Semiconducting polymers

1. Conjugated polymer of formula II

wherein

A is on each occurrence identically or differently a repeating unit of formula I,

wherein

one of X 1 and X 2 is selected from S, Se and O, and the other is selected from CH, CR x , and N,

one of X 3 and X 4 is selected from S, Se and O, and the other is selected from CH, CR x , and N,

R on each occurrence identically or differently denotes primary alkyl with 1 to 30 C atoms, secondary alkyl with 3 to 30 C atoms, or tertiary alkyl with 4 to 30 C atoms, wherein in all these groups one or more H atoms are optionally replaced by F, or —CO—R y , —CO—O—R y , or —O—CO—R y , wherein RN is straight-chain, branched or cyclic alkyl with 1 to 30 C atoms, in which one or more non-adjacent C atoms are optionally replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —CR 0 ═CR 00 — or —C≡C— and in which one or more H atoms are optionally replaced by F, Cl, Br, I or CN, or R y is aryl or heteroaryl having 2 to 30 C atoms that is unsubstituted or substituted by one or more non-aromatic groups R 1 as defined below,

R x is on each occurrence identically or differently straight-chain, branched or cyclic alkyl with 1 to 15 C atoms, in which one or more non-adjacent C atoms are optionally replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—O—, —CR 0 ═CR 00 — or —C≡C— and in which one or more H atoms are optionally replaced by F, Cl, Br, I or CN,

R 0 and R 00 are independently of each other H or optionally substituted carbyl or hydrocarbyl optionally comprising one or more hetero atoms,

R 1 is on each occurrence identically or differently H, halogen, —CN, —NC, —NCO, —NCS, —OCN, —SCN, —C(═O)NR 0 R 00 , —C(═O)X 0 , —C(═O)R 0 , —NH 2 , —NR 0 R 00 , —SH, —SR 0 , —SO 3 H, —SO 2 R 0 , —OH, —NO 2 , —CF 3 , —SF 5 , optionally substituted silyl, carbyl or hydrocarbyl with 1 to 40 C atoms that is optionally substituted and optionally comprises one or more hetero atoms, or P-Sp-,

P is a polymerisable group,

Sp is a spacer group or a single bond,

X 0 is halogen

Ar is on each occurrence identically or differently optionally substituted aryl or heteroaryl,

Y 1 and Y 2 are independently of each other H, F, Cl or CN,

m is on each occurrence identically or differently 1, 2 or 3,

x is on each occurrence identically or differently 0 or 1, wherein in at least one sub-unit ((Ar) y -(A) x ) x is 1,

y is on each occurrence identically or differently 0 or 1,

n is an integer >1.

2. Polymer according to claim 1 , selected of formula IIa

wherein A, Ar, m, n, x and y have the meanings of claim 1 , the benzene rings are optionally substituted with one or more groups R 1 , and

R 2 and R 3 have independently of each other one of the meanings of R 1 , or denote H, —CH 2 Cl, —CHO, —CH═CH 2 , —SiR′R″R′″, —SnR′R″R′″, —BR′R″, —B(OR′)(OR″), —B(OH) 2 , or P-Sp, wherein P and Sp are as defined above, and R′, R″ and W′ have independently of each other one of the meanings of R 0 , and R′ and R″ may also form a ring together with the hetero atom to which they are attached.

3. Polymer according to claim 1 , wherein Ar is selected from the group consisting of selenophene-2,5-diyl, thiophene-2,5-diyl, thieno[3,2-b]thiophene-2,5-diyl, thieno[2,3-b]thiophene-2,5-diyl, selenopheno[3,2-b]selenophene-2,5-diyl, selenopheno[2,3-b]selenophene-2,5-diyl, selenopheno[3,2-b]thiophene-2,5-diyl, selenopheno[2,3-b]thiophene-2,5-diyl, benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl, 2,2-dithiophene, 2,2-diselenophene, dithieno[3,2-b:2′,3′-d]silole-5,5-diyl, 4H-cyclopenta[2,1-b:3,4-b′]dithiophene-2,6-diyl, 2,7-di-thien-2-yl-carbazole, 2,7-di-thien-2-yl-fluorene, indaceno[1,2-b:5,6-b′]dithiophene-2,7-diyl, benzo[1″,2″:4,5;4″,5″:4′,5′]bis(silolo[3,2-b:3′,2′-b′]thiophene)-2,7-diyl, 2,7-di-thien-2-yl-indaceno[1,2-b:5,6-b′]dithiophene, 2,7-di-thien-2-yl-benzo[1″,2″:4,5;4″,5″:4′,5′]bis(silolo[3,2-b:3′,2′-b′]thiophene)-2,7-diyl, 2,7-di-thien-2-yl-phenanthro[1,10,9,8-c,d,ef,g]carbazole, 4,7-di-thien-2-yl-benzo[1,2,3]thiadiazole, 4,7-di-thien-2-yl-benzo[1,2,3]selenadiazole, 3,4-difluorothiophene-2,5-diyl, 2,5-di-thien-2-yl-thieno[3,4-b]pyrazine, 5,8-di-thien-2-yl-quinoxaline, thieno[3,4-b]thiophene-4,6-diyl, 4,6-di-thien-2-yl-thieno[3,4-b]thiophene, thieno[3,4-b]thiophene-6,4-diyl, 6,4-di-thien-2-yl-thieno[3,4-b]thiophene, 3,6-di-thien-2-yl-pyrrolo[3,4-c]pyrrole-1,4-dione, all of which are unsubstituted, or mono- or polysubstituted.

4. Polymer according to claim 1 , wherein in the unit of formula I, X 1 and X 3 are S, and X 2 and X 4 are CH.

5. Polymer according to claim 1 , wherein R is —CO—R y or —COO—R y , wherein R y is primary alkyl with 1 to 30 C atoms, secondary alkyl with 3 to 30 C atoms, or tertiary alkyl with 4 to 30 C atoms, wherein in all these groups one or more H atoms are optionally replaced by F.

6. Polymer blend comprising one or more polymers according to claim 1 and one or more additional polymers, wherein these additional polymers are selected from polymers having semiconducting, charge transport, hole/electron transport, hole/electron blocking, electrically conducting, photoconducting or light emitting properties.

7. Formulation comprising one or more polymers of claim 1 , and one or more solvents, preferably selected from organic solvents.

8. Optical, electrooptical or electronic component or device comprising one or more polymers, polymer blends or formulations according to claim 1 .

9. Component or device according to claim 8 , characterized in that it is selected from the group consisting of organic field effect transistors (OFET), thin film transistors (TFT), integrated circuits (IC), logic circuits, capacitors, radio frequency identification (RFID) tags, devices or components, organic light emitting diodes (OLED), organic light emitting transistors (OLET), flat panel displays, backlights of displays, organic photovoltaic devices (OPV), solar cells, laser diodes, photoconductors, photodetectors, electrophotographic devices, electrophotographic recording devices, organic memory devices, sensor devices, charge injection layers, charge transport layers or interlayers in polymer light emitting diodes (PLEDs), Schottky diodes, planarising layers, antistatic films, polymer electrolyte membranes (PEM), conducting substrates, conducting patterns, electrode materials in batteries, alignment layers, biosensors, biochips, security markings, security devices, and components or devices for detecting and discriminating DNA sequences.

10. Component or device according to claim 8 , which is an OFET or a bulk heterojunction OPV device.