Organic electroluminescent member and method for producing organic electroluminescent element
View Patent ↗An organic electroluminescent member comprising: a positive electrode and a negative electrode on a substrate: multiple organic layers which include at least a positive hole transport layer, a light-emitting layer and an electron transport layer, and which are arranged between the positive electrode and the negative electrode; and an electron injection layer arranged between the electron transport layer and the negative electrode. The electron injection layer is formed from at least one selected from the group consisting of alkali metals and compounds containing alkali metals having a melting point of less than 90° C., and at least one selected from the group consisting of alkali metals, alkaline earth metals, compounds containing alkali metals, and compounds containing.
1. An organic electroluminescence member comprising:
a substrate havening thereon an anode, a cathode, a plurality of organic layers including a hole transport layer, a light emitting later and an electron transport layer, the plurality of organic layers being sandwiched between the anode and the cathode, and an electron injection layer located between the electron transport layer and the cathode,
wherein the electron injection layer is formed only with:
at least one selected from the group consisting of an alkali metal having a melting point of less than 90° C. and a compound containing an alkali metal having a melting point of less than 90° C.; and
at least one selected from the group consisting of an alkali metal having a melting point of 90° C. or more, an alkali earth metal having a melting point of 90° C. or more, a compound containing an alkali metal having a melting point of 90° C. or more, and a compound containing an alkali earth metal having a melting point of 90° C. or more.
2. The organic electroluminescence member described in claim 1 ,
wherein the electron injection layer is composed of a first electron injection layer and a second electron injection layer: the first electron injection layer being formed of at least one selected from the group consisting of an alkali metal having a melting point of 90° C. or more, an alkali earth metal having a melting point of 90° C. or more, a compound containing an alkali metal having a melting point of 90° C. or more, and a compound containing an alkali earth metal having a melting point of 90° C. or more; and the second electron injection layer being formed of at least one selected from the group consisting of an alkali metal having a melting point of less than 90° C. and a compound containing an alkali metal having a melting point of less than 90° C.
3. The organic electroluminescence member described in claim 2 ,
wherein the first electron injection layer is formed adjacent to the electron transport layer at a side near to the cathode, and the second electron injection layer is formed between the first electron injection layer and the cathode.
4. The organic electroluminescence member described in claim 1 ,
wherein a heat treatment is carried out to the organic electroluminescence member after forming the electron injection layer, or after forming the cathode, the heat treatment being carried out at a temperature of 80° C. or more and below a glass transition temperature of an organic material used in the organic layer.
5. A method for producing an organic electroluminescence element comprising the steps of:
pasting together a sealing member having a heat curable adhesive agent on a sealing substrate with the organic electroluminescence member described in claim 1 in a manner that a surface of the heat curable adhesive agent have contact with a surface of the cathode of the organic electroluminescence member;
carrying out a heat treatment at a temperature of 80° C. or more and below a glass transition temperature of an organic material used in the organic layer; then
curing the heat curable adhesive agent to form a close-contact sealing structure.