IP Library Granted Patent US 8,603,887
Granted Patent B2
US 8,603,887 · App. 13/560,348 · Granted Dec 10, 2013

Method for depositing a silicon oxide layer of same thickness on silicon and on silicon-germanium

Inventors: Didier Dutartre (Meylan, FR); Nicolas Breil (Wappingers Falls, NY); Yves Campidelli (Le Moutaret, FR); Olivier Gourhant (Goncelin, FR)
Assignees: STMicroelectronics S.A.; STMicroelectronics (Crolles 2) SAS; International Business Machines Corporation
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Quick Facts
Patent No.
US 8,603,887
App. No.
13/560,348
Granted
Dec 10, 2013
Kind
B2
Abstract

A method for depositing a silicon oxide layer on a substrate including a silicon region and a silicon-germanium region, including the steps of: forming a very thin silicon layer having a thickness ranging from 0.1 to 1 nm above silicon-germanium; and depositing a silicon oxide layer on the substrate.

Claims (23)

1. A method for depositing a silicon oxide layer on a substrate, the substrate comprising a silicon region and a silicon-germanium region, the method comprising:

forming, above the silicon-germanium region, a very thin silicon layer having a thickness between 0.1 and 1 nm;

depositing, on the silicon layer and the silicon region, a silicon oxide layer; and

wherein the silicon-germanium region is formed of a silicon-germanium layer having an upper surface substantially at a same level as an upper surface of the silicon region,

wherein forming the silicon layer comprises forming the silicon layer in an epitaxy chamber previously used to form the silicon-germanium region.

2. The method of claim 1 , wherein depositing the silicon oxide layer comprises depositing the silicon oxide layer by chemical vapor deposition.

3. The method of claim 1 , further comprising, prior to depositing the silicon oxide layer, performing chemical cleaning.

4. The method of claim 1 , further comprising:

forming the silicon-germanium region in the epitaxy chamber in the presence of a germanium precursor and of a silicon precursor, wherein

forming the silicon layer further comprises, after forming the silicon-germanium region, stopping introduction of the germanium precursor into the expitaxy chamber.

5. The method of claim 4 , further comprising decreasing a temperature of the substrate prior to or during the forming of the silicon layer.

6. The method of claim 5 , wherein the temperature of the substrate is between 550 and 650° C. during the forming of the silicon-germanium region, and wherein the temperature of the substrate is between 450 and 550° C. during the forming of the very thin silicon layer.

7. The method of claim 4 , wherein the silicon precursor is a first silicon precursor, and wherein forming the silicon layer further comprises, after forming the silicon-germanium region:

stopping introduction of the silicon precursor into the epitaxy chamber, and

introducing a second silicon precursor into the expitaxy chamber, the second silicon precursor being a more chlorinated silicon precursor species than the first silicon precursor.

8. The method of claim 4 , wherein forming the silicon layer further comprises, after forming the silicon-germanium region, introducing HCl gas into the epitaxy chamber.

9. A method for depositing a silicon oxide layer on a substrate, the substrate comprising a silicon region and a silicon-germanium region, the method comprising:

forming, above the silicon-germanium region and at a rate less than or equal to 0.1 nm/minute, a silicon layer having a thickness between 0.1 and 1 nm;

depositing, on the silicon layer and the silicon region, a silicon oxide layer; and

wherein the silicon-germanium region is formed of a silicon-germanium layer having an upper surface substantially at a same level as an upper surface of the silicon region.

10. The method of claim 9 , wherein forming the silicon layer at the rate less than or equal to 0.1 nm/minute comprises forming the silicon layer at a rate less than or equal to 0.01 nm/minute.

11. The method of claim 9 , wherein forming the silicon layer at the rate less than or equal to 0.1 nm/minute comprises forming the silicon layer at a rate between 0.01 nm/minute and 0.1 nm/minute.

12. The method of claim 9 , wherein forming the silicon layer comprises forming the silicon layer in an epitaxy chamber previously used to form the silicon-germanium region.

Assignments (3)
CHANGE OF NAME Recorded Jan 21, 2024
From: STMICROELECTRONICS SA
To: STMICROELECTRONICS FRANCE
Reel/Frame 066357/0693 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY DATA PREVIOUSLY RECORDED ON REEL 029399 FRAME 0068. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT LISTS STMICROELECTRONICS (CROLLES 2) SAS, BUT THIS ENTITY WAS INADVERTENTLY OMITTED FROM THE RECORDATION COVER SHEET. Recorded Jan 23, 2014
From: DUTARTE, DIDIER; CAMPIDELLI, YVES; GOURHANT, OLIVIER; BREIL, NICOLAS
To: STMICROELECTRONICS S.A.; STMICROELECTRONICS (CROLLES 2) SAS; INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 032118/0388 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 4, 2012
From: DUTARTRE, DIDIER; CAMPIDELLI, YVES; GOURHANT, OLIVIER; BREIL, NICOLAS
To: STMICROELECTRONICS S.A; INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 029399/0068 →
Priority Claims (1)
FR 11 56990 · Jul 29, 2011 · national
Continuity (1)
Related Publication 20130072032A1 · Mar 21, 2013