IP Library Granted Patent US 8,608,982
Granted Patent B1
US 8,608,982 · App. 13/558,114 · Granted Dec 17, 2013

Recycling organic compounds from gasifier syngas condensate

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Quick Facts
Patent No.
US 8,608,982
App. No.
13/558,114
Granted
Dec 17, 2013
Kind
B1
Abstract

Systems and methods for producing a synthetic gas are provided. A feedstock can be gasified within a gasifier to produce a raw syngas. The raw syngas can be processed within a processing device to produce a processed syngas. The processed syngas can be separated into a vapor phase, an organic phase, and an aqueous phase within a separator. The organic phase can be introduced to the gasifier. The aqueous phase can be introduced to a stripper to provide steam and a condensate, and the steam can then be introduced to the gasifier.

Claims (34)

1. A method for producing a synthetic gas, comprising:

gasifying a feedstock within a gasifier to produce a raw syngas;

processing the raw syngas within a processing device to produce a processed syngas;

separating the processed syngas into a vapor phase, an organic phase, and an aqueous phase within a separator;

introducing the organic phase to the gasifier;

introducing the aqueous phase to a stripper to provide steam and a condensate; and

introducing the steam into the gasifier.

2. The method of claim 1 , wherein the processed syngas comprises contaminants including at least one of benzene, toluene, xylene, naphthalenes, oxygen-substituted one and two-ring aromatics, phenol, phenanthracene, ethane, ethylene, and propane.

3. The method of claim 2 , wherein greater than about 40 mol % of the contaminants present in the processed syngas are recycled back to the gasifier via the organic phase and the steam.

4. The method of claim 1 , further comprising introducing a heat transfer medium to the stripper, wherein the heat transfer medium has a pressure between about 4,100 kPa and about 4,500 kPa.

5. The method of claim 1 , wherein the steam has a pressure between about 3,400 kPa and about 3,800 kPa.

6. The method of claim 5 , wherein a mixing zone in the gasifier where at least one of the organic phase and the steam is introduced has a pressure between about 3,400 kPa and about 3,800 kPa.

7. The method of claim 1 , further comprising:

vaporizing the organic phrase to provide a vaporized organic phase; and

introducing the vaporized organic phase to the gasifier.

8. The method of claim 1 , wherein processing the raw syngas further comprises:

removing particulates from the raw syngas with a particulate control device to provide a filtered syngas;

increasing a moisture content of the filtered syngas with a saturator to provide a saturated syngas; and

converting carbon monoxide in the saturated gas into carbon dioxide with a gas shift device to provide the processed syngas.

9. The method of claim 8 , further comprising introducing at least a portion of the condensate to the saturator.

10. A method for producing a synthetic gas, comprising;

gasifying a feedstock within a gasifier to produce a raw syngas;

processing the raw syngas within a processing device to produce a processed syngas, wherein the processed syngas comprises contaminants;

separating the processed syngas into a vapor phase, an organic phase, and an aqueous phase within a separator, wherein the organic phase and the aqueous phase each include at least a portion of the contaminants;

introducing the organic phase to the gasifier;

stripping at least a portion of the contaminants from the aqueous phase in the presence of a heat transfer medium within a stripper to provide a contaminant steam and a condensate, wherein the heat transfer medium has a pressure between about 3,900 kPa to about 4,800 kPa; and

introducing the contaminant steam to the gasifier.

11. The method of claim 10 , wherein the contaminants comprise at least one of benzene, toluene, xylene, naphthalenes, oxygen-substituted one and two-ring aromatics, phenol, phenanthracene, ethane, ethylene, and propane.

12. The method of claim 10 , wherein the processed syngas has a contaminant content between about 50 ppmv and about 4,000 ppmv.

13. The method of claim 10 , wherein the organic phase has a contaminant content between about 40 mol % and about 99 mol %.

14. The method of claim 10 , wherein the aqueous phase has a contaminant content between about 0.1 mol % and about 20 mol %.

15. The method of claim 10 , wherein the contaminant steam has a contaminant content between about 0.1 mol % and about 20 mol %.

16. The method of claim 10 , wherein the condensate has a contaminant content between about 0.1 mol % and about 10 mol %.

17. The method of claim 1 , wherein greater than about 40 mol % of the contaminants present in the processed syngas are recycled back to the gasifier via the organic phase and the contaminant steam.

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Jun 30, 2025
From: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
To: KELLOGG BROWN & ROOT LLC
Reel/Frame 071570/0242 →
SECURITY INTEREST Recorded Apr 25, 2018
From: KELLOGG BROWN & ROOT LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 046022/0413 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2012
From: ABUGHAZALEH, JOHN; ARIYAPADI, SIVA; MANN, DAVID P.
To: KELLOGG BROWN & ROOT LLC
Reel/Frame 028642/0366 →