Pressure sensitive adhesive composition
The present invention relates to a pressure sensitive adhesive composition, a protective film for optical elements, an optical element and a liquid crystal display device. The present invention may provide a pressure sensitive adhesive composition and a protective film for optical elements, having a high peel force at a low rate and a low peel force at a high rate, the balance of which is excellently maintained and showing excellent wettablity to an adherend, durability, repeelability, transparency and antistatic performance.
1. A protective film for optical elements comprising a pressure sensitive adhesive layer formed by hardening a pressure sensitive adhesive composition comprising an acrylic resin with a weight average molecular weight of 450,000 to 1,100,000, a multi-functional crosslinker, a photopolymerizable compound and a photo initiator,
wherein the multi-functional crosslinker having at least three functional groups, and is present in an amount of 0.5 to 2 parts by the weight relative to 100 parts by weight of the acrylic resin,
wherein the photopolymerizable compound comprising a multifunctional acrylate having at least 3 (meth)acryloyl groups and is present in an amount of 3 to 20 parts by weight relative to 100 parts by weight of the acrylic resin,
wherein the photoinitiator is present in an amount of 0.1 to 10 parts by weight relative to 100 parts by weight of the acrylic resin,
wherein after hardening, the composition comprises an interpenetrating polymer network structure having said acrylic resin cross-linked by the multi-functional crosslinker and a polymerized product of the photopolymerizable compound, and has a peel force to a TAC (triacetyl cellulose) sheet of 10 to 40 gf/inch, as measured at a peel angle of 180° and a peel rate of 0.3 m/min, and a peel force to a TAC sheet of 80 to 300 gf/inch, as measured at a peel angle of 180° and a peel rate of 30 m/min, and
wherein a ratio (X 2 /X 1 ) of the peel force (X 2 ) to a TAC sheet, as measured at a peel angle of 180° and a peel rate of 30 m/min, to the peel force (X 1 ) to a TAC sheet, as measured at a peel angle of 180° and a peel rate of 0.3 m/min, after hardening the composition, is 5 to 13.
2. The protective film for optical elements according to claim 1 , wherein the acrylic resin has a weight average molecular weight of 450,000 to 1,000,000.
3. The protective film for optical elements according to claim 1 , further comprising an antistatic agent.
4. The protective film for optical elements according to claim 1 , wherein a gel content in the state including the interpenetrating polymer network structure is 80 to 99%.
5. The protective film for optical elements according to claim 1 , wherein the peel force to a TAC sheet, as measured at a peel angle of 180° and a peel rate of 0.3 m/min, after hardening the composition, is 10 to 30 gf/inch.
6. The protective film for optical elements according to claim 1 , wherein the peel force to a TAC sheet, as measured at a peel angle of 180° and a peel rate of 30 m/min, after hardening the composition, is 100 to 280 gf/inch.
7. The protective film according to claim 1 , wherein the multi-functional crosslinker has four functional groups.
8. The protective film according to claim 1 , wherein the photopolymerizable compound has a molecular weight of less than 1,000.
9. The protective film according claim 1 , wherein the multifunctional cross-linker is a tolylenediisocyanate adduct of trimethylolpropane or N,N,N′,N′-tetraglycidyl ethylenediamine.
10. The protective film according to claim 1 , wherein after hardening, the composition has a gel fraction of 80%-90%, the gel fraction calculated as: gel fraction =B/A×100, wherein A is a mass of the pressure sensitive adhesive composition comprising the interpenetrating polymer network (IPN) structure, and B is a dry mass of insoluble fractions recovered after depositing the pressure sensitive adhesive composition in ethyl acetate at room temperature for 48 hours.
11. The protective film according to claim 1 , wherein the acrylic resin comprises 80-99.8 parts by weight (meth) acrylic acid ester monomers and 0.01-10 parts by weight of cross-linkable monomers, relative to 100 total parts by weight of all acrylic resin monomers.
12. An optical element comprising a substrate; and a protective film according to claim 1 attached to one or both sides of said substrate.
13. The optical element according to claim 12 , wherein the substrate is a polarizing plate, a retardation plate, an optical compensation film, a reflective sheet or a brightness enhancing film.
14. A liquid crystal display device comprising a liquid crystal panel; and an optical element according to claim 13 attached to one or both sides of said liquid crystal panel.