IP Library Granted Patent US 8,716,430
Granted Patent B2
US 8,716,430 · App. 13/559,657 · Granted May 6, 2014

Aramid copolymer

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Quick Facts
Patent No.
US 8,716,430
App. No.
13/559,657
Granted
May 6, 2014
Kind
B2
Abstract

The invention concerns polymer comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, made by a process comprising the steps of: (a) forming a slurry of b mole percent DAPBI and y mole percent PPD in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight percent of the organic solvent, DAPBI and PPD being present in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and (b) contacting the slurry of step a) with a stoichiometric amount of terephthaloyl dichloride to form a product comprising the polymer; wherein the sum of y+b is 100 and the product of b×c is 225 or greater.

Claims (4)

1. A polymer comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride (TCl), having a polydispersity index of 1 to 1.8 and an oligomer content of 1.0 weight percent or less.

2. The polymer of claim 1 having a polydispersity index of 1 to 1.5.

3. The polymer of claim 1 having an oligomer content of 0.75 weight percent or less.

4. The polymer of claim 1 having an oligomer content of 0.5 weight percent or less.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 25, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT SAFETY & CONSTRUCTION, INC.
Reel/Frame 049585/0450 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 19, 2012
From: MALLON, FREDERICK K.
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 028809/0244 →