Electrophotographic photoreceptor, process cartridge, and image forming apparatus
View Patent ↗An electrophotographic photoreceptor includes a conductive support, and an undercoat layer, a charge generation layer, and a charge transport layer that are provided in this order on the conductive support, wherein the undercoat layer includes at least metallic oxide particles, a reactive acceptor substance including an anthraquinone structure expressed by the following Formula 1, and a binder resin, the charge generation layer includes hydroxygallium phthalocyanine as a charge generation material, and a reflectance of incident light having a wavelength of 780 nm on a surface of the charge generation layer when the charge transport layer is removed is 17% or greater: wherein the anthraquinone structure expressed by Formula 1 is bonded to another structure at a position of *, and thus forms the reactive acceptor substance, and in Formula 1, n1 represents an integer of 1 to 7.
1. An electrophotographic photoreceptor comprising:
a conductive support; and
an undercoat layer, a charge generation layer, and a charge transport layer that are provided in this order on the conductive support,
wherein the undercoat layer includes at least metallic oxide particles, a reactive acceptor substance including an anthraquinone structure expressed by the following Formula 1, and a binder resin,
the charge generation layer includes hydroxygallium phthalocyanine as a charge generation material formed at a dip coating speed between 55 mm/min and 65 mm/min, and
a reflectance of incident light having a wavelength of 780 nm on a surface of the charge generation layer when the charge transport layer is removed is 17% or greater:
wherein the anthraquinone structure expressed by Formula 1 is bonded to another structure at a position of *, and thus forms the reactive acceptor substance, and in Formula 1, n1 represents an integer of from 1 to 7, and
wherein in the Formula 1, the another structure bonded at the position of * is an alkoxy group.
2. The electrophotographic photoreceptor according to claim 1 ,
wherein the reflectance is 20% or greater.
3. The electrophotographic photoreceptor according to claim 1 ,
wherein in the Formula 1, n1 is 1 to 4.
4. The electrophotographic photoreceptor according to claim 1 ,
wherein in the Formula 1, another structure bonded at the position of * is an alkoxy group having from 1 to 8 carbon atoms.
5. The electrophotographic photoreceptor according to claim 1 ,
wherein an amount of the reactive acceptor substance added of the Formula 1 is 0.1% by weight to 10% by weight in the undercoat layer.
6. The electrophotographic photoreceptor according to claim 1 ,
wherein an amount of the reactive acceptor substance added of the Formula 1 is 0.5% by weight to 5% by weight in the undercoat layer.
7. The electrophotographic photoreceptor according to claim 1 ,
wherein the charge transport layer includes a compound that has a charge transport ability and has a butadiene structure expressed by the following Formula 2, and a polycarbonate copolymer including a repeating unit expressed by the following Formula 3 and a repeating unit expressed by the following Formula 4:
wherein in Formula 2, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 each may be the same as, or different from each other, and represent a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, or a substituted or unsubstituted aryl group, and m1 and n2 represent 0 or 1;
wherein in Formulas 3 and 4, R 7 , R 8 , R 9 , and R 10 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or an aryl group having 6 to 12 carbon atoms, and X represents a phenylene group, a biphenylene group, a naphthylene group, a linear or branched alkylene group, or a cycloalkylene group.
8. The electrophotographic photoreceptor according to claim 7 ,
wherein in the Formula 2, m1 and n2 are 1.
9. The electrophotographic photoreceptor according to claim 7 ,
wherein in the Formula 4, X is a cycloalkylene group.
10. A process cartridge comprising:
the electrophotographic photoreceptor according to claim 1 ; and
at least one selected from the group consisting of a charging unit that charges a surface of the electrophotographic photoreceptor, a developing unit that develops an electrostatic latent image formed on the electrophotographic photoreceptor with a developer to form a toner image, and a toner removing unit that removes a toner remaining on the surface of the electrophotographic photoreceptor.
11. An image forming apparatus comprising:
the electrophotographic photoreceptor according to claim 1 ;
a charging unit that charges a surface of the electrophotographic photoreceptor;
an electrostatic latent image forming unit that exposes the charged surface of the electrophotographic photoreceptor to form an electrostatic latent image;
a developing unit that develops the electrostatic latent image with a developer to form a toner image; and
a transfer unit that transfers the toner image onto a transfer medium.
12. The image forming apparatus according to claim 11 ,
wherein the charging unit is a contact-type charging unit.
13. The image forming apparatus according to claim 11 ,
wherein the charging potential by the contact-type charging unit is 650 V or greater in terms of absolute value.
14. The image forming apparatus according to claim 11 ,
wherein the charging potential by the contact-type charging unit is 700 V or greater in terms of absolute value.