Process for making improved catalysts from clay-derived zeolites
View Patent ↗This invention relates to a process of preparing an improved catalyst comprising a clay derived zeolite. In particular, the invention comprises combining an yttrium compound with a zeolite produced by treating clay with a silica source and under alkaline conditions. The clay derived zeolite can be further combined with conventional matrix and/or binder precursors to form particulates suitable for use as catalysts in fluid catalytic cracking (FCC). Alternatively, the clay that is treated with the silica source and alkaline conditions can be in particulate form having sizes suitable for use in FCC, and the zeolite is produced in situ within the particulate. Yttrium compound is then combined with the zeolite in the particulate, e.g., via impregnation. It has been shown that the addition of the yttrium compound improves zeolite surface area retention, and zeolite stability in catalysts comprising clay derived zeolites.
1. A process for making a catalyst, the process comprising:
(a) treating clay with source of silica and under alkaline conditions to produce clay-derived Y zeolite, and
(b) combining the clay-derived Y zeolite with yttrium compound, wherein yttrium measured as yttrium oxide (Y 2 O 3 ) is present in the combination in an amount of 0.5 to 15% by weight based on the zeolite.
2. A process according to claim 1 , wherein the clay is kaolin or one or more of kaolin clay's characteristic phase transitions.
3. A process according to claim 1 , wherein the alkaline conditions include contacting the clay with a compound selected from the group consisting of alkali hydroxide, silicate, aluminate, and mixtures thereof.
4. A process according to claim 1 , wherein the source of silica is selected from the group consisting of silica gel, colloidal silica, precipitated silica, rice hull ash, sodium silicate, and/or mixtures thereof.
5. A process according to claim 1 , further comprising adding seed to the clay and source of silica.
6. A process according to claim 1 , wherein the zeolite produced in (a) comprises at least one metal impurity.
7. A process according to claim 6 wherein the metal impurity comprises a compound derived from a metal selected from the group consisting of iron, titanium, magnesium, calcium and mixture of two or more thereof.
8. A process according to claim 1 , wherein the zeolite and yttrium compound are combined in (b) with precursors of matrix, and the process further comprises forming particulates.
9. A process according to claim 8 wherein the zeolite produced in (a) is crystalline, and has an average particle size in the range of 0.05 to 10 microns.
10. A process according to claim 8 , wherein the particulates have an average particle size in the range of 20 to 150 microns.
11. A process according to claim 1 wherein the yttrium compound is water soluble yttrium salt.
12. A process according to claim 1 wherein the yttrium compound is selected from the group consisting of yttrium halide, yttrium nitrate, yttrium carbonate, and yttrium sulfate.
13. A process according to claim 1 , wherein the clay in (a) is present in particulates having an average particle size in the range of 20 to 150 microns, and zeolite is produced in situ within the clay particulate.
14. A process according to claim 13 wherein the yttrium compound is combined with the zeolite by impregnation of yttrium into the particulate.
15. A process according to claim 14 wherein the impregnation is carried out with an aqueous solution comprising yttrium salt in a concentration in the range of 1 to 40% by weight measured as yttrium oxide.
16. A process according to claim 13 , further comprising drying the zeolite particulates after its combination with the yttrium compound in (b).
17. A process according to claim 1 , wherein the yttrium compound comprises rare earth oxide in a weight ratio of 0.01 to 1 rare earth oxide to yttrium oxide.
18. A process according to claim 1 , wherein the yttrium compound consists essentially of yttrium compound or an yttrium moiety.
19. A process according to claim 8 , wherein the precursor of matrix comprises inorganic oxide selected from the group consisting of silica, alumina, silica alumina, and clay.
20. A process according to claim 1 , wherein the zeolite and yttrium compound are combined in (b) with a precursor of binder.
21. A catalyst made by a process in accordance with claim 1 .
22. A catalyst made by a process in accordance with claim 21 , wherein the catalyst contains no more than 5% by weight rare earth, measured as oxide, based on the zeolite.
23. A process according to claim 11 , wherein the yttrium compound comprises rare earth oxide in a weight ratio of 0.01 to 1 rare earth oxide to yttrium oxide.
24. A process according to claim 12 , wherein the yttrium compound comprises rare earth oxide in a weight ratio of 0.01 to 1 rare earth oxide to yttrium oxide.
25. A process according to claim 11 , wherein the yttrium compound consists essentially of yttrium compound or an yttrium moiety.
26. A process according to claim 12 , wherein the yttrium compound consists essentially of yttrium compound or an yttrium moiety.