Method of manufacturing grain-oriented electrical steel sheet
View Patent ↗Hot rolling is performed on a steel with a predetermined composition containing Ti: 0.0020 mass % to 0.010 mass % and/or Cu: 0.010 mass % to 0.50 mass % to obtain a hot-rolled steel sheet. Annealing is performed on the hot-rolled steel sheet to obtain an annealed steel sheet. Cold rolling is performed on the annealed steel sheet to obtain a cold-rolled steel sheet. Decarburization annealing and nitridation annealing are performed on the cold-rolled steel sheet to obtain a decarburized nitrided steel sheet. Then, finish annealing is performed on the decarburized nitrided steel sheet. When obtaining the decarburized nitrided steel sheet, heating on the cold-rolled steel sheet is started in a decarburizing and nitriding atmosphere, then first annealing is performed at a first temperature within a predetermined range, and then second annealing is performed at a second temperature within a predetermined range.
1. A method of manufacturing a grain-oriented electrical steel sheet, comprising:
hot rolling a steel containing Si: 2.5 mass % to 4.0 mass %, C: 0.02 mass % to 0.10 mass %, Mn: 0.05 mass % to 0.20 mass %, acid-soluble Al: 0.020 mass % to 0.040 mass %, N: 0.002 mass % to 0.012 mass %, S: 0.001 mass % to 0.010 mass %, and P: 0.01 mass % to 0.08 mass %, further containing at least one selected from the group consisting of Ti: 0.0020 mass % to 0.010 mass % and Cu: 0.010 mass % to 0.50 mass %, and a balance composed of Fe and inevitable impurities, to obtain a hot-rolled steel sheet;
annealing the hot-rolled steel sheet to obtain an annealed steel sheet;
cold rolling the annealed steel sheet to obtain a cold-rolled steel sheet;
decarburization annealing and nitridation annealing the cold-rolled steel sheet to obtain a decarburized nitrided steel sheet; and
finish annealing the decarburized nitrided steel sheet,
wherein the step of decarburization annealing and nitridation annealing comprises:
heating the cold-rolled steel sheet in a decarburizing and nitriding atmosphere;
performing first annealing at a first temperature within a range of 700° C. to 850° C. and with a holding time of at least 15 seconds to effectively diffuse the nitrogen entering a surface of the cold-rolled steel sheet into a central portion of the cold-rolled steel sheet; and
then performing second annealing at a second temperature within a range of 860° C. to 950° C. and with a holding time of at least 15 seconds to adjust primary recrystallized grains to a sufficient size.
2. A method of manufacturing a grain-oriented electrical steel sheet, comprising:
hot rolling a steel containing Si: 2.5 mass % to 4.0 mass %, C: 0.02 mass % to 0.10 mass %, Mn: 0.05 mass % to 0.20 mass %, acid-soluble Al: 0.020 mass % to 0.040 mass %, N: 0.002 mass % to 0.012 mass %, S: 0.001 mass % to 0.010 mass %, and P: 0.01 mass % to 0.08 mass %, further containing at least one selected from the group consisting of Ti: 0.010 mass % or less and Cu: 0.50 mass % or less to satisfy at least one of Ti: 0.0020 mass % or more and Cu: 0.010 mass % or more, and a balance composed of Fe and inevitable impurities, to obtain a hot-rolled steel sheet;
annealing the hot-rolled steel sheet to obtain an annealed steel sheet;
cold rolling the annealed steel sheet to obtain a cold-rolled steel sheet;
decarburization annealing and nitridation annealing the cold-rolled steel sheet to obtain a decarburized nitrided steel sheet; and
finish annealing the decarburized nitrided steel sheet,
wherein the step of decarburization annealing and nitridation annealing comprises:
heating the cold-rolled steel sheet in a decarburizing and nitriding atmosphere;
performing first annealing at a first temperature within a range of 700° C. to 850° C. and with a holding time of at least 15 seconds to effectively diffuse the nitrogen entering a surface of the cold-rolled steel sheet into a central portion of the cold-rolled steel sheet; and
then performing second annealing at a second temperature within a range of 860° C. to 950° C. and with a holding time of at least 15 seconds to adjust primary recrystallized grains to a sufficient size.
3. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 or 2 , wherein the steel further contains at least one selected from the group consisting of Cr: 0.010 mass % to 0.20 mass %, Sn: 0.010 mass % to 0.20 mass %, Sb: 0.010 mass % to 0.20 mass %, Ni: 0.010 mass % to 0.20 mass %, Se: 0.005 mass % to 0.02 mass %, Bi: 0.005 mass % to 0.02 mass %, Pb: 0.005 mass % to 0.02 mass %, B: 0.005 mass % to 0.02 mass %, V: 0.005 mass % to 0.02 mass %, Mo: 0.005 mass % to 0.02 mass %, and As: 0.005 mass % to 0.02 mass %.
4. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 or 2 , wherein the steel further contains at least one selected from a group consisting of Cr: 0.20 mass % or less, Sn: 0.20 mass % or less, Sb: 0.010 mass % to 0.20 mass %, Ni: 0.010 mass % to 0.20 mass %, Se: 0.005 mass % to 0.02 mass %, Bi: 0.005 mass % to 0.02 mass %, Pb: 0.005 mass % to 0.02 mass %, B: 0.005 mass % to 0.02 mass %, V: 0.005 mass % to 0.02 mass %, Mo: 0.005 mass % to 0.02 mass %, and As: 0.005 mass % to 0.02 mass %.
5. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 , wherein
the Ti content in the steel is 0.0020 mass % to 0.0080 mass %,
the Cu content in the steel is 0.01 mass % to 0.10 mass %, and
a relation of 20×[Ti]+[Cu]≦0.18 is satisfied where the Ti content (mass %) in the steel is expressed as [Ti] and the Cu content (mass %) is expressed as [Cu].
6. The method of manufacturing a grain-oriented electrical steel sheet according to claim 3 , wherein
the Ti content in the steel is 0.0020 mass % to 0.0080 mass %,
the Cu content in the steel is 0.01 mass % to 0.10 mass %, and
a relation of 20×[Ti]+[Cu]≦0.18 is satisfied where the Ti content (mass %) in the steel is expressed as [Ti] and the Cu content (mass %) is expressed as [Cu].
7. The method of manufacturing a grain-oriented electrical steel sheet according to claim 4 , wherein
the Ti content in the steel is 0.0020 mass % to 0.0080 mass %,
the Cu content in the steel is 0.01 mass % to 0.10 mass %, and
a relation of 20×[Ti]+[Cu]≦0.18 is satisfied where the Ti content (mass %) in the steel is expressed as [Ti] and the Cu content (mass %) is expressed as [Cu].
8. The method of manufacturing a grain-oriented electrical steel sheet according to claim 5 , wherein a relation of 10×[Ti]+[Cu]≦0.07 is satisfied.
9. The method of manufacturing a grain-oriented electrical steel sheet according to claim 6 , wherein a relation of 10×[Ti]+[Cu]≦0.07 is satisfied.
10. The method of manufacturing a grain-oriented electrical steel sheet according to claim 7 , wherein a relation of 10×[Ti]+[Cu]≦0.07 is satisfied.
11. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 , wherein the hot rolling the steel is performed after heating the steel to a temperature of 1250° C. or lower.
12. The method of manufacturing a grain-oriented electrical steel sheet according to claim 3 , wherein the hot rolling the steel is performed after heating the steel to a temperature of 1250° C. or lower.
13. The method of manufacturing a grain-oriented electrical steel sheet according to claim 5 , wherein the hot rolling the steel is performed after heating the steel to a temperature of 1250° C. or lower.
14. The method of manufacturing a grain-oriented electrical steel sheet according to claim 8 , wherein the hot rolling the steel is performed after heating the steel to a temperature of 1250° C. or lower.
15. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 or 2 ,
wherein the steel further contains at least one selected from the group consisting of Cr: 0.010 mass % to 0.20 mass % and Sn: 0.010 mass % to 0.20 mass %.
16. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 or 2 ,
wherein the steel further contains at least one selected from the group consisting of Cr: 0.20 mass % or less and Sn: 0.20 mass % or less.
17. The method of manufacturing a grain-oriented electrical steel sheet according to claim 2 , wherein
the Ti content in the steel is 0.0020 mass % to 0.0080 mass %,
the Cu content in the steel is 0.01 mass % to 0.10 mass %, and
a relation of 20×[Ti]+[Cu]≦0.18 is satisfied where the Ti content (mass %) in the steel is expressed as [Ti] and the Cu content (mass %) is expressed as [Cu].
18. The method of manufacturing a grain-oriented electrical steel sheet according to claim 17 , wherein a relation of 10×[Ti]+[Cu]≦0.07 is satisfied.
19. The method of manufacturing a grain-oriented electrical steel sheet according to claim 2 , wherein the hot rolling the steel is performed after heating the steel to a temperature of 1250° C. or lower.