IONIC/IONOGENIC COMB COPOLYMER COMPOSITIONS AND PERSONAL CARE PRODUCTS CONTAINING THE SAME
Ionic and ionogenic comb copolymers are disclosed along with personal care products that employ them as a modifier that results in increased sensory attributes and increased effectiveness in the deposition of actives and can also act as a thickening agent. The copolymer includes one or more repeating units derived from olefinically unsaturated anionic or anionogenic or zwitterionic comonomers, and one or more repeating units having the formula in which Y is a moiety forming part of a copolymer backbone, Z is a moiety that exhibits association with other Z moieties or with other moieties within the ultimate formulation in which the copolymer will be employed, and b is a bond or moiety that links the Z moiety to the Y moiety. In certain embodiments, the copolymer also includes repeating units derived from acrylamide monomers, olefinically unsaturated hydrophilic monomers or other olefinically unsaturated monomers.
1 . A comb copolymer comprising:
A) one or more repeating units derived from at least one member selected from the group consisting of olefinically unsaturated anionic, anionogenic and zwitterionic comonomers; and
B) one or more repeating units having the formula
wherein Y is a moiety forming part of the copolymer backbone, Z is a moiety that exhibits association with other Z moieties or with other moieties within a formulation in which the copolymer will be employed, and b is a bond or moiety that links the Z moiety to the Y moiety; wherein the concentration of ionic and ionogenic repeats in the copolymer is between about 10 and about 450 meq per 100 grams of polymer, the weight of associative moieties Z is between about 3 and about 40 grams per 100 grams of polymer and the ratio of associative moieties Z to ionic and ionogenic repeats is between about 0.025 and about 1.3.
2 . The comb copolymer of claim 1 , further comprising one or more repeating units derived from a monomer selected from at least one of the following groups:
C) acrylamide monomers;
D) one or more olefinically unsaturated hydrophilic monomers that are not A, B or C; or
E) one or more olefinically unsaturated monomers that are not A, B, C or D.
3 . The comb copolymer of claim 2 , comprising one or more repeating units derived from monomers selected from at least two of groups C, D or E.
4 . The comb copolymer of claim 3 , comprising one or more repeating units derived from monomers selected from each of groups C, D and E.
5 . The comb copolymer of claim 1 wherein the repeating units of Group B comprise surfactant repeating units.
6 . The comb copolymer of claim 1 wherein Z comprises at least one member selected from the group consisting of alkyl, fluoroalkyl, silicone and silane.
7 . The comb copolymer of claim 1 wherein A comprises at least one comonomer having a formula:
R 1 and R 2 are independently either H or CH 3 ; a is between 0-50 and b is between 0-50.
8 . The comb copolymer of claim 1 wherein a three percent (solids) weight solution of the comb copolymer in water at pH 7.0±1.0 has a viscosity at 25° C. of less than about 250 cP.
9 . A personal care product comprising
a cosmetic base media; and
about 0.1% to about 20% by weight of the comb copolymer of any one of claims 1 to 4 , or of any one of claims 1 to 8 .
10 . The personal care product of claim 9 , further comprising an active ingredient, wherein the comb copolymer increases the deposition of the active ingredient to a keratinous substrate by at least 10% over a personal care product having a same formulation without the comb copolymer.
11 . A personal care composition comprising:
a cosmetic base media and at least one comb copolymer comprising:
A) one or more repeating units derived from at least one member selected from the group consisting of olefinically unsaturated anionic, anionogenic and zwitterionic comonomers; and
B) one or more repeating units having the formula
wherein Y is a moiety forming part of the copolymer backbone, Z is a moiety that exhibits association with other Z moieties or with other moieties within the composition, and b is a bond or moiety that links the Z moiety to the Y moiety.
12 . The composition of claim 11 comprising at least two repeating units.
13 . The composition of claim 11 wherein A comprises zwitterionic comonomers.
14 . The composition of claim 11 wherein the repeating units of Group B comprise surfactant repeating units.
15 . The composition of claim 11 wherein Z comprises at least one member selected from the group consisting of alkyl, fluoroalkyl, silicone and silane.
16 . The composition of claim 11 wherein comonomer A comprises at least one comonomer having a formula:
R 1 and R 2 are independently either H or CH 3 ; a is between 0-50 and b is between 0-50.
17 . The composition of claim 11 wherein Z comprises about 10 to about 18 carbon atoms.
18 . The composition of claim 11 wherein the repeating units of Group B comprise hydrophobic repeating units.
19 . The composition of claim 11 wherein b comprises at least one of urethane and urea linkages.
20 . The composition of claim 11 wherein Group B comprises at least one of sulphonic and phosphonic acid repeating units.
21 . The composition of claim 11 wherein the comb copolymer is not crosslinked.