Silica glass having improved properties
View Patent ↗The invention relates to a silica glass compound having improved physical and chemical properties. In one embodiment, the present invention relates to a silica glass having a desirable brittleness in combination with a desirable density while still yielding a glass composition having a desired hardness and desired strength relative to other glasses. In another embodiment, the present invention relates to a silica glass composition that contains at least about 85 mole percent silicon dioxide and up to about 15 mole percent of one or more dopants selected from F, B, N, Al, Ge, one or more alkali metals (e.g., Li, Na, K, etc.), one or more alkaline earth metals (e.g., Mg, Ca, Sr, Ba, etc.), one or more transition metals (e.g., Ti, Zn, Y, Zr, Hf, etc.), one or more lanthanides (e.g., Ce, etc.), or combinations of any two or more thereof.
1. A silica glass composition comprising:
(i) at least about 85 mole percent silicon dioxide; and
(ii) from 0.2 to about 15 mole percent of one or more dopants selected from B, N, Al, Ge, one or more alkali metals, one or more alkaline earth metals, one or more transition metals, one or more lanthanides, or combinations of any two or more thereof, wherein the silica glass composition contains OH in a concentration of from about 0.5 ppm to about 1000 ppm, a halogen concentration of less than about 100 ppm, and up to about 0.5 mole percent of one or more impurities selected from, refractory metal concentration.
2. The silica glass composition of claim 1 , wherein the amount of the one or more dopants in the silica glass composition is in the range of about 0.25 mole percent to about 15 mole percent.
3. The silica glass composition of claim 1 , wherein the amount of the one or more dopants in the silica glass composition is in the range of about 0.1 mole percent to about 10 mole percent.
4. The silica glass composition of claim 1 , wherein the amount of the one or more dopants in the silica glass composition is in the range of about 0.1 mole percent to about 8 mole percent.
5. The silica glass composition of claim 1 , wherein the silica glass composition has a brittleness that is in the range of about 4 μm −1/2 to about 10 μm −1/2 .
6. The silica glass composition of claim 1 , wherein the silica glass composition has a brittleness that is in the range of about 5 μm −1/2 to about 9 μm −1/2 .
7. The silica glass composition of claim 1 , wherein the silica glass composition has a brittleness that is in the range of about 6 μm −1/2 to about 8 μm −1/2 .
8. The silica glass composition of claim 1 , wherein the silica glass composition has a hardness in the range of about 350 HV and about 1300 HV.
9. The silica glass composition of claim 1 , wherein the silica glass composition has a hardness in the range of about 400 HV and about 1250 HV.
10. The silica glass composition of claim 1 , wherein the silica glass composition has a hardness in the range of about 800 HV and about 1200 HV.
11. The silica glass composition of claim 1 , wherein the silica glass composition has a density in the range of about 2.1 g/cc to about 2.5 g/cc.
12. The silica glass composition of claim 1 , wherein the silica glass composition has a density in the range of about 2.15 g/cc to about 2.45 g/cc.
13. The silica glass composition of claim 1 , wherein the silica glass composition has a density in the range of about 2.2 g/cc to about 2.4 g/cc.
14. The silica glass composition of claim 1 , wherein the silica glass composition has a density in the range of about 2.2 g/cc to about 2.35 g/cc.
15. The silica glass composition of claim 1 , wherein the silica glass composition has a refractory metal concentration of less than about 1000 ppm.
16. The silica glass composition of claim 1 , wherein the silica glass composition has a refractory metal concentration of less than about 750 ppm.
17. The silica glass composition of claim 1 , wherein the silica glass composition has a refractory metal concentration of less than about 500 ppm.
18. The silica glass composition of claim 1 , wherein the silica glass composition has a refractory metal concentration of less than about 250 ppm.
19. The silica glass composition of claim 1 , wherein the silica glass composition has a fracture toughness in the range of about 0.5 to about 1 mega Newtons per meter squared.
20. The silica glass composition of claim 1 , wherein the silica glass composition has a fracture toughness in the range of about 0.6 to about 1 mega Newtons per meter squared.
21. The silica glass composition of claim 1 , wherein the silica glass composition has a fracture toughness in the range of about 0.7 to about 1 mega Newtons per meter squared.
22. The silica glass composition of claim 1 , wherein the silica glass composition has an annealing temperature (T A ) of at least about 650° C.
23. The silica glass composition of claim 1 , wherein the silica glass composition has an annealing temperature (T A ) of at least about 850° C.
24. The silica glass composition of claims 1 , wherein the silica glass composition has an annealing temperature (T A ) of at least about 1050° C.
25. The silica glass composition of claim 1 , wherein the silica glass composition has an annealing temperature (T m ) of at least about 1200° C.
26. The silica glass composition of claim 1 , wherein the silica glass composition has an melting temperature (T m ) of at least about 1850° C.