Pressure sensitive adhesive composition
The present invention relates to a pressure sensitive adhesive composition. The present invention may effectively provide a pressure sensitive adhesive where peel forces for both sides are different and an modulus differs along the thickness direction. By applying the pressure sensitive adhesive as above, the present invention may provide, for example, an optical element, such as a polarizing plate, which can effectively inhibit light leakage and shows excellent durability, while being formed to have a thin thickness as well.
1. A pressure sensitive adhesive composition comprising:
an acrylic polymer with an alkyleneoxide group, and
an ultraviolet absorber,
wherein the composition in a hardened state has an average tensile modulus at 25° C. ranging from 10 to 400 MPa,
wherein the composition comprises an interpenetrating polymer network structure having said acrylic polymer in a cross-linked state, the interpenetrating polymer network further comprising a multifunctional acrylate in an amount of 80-100 parts by weight relative to 100 parts by weight of the acrylic polymer, and represents different peel forces in both sides of a single layer sheet shape having a first surface and second surface present opposite to the first surface on hardening the composition into the sheet shape, and
wherein the peel force of the first surface of the sheet shape to glass is from 5 gf/25 mm to 100 gf/25 mm and the peel force of the second surface of the sheet shape to glass is from 265 gf/25 mm to 625 gf/25 mm.
2. The pressure sensitive adhesive composition according to claim 1 , wherein the acrylic polymer has a weight average molecular weight of 400,000 to 2,000,000.
3. The pressure sensitive adhesive composition according to claim 1 , wherein the acrylic polymer comprises a (meth)acrylic acid ester monomer; a monomer of chemical formula 1 and a crosslinkable monomer as a polymerized unit:
[Chemical Formula 1]
wherein, R represents hydrogen or an alkyl group, A represents alkylene, R 1 represents an alkyl group or an aryl group, and n represents a number of 1 to 50.
4. The pressure sensitive adhesive composition according to claim 3 , wherein the monomer of chemical formula 1 is an alkoxy alkyleneglycol(meth)acrylic acid ester, alkoxy dialkyleneglycol(meth)acrylic acid ester, alkoxy trialkyleneglycol(meth)acrylic acid ester, alkoxy tetraalkyleneglycol(meth)acrylic acid ester, alkoxy polyethyleneglycol (meth)acrylic acid ester, a phenoxy alkyleneglycol(meth)acrylic acid ester, phenoxy dialkyleneglycol(meth)acrylic acid ester, phenoxy trialkyleneglycol(meth)acrylic acid ester, phenoxy tetraalkyleneglycol(meth)acrylic acid ester or phenoxy polyalkyleneglycol (meth)acrylic acid ester.
5. The pressure sensitive adhesive composition according to claim 1 , wherein the acrylic polymer in a state cross-linked by a multi-functional crosslinker is included in the interpenetrating polymer network structure.
6. The pressure sensitive adhesive composition according to claim 1 , wherein the ultraviolet absorber is a benzotriazole compound, a benzophenone compound, an oxalanilide compound, a benzoic acid ester compound or a triazine compound.
7. The pressure sensitive adhesive composition according to claim 1 , further comprising a silane coupling agent having an acetoacetate group or a β-cyanoacetyl group.
8. The pressure sensitive adhesive composition according to claim 1 , wherein a gradient of tensile modulus is formed along the thickness direction of the sheet shape in a direction from the first surface to the second surface.
9. The pressure sensitive adhesive composition according to claim 1 , wherein the composition in the hardened state has an average tensile modulus at 25° C. ranging from 65 to 400 MPa.
10. A polarizing plate comprising a polarizer; and a layer of a pressure sensitive adhesive which is formed by hardening the pressure sensitive adhesive composition according to claim 1 formed on one or both sides of said polarizer.
11. A liquid crystal display device comprising a liquid crystal panel; and a polarizing plate according to claim 10 attached to one or both sides of said liquid crystal panel.