent, the first amount of polycrystalline diamond grains exhibiting an average diamond grain size of about 10 μm to about 40 μm; and
a second amount of polycrystalline diamond grains forming the balance of the polycrystalline diamond grains, the second amount of polycrystalline diamond grains exhibiting an average grain size of about 1 μm to about 10 μm;
a catalyst material distributed throughout at least a portion thereof.
17. The polycrystalline diamond compact of claim 16 wherein a region of the polycrystalline diamond body is substantially free of the catalyst material.
18. A rotary drill bit, comprising:
a bit body adapted to engage a subterranean formation during drilling; and
a plurality of polycrystalline diamond cutting elements affixed to the bit body, wherein at least one of the polycrystalline diamond cutting elements comprises the polycrystalline diamond compact according to claim 16 .
19. A polycrystalline diamond compact, comprising:
a polycrystalline diamond body including a catalyst material distributed throughout at least a portion thereof, the polycrystalline diamond body fabricated according to a process comprising:
mixing a plurality of sp 2 -carbon-containing particles and a plurality of diamond particles to form a mixture; and
sintering the mixture in the presence of the catalyst material to form the polycrystalline diamond body;
wherein the plurality of sp 2 -carbon-containing particles was present in the mixture in an effective amount such that the polycrystalline diamond body is capable of cutting a distance of at least 1868 linear feet in a granite workpiece during a vertical turret lathe thermal stability test without removal of the catalyst material from the polycrystalline diamond body.
20. The polycrystalline diamond compact of claim 19 wherein the distance is at least 2135 linear feet.
21. The polycrystalline diamond compact of claim 19 wherein at least a portion of the plurality of sp 2 -carbon-containing particles comprise a plurality of nanocrystalline diamond particles.
22. The polycrystalline diamond compact of claim 19 wherein at least a portion of the plurality of sp 2 -carbon-containing particles comprise a plurality of ultra-dispersed diamond particles.
23. The polycrystalline diamond compact of claim 19 wherein the amount of the plurality of sp 2 -carbon-containing particles is greater than zero to about 5 weight percent of the mixture.
24. The polycrystalline diamond compact of claim 19 wherein the amount of the sp 2 -carbon-containing particles is greater than zero weight percent to about 1 weight percent of the mixture.
25. The polycrystalline diamond compact of claim 19 wherein the amount of the plurality of sp 2 -carbon-containing particles is greater than zero weight percent to about 2 weight percent of the mixture.