Compositions having multiple responses to excitation radiation and methods for making same
View Patent ↗The present invention relates to a composition having a first response to a first electromagnetic radiation and, after intermediate exposure to a second electromagnetic radiation, a second response to the first electromagnetic radiation, different from the first response. In one aspect, the composition exhibits a regenerated first response to the first electromagnetic radiation after exposure to a third electromagnetic radiation.
1. A method for authenticating an article by using a regenerable composition comprising a plurality of forms having a plurality of responses, the method comprising:
subjecting the composition to a first electromagnetic radiation and generating a first response;
applying a second electromagnetic radiation to transform the composition from a first form having the first response to a second form having a second response to the first electromagnetic radiation that is different from the first response; and
subjecting the composition to the first electromagnetic radiation and generating the second response,
wherein the composition comprises a host material, an emissive material, and an emission modifier, and
wherein the composition is incorporated into a security feature for authenticating the article.
2. The method of claim 1 , wherein the first response and/or the second response comprise electromagnetic radiation in the ultraviolet spectrum.
3. The method of claim 1 , wherein the first response and/or the second response comprise electromagnetic radiation in the infrared spectrum.
4. The method of claim 1 , wherein the first response and/or the second response comprise electromagnetic radiation in the visible spectrum.
5. The method of claims claim 1 , wherein the composition exhibits a regenerated first response to the first electromagnetic radiation after exposure to a third electromagnetic radiation.
6. The method of claim 1 , wherein the host material comprises an oxygen-containing compound selected from the group consisting of Y 2 O 3 , Y 2 GdAl 5 O 12 , Y 3 Al 5 O 12 , Y 3 Al 4 GaO 12 , YBO 3 , Y 0.76 Gd 0.24 BO 3 , YPO 4 , YSiO 5 , LaBO 3 , LaPO 4 , La 2 O 3 , LaAlO 3 , LuAlO 3 , La 3 Al 5 O 12 , LaSiO 5 and ReP 5 O 14 , a sulfide, a fluoride, an oxynitride, an oxysulfide, and an oxyfluoride.
7. The method of claim 1 , wherein the emissive material and/or the emission modifier comprise a lanthanide or a transition metal.
8. The method of claim 1 , wherein the composition comprises substantially spherical particles.
9. The method of claim 1 , wherein the composition has a particle size distribution such that at least about 90 volume percent of the particles are not larger than twice the average particle size.
10. The method of claim 1 , further comprising printing the composition onto the article.