Electrophoretic fluid
View Patent ↗The present invention is directed to a display fluid comprising charged composite pigment particles dispersed in a solvent. The composite pigment particles have a density which matches to the density of the solvent in which they are dispersed. A display fluid comprising the composite pigment particles provides improved display performance.
1. A display fluid comprising a charge control agent and charged composite pigment particles dispersed in a hydrocarbon solvent, wherein each of said composite pigment particles consisting of at least one organic core pigment particle, an organic polymer shell, and steric stabilizer polymers, wherein each of the steric stabilizer polymers is chemically bonded on the surface of the organic polymer shell, and the polymer content determined by total weight of the shell and the steric stabilizer polymers divided by total weight of the core pigment particles, the shell, and the steric stabilizer polymers is 30% to 70% by weight, the fluid is an electrophoretic fluid, and the steric stabilizer polymers are selected from the group consisting of: polyethylene, polypropylene, polyester, polysiloxane, and a mixture thereof.
2. The fluid of claim 1 , wherein the density of the composite pigment particles substantially matches to that of the solvent.
3. The fluid of claim 2 , wherein the difference between the density of the composite pigment particles and the density of the solvent is less than 2 g/cm 3 .
4. The fluid of claim 1 , wherein said core pigment particle is surface treated.
5. The fluid of claim 1 , wherein said core pigment particle is not surface treated.
6. The fluid of claim 1 , wherein said shell is formed from polyacrylate, polyurethane, polyurea, polyethylene, polyester, or polysiloxane.
7. The fluid of claim 1 , wherein the total weight of the shell and the steric stabilizer polymers in the total weight of the core pigment particles, the shell, and the steric stabilizer polymers is 40% to 60% by weight.
8. The fluid of claim 1 , wherein said shell is completely incompatible or relatively incompatible with the solvent.
9. The fluid of claim 1 , wherein the surface of the shell comprises functional groups to enable charge generation or interaction with the charge control agent.
10. The fluid of claim 1 , wherein the composite pigment particles are made from dispersion polymerization or living radical dispersion polymerization.
11. The fluid of claim 1 , further comprising a second type of charged pigment particles which are charged composite particles.
12. The fluid of claim 1 , further comprising a second type of charged pigment particles which are formed from a conventional microencapsulation technique.
13. The fluid of claim 1 , wherein no more than 5% of said shell is miscible with the display fluid.
14. The fluid of claim 1 , wherein no more than 1% of said shell is miscible with the display fluid.
15. The fluid of claim 1 , wherein said shell is formed from a polymer material having a polar functionality on a main chain or a side chain.
16. The fluid of claim 1 , wherein said shell is formed from monomers selected from the group consisting of styrene, methyl acrylate, methyl methacrylate, n-butyl acrylate, n-butyl methacrylate, t-butyl acrylate, t-butyl methacrylate, vinyl pyridine, n-vinyl pyrrolidone, 2-hydoxyethyl acrylate, 2-hydroxyethyl methacrylate and dimethylaminoethyl methacrylate.