Polyester coating composition for metal substrates comprising oxirane-functional acrylic resin
View Patent ↗The present invention provides novel packaging articles, e.g., food and beverage cans. Preferred cans typically comprise a body portion and an end portion, wherein at least one of the body and end portions are aluminum and are coated on at least one major surface with a coating composition of the present invention. Suitable coating compositions of the present invention comprise: one or more polyester resins, wherein at least one of the polyester resins has a glass transition temperature (“T g ”) less than about 50° C., and wherein the polyester resin is formed by the reaction of one or more polyacid molecules and one or more polyol molecules; and a crosslinker. The present invention also provides a method of making such cans.
1. An article, comprising:
a metal beverage can having a body portion and an end portion, wherein the end portion is an aluminum beverage can end coated on an interior surface with a coating obtained from a coating composition comprising:
between about 60 and 95 weight percent of one or more polyester resins, based on solids content of the coating composition, wherein at least one polyester resin has a Tg of less than about 50° C.; and
an oxirane-functional acrylic resin, wherein the acrylic resin is present in an amount up to about 20% by weight of the coating composition, based upon the total resin solids in the coating composition;
wherein the coating composition is substantially free of mobile BPA and aromatic glycidyl ether compounds; and
wherein the coating on the interior surface of the beverage can end passes less than 10 milliamps of current while being exposed for 4 seconds to an electrolyte solution containing 1% by weight of NaCl dissolved in deionized water.
2. The article of claim 1 , wherein the coating composition includes a crosslinker.
3. The article of claim 2 , wherein the coating composition includes 5 to 40% by weight of crosslinker, based upon the total weight of the resin solids in the coating composition.
4. The article of claim 2 , wherein the coating composition includes 15 to 25% by weight of crosslinker, based upon the total weight of the resin solids in the coating composition.
5. The article of claim 3 , wherein the crosslinker comprises a phenoplast resin.
6. The article of claim 5 , wherein the phenoplast resin comprises a condensation product of component (i) selected from the group consisting of formaldehyde or acetaldehyde and component (ii) selected from the group consisting of phenol, cresol, p-phenylphenol, p-tert-butylphenol, p-tert-amylphenol, and cyclopentylphenol.
7. The article of claim 3 , wherein the crosslinker comprises an aminoplast resin.
8. The article of claim 3 , wherein the crosslinker comprises a benzoguanamine-formaldehyde resin.
9. The article of claim 1 , wherein the coating composition includes between 65 and 85 weight percent of one or more polyester resins, based on solids content of the coating composition.
10. The article of claim 1 , wherein the coating composition, based on solids content of the coating composition, includes between 60 and 95 weight percent of the at least one polyester resin having a Tg of less than about 50° C.
11. The article of claim 1 , wherein the at least one polyester resin having a Tg of less than about 50° C. has a number average molecular weight of between 5,000 and 12,000 Daltons.
12. The article of claim 1 , wherein the at least one polyester resin having a Tg of less than about 50° C. has a number average molecular weight of at least 4,000 Daltons, an acid number below about 5, and a hydroxyl number below about 20.
13. The article of claim 1 , wherein the at least one polyester resin having a Tg of less than about 50° C. is formed by the reaction of one or more polyacids and one or more polyols, wherein the one or more polyacids comprise adipic, azelaic, cyclohexane dicarboxylic, dimer fatty acid, fumaric, isophthalic, maleic, phthalic, sebacic, succinic, terephthalic acids, anhydrides and esters thereof, or mixtures thereof.
14. The article of claim 1 , wherein the at least one polyester resin having a Tg of less than about 50° C. is formed by the reaction of one or more polyacids and one or more polyols, wherein the one or more polyacids includes sebacic acid.
15. The article of claim 1 , wherein the at least one polyester resin having a Tg of less than about 50° C. is formed by the reaction of one or more polyacids and one or more polyols, wherein the one or more polyacids includes dimer fatty acid.
16. The article of claim 1 , wherein the at least one polyester resin having a Tg of less than about 50° C. is formed by the reaction of (i) one or more polyols and (ii) a mixture of polyacids comprising sebacic acid, terephthalic acid, and isophthalic acid.
17. The article of claim 1 , wherein the at least one polyester resin having a Tg of less than about 50° C. is formed by the reaction of (i) one or more polyols and (ii) a mixture of polyacids comprising dimer fatty acid, terephthalic acid, and isophthalic acid.
18. The article of claim 1 , wherein the oxirane-functional acrylic resin is present in the coating composition in an amount from 2 to 15% by weight of the coating composition, based upon the total resin solids in the coating composition.
19. The article of claim 1 , wherein the oxirane-functional acrylic resin is present in the coating composition in an amount from 2 to 10% by weight of the coating composition, based upon the total resin solids in the coating composition.
20. The article of claim 1 , wherein the oxirane-functional acrylic resin is present in the coating composition in an amount from 6 to 10% by weight of the coating composition, based upon the total resin solids in the coating composition.
21. The article of claim 1 , wherein the oxirane-functional acrylic resin has pendant glycidyl groups.
22. The article of claim 21 , wherein the oxirane-functional acrylic resin includes 30 to 80% by weight of a monomer containing a glycidyl group.
23. An article, comprising:
an aluminum beverage can end coated on an interior surface with a coating obtained from a coating composition comprising:
between about 60 and 95 weight percent of one or more polyester resins, based on solids content of the coating composition, wherein at least one polyester resin has a Tg of less than about 50° C. and an acid number of less than about 5; and
an oxirane-functional acrylic resin, wherein the acrylic resin is present in the coating composition in an amount from 2 to 20% by weight of the coating composition, based upon the total resin solids in the coating composition;
wherein the coating composition is substantially free of mobile and bound BPA and aromatic glycidyl ether compounds.