Cutting tools with Al—Cr—B—N/Ti—Al—N multilayer coatings
View Patent ↗The present invention relates to a multilayer coating system deposited on at least a portion of a solid body surface and containing in the multilayer architecture Al—Cr—B—N individual layers deposited by means of a physical vapor deposition method characterized in that in at least a portion of the overall thickness of the multilayer coating system the Al—Cr—B—N individual layers are combined with Ti—Al—N individual layers, wherein the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other, and wherein the thickness of the Al—Cr—B—N individual layers is thicker than the thickness of the Ti—Al—N individual layers, and thereby the residual stress of the multilayer coating system is considerably lower in comparison to the residual stress of the corresponding analogical Al—Cr—B—N monolayer coating.
1. A multilayer coating system deposited on at least a portion of a solid body surface and containing in a multilayer architecture Al—Cr—B—N individual layers deposited by means of a physical vapour deposition method characterized in that in at least a portion of the overall thickness of the multilayer coating system at least two Al—Cr—B—N individual layers are combined with at least two Ti—Al—N individual layers, wherein the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other, and wherein the thickness of the Al—Cr—B—N individual layers is greater than the thickness of the Ti—Al—N individual layers, and thereby residual stress of the multilayer coating system is considerably lower in comparison to residual stress of a corresponding analogical Al—Cr—B—N monolayer coating system.
2. The multilayer coating system according to claim 1 characterized in that a thickness ratio of the Al—Cr—B—N individual layers related to the Ti—Al—N individual layers in the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other is 2:1.
3. The multilayer coating system according to claim 1 characterized in that the layer composition of the Al—Cr—B—N layers contained in the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other is Al a Cr b B c N d with a+b+c=1, a=9/5·y, 0.1≦z·0.3 where a, b and c are the atomic fractions determined after element analysis taking only the elements Al, Cr and B into account for the element balance, and where y and z are atomic fractions of Cr and B for at least one alloyed source material target containing aluminum, chromium and boron with the following element composition, AlxCryBz, where x+y+z=1, x=1.8·y and 0.1≦z≦0.3 with x, y and z values are atomic fractions.
4. The multilayer coating system according to claim 1 characterized in that the thickness of the Ti—Al—N and Al—Cr—B—N individual layers in the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other remains constant.
5. The multilayer coating system according to claim 1 characterized in that the element composition of the Al—Cr—B—N individual layers in the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other remains constant.
6. The multilayer coating system according to claim 1 characterized in that the Al—Cr—B—N and Ti—Al—N individual layers in the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other are nano-layers whose corresponding individual thicknesses are each ≦100 nm.
7. The multilayer coating system according to claim 1 characterized in that an additional Ti—Al—N individual layer is deposited between the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other and a substrate surface; and said additional Ti—Al—N individual layer's values of thickness and elements concentration are equal or different to the corresponding values of the Ti—Al—N individual layers contained in the coating portion.
8. The multilayer coating system according to claim 1 characterized in that an additional Al—Cr—B—N individual layer is deposited between the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other and the coating surface; and said additional Al—Cr—B—N individual layer's values of thickness and elements concentration are equal or different to the corresponding values of the Al—Cr—B—N individual layers contained in the coating portion.
9. The multilayer coating system according to claim 7 or 8 characterized in that the additional Ti—Al—N individual layer is deposited directly on the substrate surface and/or the additional Al—Cr—B—N individual layer is deposited as outermost layer.
10. The multilayer coating system according to claim 1 characterized in that an additional adhesion layer not consisting of Ti—Al—N is deposited directly on the substrate surface to improve the coating adhesion to substrate and/or an additional outermost layer not consisting of Al—Cr—B—N is deposited on the coating surface as top layer.
11. The multilayer coating system according to claim 1 characterized in that the overall coating thickness of the multilayer coating system is equal or thicker than 3 μm.
12. The multilayer coating system according to claim 1 characterized in that at least the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other is synthetized by reactive cathodic arc evaporation, wherein due to the deposition using arc evaporation, macro particles of metallic materials from target are present in the coating.
13. The multilayer coating system according to claim 1 characterized in that at least the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other exhibit a face-centered cubic structure in the as-deposited state.
14. The multilayer coating system according to claim 1 characterized in that the outermost layer is an Al—Cr—B—N layer that exhibits the formation of BxNy, wherein x and y are atomic fractions of B and N, respectively.
15. A solid body at least partially coated with a multilayer coating system according to claim 1 .
16. The solid body according to claim 15 characterized in that the solid body is a cutting tool or a forming tool or a stamping tool, or a component or a part of a vehicle, or a component or a part to be used in the motor industry or aerospace industry.
17. The multilayer coating system according to claim 1 wherein the hardness of the multilayer coating system is larger or equal to the hardness of the corresponding analogical Al—Cr—B—N monolayer coating.
18. The multilayer coating system according to claim 1 wherein the coating portion where the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other contains at least three Ti—Al—N and three Al—Cr—B—N individual layers.
19. The multilayer coating system according to claim 8 wherein the Al—Cr—B—N and Ti—Al—N individual layers are deposited alternately one on each other.
20. The multilayer coating system according to claim 1 wherein the overall coating thickness of the multilayer coating system is equal or thicker than 5 μm.