Organic electroluminescent device
View Patent ↗Disclosed is an organic electroluminescent device (organic EL device) that is improved in luminous efficiency, sufficiently secures driving stability, and has a simple configuration. This organic EL device has a light-emitting layer between an anode and a cathode piled one upon another on a substrate and the said light-emitting layer contains a fused polycyclic compound in which seven or more rings are fused together as a host material. The aforementioned fused polycyclic compound has a structure formed by fusing two or more indole rings to a carbazole ring. A specific example thereof is the compound represented by the following formula.
1. An organic electroluminescent device comprising an anode, organic layers containing a phosphorescent light-emitting layer, and a cathode piled one upon another on a substrate wherein at least one organic layer selected from the group consisting of a light-emitting layer, a hole-transporting layer, an electron-transporting layer, a hole-blocking layer, and an electron-blocking layer contains a compound represented by general formula (1);
in general formula (1), Z is a group formed by removing one of Ars from a compound represented by formula (1a); L is an m-valent aromatic hydrocarbon group of 6 to 50 carbon atoms or an m-valent aromatic heterocyclic group of 3 to 50 carbon atoms; m is an integer of 1 to 4 and, when in is 2 or more, Zs may be identical with or different from one another;
in formula (1a), ring A is a hydrocarbon ring represented by formula (1b) and fused to the adjacent rings at arbitrary positions, ring B is a heterocyclic ring represented by formula (1c) and fused to the adjacent rings at arbitrary positions, and n is an integer of 2 to 4; in formulas (1a) and (1b), each R is independently a hydrogen atom, an aliphatic hydrocarbon group of 1 to 10 carbon atoms, an aromatic hydrocarbon group of 6 to 18 carbon atoms, or an aromatic heterocyclic group of 3 to 17 carbon atoms; and in formulas (1a) and (1c), each Ar is independently an aromatic hydrocarbon group of 6 to 50 carbon atoms or an aromatic heterocyclic group of 3 to 50 carbon atoms; however, at least one of L and Ars is an m-valent or monovalent group formed from a compound represented by formula (1d) by removing hydrogen atoms or a hydrogen atom;
in formula (1d), X is a methine group, a nitrogen atom, or C—Ar 1 and at least one of Xs is a nitrogen atom; each Ar 1 is independently an aromatic hydrocarbon group of 6 to 50 carbon atoms or an aromatic heterocyclic group of 3 to 50 carbon atoms.
2. An organic electroluminescent device as described in claim 1 wherein, in general formula (1), m is 1 or 2.
3. An organic electroluminescent device as described in claim 1 wherein, in general formula (1), n is 2.
4. An organic electroluminescent device as described in claim 2 wherein, in general formula (1), formula (1a) is represented by any one of the following formulas (2) to (4);
in formulas (2) to (4), Ar and R respectively have the same meaning as those in formulas (1a), (1b), and (1c).
5. An organic electroluminescent device as described in claim 1 wherein the organic layer containing a compound represented by general formula (1) is a light-emitting layer containing a phosphorescent dopant.