Method for drying granular water-containing gel-like cross-linked polymer
View Patent ↗The present invention is to provide a drying method by which both cost reduction and superior physical properties can be attained in a step which comprises subjecting a water-containing gel-like crosslinked polymer obtained by polymerizing an aqueous monomer solution to fine granulation during or after the polymerization, and drying the resultant particulate water-containing gel-like crosslinked polymer with a through-circulation band dryer. The method has a feature in that the drying conditions over a period from a time of introducing the particulate water-containing gel-like crosslinked polymer into a drying zone of the through-circulation band dryer to a time of reaching a solid content concentration thereof to 80% by weight, satisfy that (1) a difference of temperature between a temperature of hot air blown to a particulate hydrogel layer and a temperature measured after the hot air passes through the particulate hydrogel layer is 20 to 70° C.
1. A method for drying a particulate water-containing gel-like crosslinked polymer which comprises polymerizing acrylic acid or partially neutralized salt thereof with a crosslinking agent in an aqueous solution to obtain a particulate water-containing gel-like crosslinked polymer of a partially neutralized salt of polyacrylic acid containing acrylic acid or salt thereof as a main component and having a solid content concentration of 35% to 75% by weight, and drying the particulate water-containing gel-like crosslinked polymer with a through-circulation dryer using hot air having a temperature of 130 to 230° C. and a dew point of 50 to 80° C.,
wherein over 60% or more of a period from a time of introducing the particulate water-containing gel-like crosslinked polymer into a drying zone of the through-circulation dryer to a time of reaching a solid content concentration thereof to 80% by weight, a difference of temperature (ΔT) between a temperature of hot air blown to a particulate hydrogel layer and a temperature measured after the hot air passes through the particulate hydrogel layer is 20 to 70° C.,
wherein the temperature of the particulate water-containing gel-like crosslinked polymer immediately before being introduced into the drying zone is 40 to 70° C., and the dew point of the hot air used in the through-circulation dryer is varied in multiple stages.
2. The method according to claim 1 , wherein the difference of temperature between a temperature of hot air blown to the particulate hydrogel layer and a temperature measured after the hot air passes through the particulate hydrogel layer is 30° C. to 60° C.
3. The method according to claim 1 , wherein the through-circulation dryer is a through-circulation band dryer.
4. The method according to claim 3 , wherein the through-circulation band dryer has a plurality of chambers.
5. The method according to claim 1 , wherein the temperature of the hot air used in the through-circulation dryer is varied in multiple stages.
6. The method according to claim 1 , wherein over 70% or more of the period until the solid content concentration reaches 80% by weight, the dew point of used hot air is 50 to 80° C.
7. The method according to claim 1 , wherein over 90% or more of the period until the solid content concentration reaches 80% by weight, the dew point of used hot air is 50 to 80° C. and/or the difference of temperature (ΔT) is 20 to 70° C.
8. A method for producing a water absorbent resin, which comprises the method set forth in claim 1 , and further comprising surface crosslinking the particulate water-containing gel-like crosslinked polymer after the drying.
9. The method according to claim 2 , wherein the through-circulation dryer is a through-circulation band dryer.
10. The method according to claim 9 , wherein the through-circulation band dryer has a plurality of chambers.
11. The method according to claim 2 , wherein the temperature of the hot air used in the through-circulation dryer is varied in multiple stages.
12. The method according to claim 3 , wherein the temperature of the hot air used in the through-circulation dryer is varied in multiple stages.
13. The method according to claim 4 , wherein the temperature of the hot air used in the through-circulation dryer is varied in multiple stages.