Coin-type lithium secondary battery
View Patent ↗A coin-type lithium secondary battery includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The negative electrode includes a negative electrode active material including a silicon alloy material, a conductive agent including a carbon material, and a binder. The silicon alloy material includes a phase A including a lithium-silicon alloy and a phase B including an intermetallic compound of a transition metal element and silicon. In the lithium-silicon alloy, a ratio of lithium atoms relative to silicon atoms is 2.75 to 3.65 in a 100% state-of-charge.
1. A coin-type lithium secondary battery comprising:
a positive electrode;
a negative electrode;
a separator interposed between the positive electrode and the negative electrode; and
a non-aqueous electrolyte,
the negative electrode including a negative electrode active material including a silicon alloy material, a conductive agent comprising a carbon material, and a binder,
the silicon alloy material including a phase A comprising a lithium-silicon alloy and a phase B comprising an intermetallic compound of a transition metal element and silicon, and
a ratio of lithium atoms relative to silicon atoms in the lithium-silicon alloy being 2.75 to 3.65 in a 100% state-of-charge, wherein:
the positive electrode includes a positive electrode active material and the positive electrode active material is a composite oxide including lithium and manganese, and
a charge cutoff voltage is set in a range of 2.8 to 3.3 V.
2. The coin-type lithium secondary battery in accordance with claim 1 , wherein the ratio of the lithium atoms relative to the silicon atoms in the 100% state-of-charge is 2.8 to 3.6.
3. The coin-type lithium secondary battery in accordance with claim 1 , wherein a ratio of the transition metal element relative to the silicon atoms in the silicon alloy material is 0.1 to 0.6.
4. The coin-type lithium secondary battery in accordance with claim 1 , wherein the inter metallic compound is TiSi 2 .
5. The coin-type lithium secondary battery in accordance with claim 1 , wherein the negative electrode active material has an average particle diameter of 2 to 50 μm.
6. The coin-type lithium secondary battery in accordance with claim 1 , wherein a ratio of the conductive agent is 18 to 42 parts by weight relative to 100 parts by weight of the negative electrode active material.
7. The coin-type lithium secondary battery in accordance with claim 1 , wherein the ratio of the conductive agent is 20 to 40 parts by weight relative to 100 parts by weight of the negative electrode active material.
8. The coin-type lithium secondary battery in accordance with claim 1 , wherein the conductive agent is graphite.
9. The coin-type lithium secondary battery in accordance with claim 1 , wherein the binder is a polymer including at least one selected from acrylic acid and methacrylic acid as a monomer unit, or a salt thereof.
10. The coin-type lithium secondary battery in accordance with claim 1 , wherein a ratio of the binder is 1 to 20 parts by weight relative to 100 parts by weight of the negative electrode active material.