Affecting the thermoelectric figure of merit (ZT) and the power factor by high pressure, high temperature sintering
A method for increasing the ZT of a material, involves creating a reaction cell including a material in a pressure-transmitting medium, exposing the reaction cell to elevated pressure and elevated temperature for a time sufficient to increase the ZT of the material, and recovering the material with an increased ZT.
1. A method of increasing the ZT of a thermoelectric material, comprising:
exposing a thermoelectric material to elevated pressure and elevated temperature for a time sufficient to increase the ZT of the thermoelectric material, wherein the elevated pressure ranges from about 1 GPa to 20 GPa and the elevated temperature ranges from about 500° C. to about 2500° C.; and
recovering the thermoelectric material with an increased ZT when measured at the pressure and temperature of use,
wherein, when said consolidated blank of thermoelectric material is exposed to a temperature of use, an increased ZT is maintained for an extended period of time as evaluated at 10 days of exposure to the temperature of use, and
wherein the thermoelectric material comprises GeTe—AgSbTe 2 alloys.
2. The method of claim 1 , wherein the elevated pressure ranges from about 2 GPa to about 10 GPa.
3. The method of claim 1 , wherein the elevated pressure ranges from about 3.5 GPa to about 4.5 GPa.
4. The method of claim 1 , wherein the elevated pressure is about 4 GPa.
5. The method of claim 1 , wherein the elevated temperature ranges from about a third of the melting temperature to about 500° C. above the melting point of the thermoelectric material at process pressures.
6. The method of claim 1 , wherein the elevated temperature ranges from a sintering temperature of the thermoelectric material to about a melting point of the thermoelectric material at process pressures.
7. The method of claim 1 , wherein the time sufficient to increase the ZT is from about 30 seconds to about 24 hours.
8. The method of claim 6 , wherein the time sufficient to increase the ZT is from about 5minutes to about 30 minutes.
9. The method of claim 1 , wherein the composition of the thermoelectric material further comprises dopants.