Semiconductive polymer composition comprising polar copolymer
View Patent ↗The present invention relates to a semiconductive polymer composition comprising: —an ethylene copolymer (A) comprising methyl(meth)acrylate co-monomer units, wherein the ethylene copolymer (A) has a melt temperature of 80° C. or below, and—carbon black, wherein the ethylene copolymer (A) is produced in a autoclave high pressure reactor or in a multi-feed tubular reactor; to a semiconductive polymer composition comprising—an ethylene copolymer (A) comprising methyl(meth)acrylate, comonomer units; and—carbon black, wherein ethylene copolymer (A) is characterized in that the fraction obtained in the first fractionation step (fraction 1) in the fractionation method of ethylene copolymer (A) as described herein, is present in an amount of not more than 40 wt. % based on the total amount of the ethylene copolymer (A); and to a cable comprising a semiconductive layer comprising the semiconductive polymer composition and to the use of the semiconductive polymer composition in the preparation of a semiconductive layer of a power cable.
1. A semiconductive polymer composition comprising:
an ethylene copolymer (A) comprising methyl(meth)acrylate co-monomer units, wherein the ethylene copolymer (A) has a melt temperature of 80° C. or below, and
carbon black,
wherein the ethylene copolymer (A) is produced in a autoclave high pressure reactor or in a multi-feed tubular reactor, and
a polymer (B) which is an alpha-olefin copolymer comprising:
alpha-olefin monomer units (Q) selected from one of C 3 to C 10 alpha-olefins; and
monomer units (R) selected from one or more alpha-olefin(s) different from (Q), wherein one of the monomer units (R) is 1-butene.
2. A semiconductive polymer composition comprising:
an ethylene copolymer (A) comprising methyl(meth)acrylate co-monomer units; and
carbon black,
wherein ethylene copolymer (A) is characterized in that when a first fraction of a sample of the ethylene copolymer is obtained using a solvent of 4% xylene/96% 2-propanol (v/v) according to a Preparative Fractionation Method of Ethylene Copolymer (A), the first fraction contains an amount of not more than 40 wt. % of the sample of the ethylene copolymer (A), and
a polymer (B) which is an alpha-olefin copolymer comprising:
alpha-olefin monomer units (Q) selected from one of C 3 to C 10 alpha-olefins; and
monomer units (R) selected from one or more alpha-olefin(s) different from (Q), wherein one of the monomer units (R) is 1-butene.
3. The semiconductive polymer composition according to claim 1 , wherein the ethylene copolymer (A) has a crystallization temperature of not more than 70° C.
4. The semiconductive polymer composition according to claim 1 , wherein the ethylene copolymer (A) is present in the composition in an amount of 20 wt % or more and 65 wt. % or less, based on the total weight of the semiconductive polymer composition.
5. The semiconductive polymer composition according to claim 1 , wherein the ethylene copolymer (A) has a content of methyl (meth)acrylate comonomer units of 5 wt. % or more, based on the total weight of the ethylene copolymer (A).
6. The semiconductive polymer composition according to claim 1 , wherein the ethylene copolymer (A) has a content of methyl(meth)acrylate comonomer units of 20 wt. % or more, based on the total weight of the ethylene copolymer (A).
7. The semiconductive polymer composition according to claim 1 , further comprising a cross-linking agent.
8. A power cable comprising a conductor, an insulation layer and at least one semiconductive layer comprising a semiconductive polymer composition as defined in claim 1 .
9. The power cable according to claim 8 , wherein the insulating layer comprises an ethylene homo- or copolymer.
10. A method for the preparation of a semiconductive layer of a power cable, wherein at least one semiconductive layer of said power cable is formed by the semiconductive polymer composition according to claim 1 .
11. The method according to claim 10 , wherein the semiconductive layer is strippable.