IP Library Granted Patent US 9,349,961
Granted Patent B2
US 9,349,961 · App. 13/571,442 · Granted May 24, 2016

Organic electroluminescent element material, organic electroluminescent element composition, organic electroluminescent element, display device, and lighting device

Inventors: Koichiro Iida (Kanagawa, JP); Hideki Gorohmaru (Kanagawa, JP); Yanjun Li (Kanagawa, JP); Tatsushi Baba (Kanagawa, JP); Tomomi Okamoto (Kanagawa, JP)
Assignee: MITSUBISHI CHEMICAL CORPORATION
H01L51/0039C08G73/026H01L51/0035H01L51/5016
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Quick Facts
Patent No.
US 9,349,961
App. No.
13/571,442
Granted
May 24, 2016
Kind
B2
Abstract

A polymer comprising a repeating unit represented by the following formula (1) and a cross-linkable group wherein Ar 11 to Ar 17 , R 11 , R 12 and r are as defined; and an organic electroluminescent element containing at least one organic layer containing a network polymer formed by cross-linking the polymer, the layer being a hole injection layer or a hole transporting layer.

Claims (32)

1. A polymer, which has a weight-average molecular weight (Mw) of 20,000 or more and a degree of dispersion (Mw/Mn) of 2.5 or less, comprising a repeating unit represented by the following general formula (1) and a cross-linkable group:

wherein:

Ar 11 is a biphenylene group or a terphenylene group,

Ar 12 and Ar 13 each independently represents a divalent aromatic group which may have a substituent,

Ar 14 and Ar 15 each independently represents an aromatic group which may have a substituent,

Ar 16 and Ar 17 each independently represents a direct bond or a divalent aromatic group which may have a substituent, with the proviso that at least one of Ar 16 and Ar 17 represents a divalent aromatic group which may have a substituent,

R 11 and R 12 each independently represents a hydrogen atom, an alkyl group which may have a substituent, or an alkoxy group which may have a substituent,

r represents an integer of from 0 to 5, and

R 11 and R 12 may be connected to each other to form a ring structure,

wherein the repeating unit represented by the above-described general formula (1) may contain the cross-linkable group, and

wherein the cross-linkable group is at least one group selected from the group T of the following cross-linkable groups:

wherein:

R 21 to R 23 each independently represents a hydrogen atom or an alkyl group which may have a substituent,

Ar 21 represents an aromatic group which may have a substituent,

X 1 , X 2 , and X 3 each independently represents a hydrogen atom or a halogen atom, and

R 24 represents a hydrogen atom or a vinyl group,

wherein the benzocyclobutene ring may have substituent(s), and the substituents may be connected to each other to form a ring.

2. An organic electroluminescent element material comprising the polymer of claim 1 .

3. An organic electroluminescent element composition comprising the polymer of claim 1 .

4. An organic electroluminescent element comprising, on a substrate, an anode, a cathode, and one or more organic layers provided between these two electrodes, wherein at least one of the organic layers contains a network polymer formed by cross-linking the polymer of claim 1 .

5. The organic electroluminescent element according to claim 4 , wherein the layer containing the network polymer is a hole injection layer or a hole-transporting layer.

6. The organic electroluminescent element according to claim 4 , wherein the layer containing the network polymer is a hole-transporting layer.

7. The organic electroluminescent element according to claim 5 , which further comprises a luminescent layer, and all of the hole injection layer, the hole-transporting layer, and the luminescent layer are formed by a wet film formation method.

8. A display device comprising the organic electroluminescent element of claim 4 .

9. A lighting device comprising the organic electroluminescent element of claim 4 .

10. The polymer according to claim 1 , wherein the number of the cross-linkable groups which the polymer has per 1000 molecular weight, is from 0.01 to 3.0.

11. The polymer according to claim 1 , wherein the number of the cross-linkable groups which the polymer has per 1000 molecular weight, is from 0.01 to 2.0.

12. The polymer according to claim 1 , wherein the number of the cross-linkable groups which the polymer has per 1000 molecular weight, is from 0.05 to 1.0.

13. The polymer according to claim 1 , wherein the cross-linkable group is a group represented by formula (II-a):

wherein the benzocyclobutene ring in formula (II-a) may have substituent(s), and the substituents may be connected to each other to form a ring.

14. The polymer according to claim 1 , wherein Ar 11 is a biphenylene group.

15. The polymer according to claim 1 , wherein Ar 11 is a terphenylene group.

Assignments (4)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Sep 4, 2017
From: MITSUBISHI CHEMICAL CORPORATION
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043750/0207 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE'S INFORMATION PREVIOUSLY RECORDED ON REEL 029173 FRAME 0709. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Nov 6, 2012
From: IIDA, KOICHIRO; GOROHMARU, HIDEKI; LI, YANJUN; BABA, TATSUSHI; OKAMOTO, TOMOMI
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 029247/0792 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 23, 2012
From: IIDA, KOICHIRO; GOROHMARU, HIDEKI; LI, YANJUN; BABA, TATSUSHI; OKAMOTO, TOMOMI
To: SONY CORPORATION
Reel/Frame 029173/0709 →
Priority Claims (1)
JP 2010-027585 · Feb 10, 2010 · national
Continuity (2)
Continuation PCTJP2011052776 · Feb 9, 2011
Related Publication 20130200337A1 · Aug 8, 2013