Method to form an aqueous dispersion of an ionomer
View Patent ↗Disclosed is a method for forming an aqueous dispersion of an ionomer composition comprising mixing a solid ionomer composition with water heated to a temperature from about 80 to about 90° C., the solid ionomer composition comprising an ethylene acid copolymer comprising about 18 to about 30 weight % of copolymerized units of acrylic acid or methacrylic acid, based on the total weight of the parent acid copolymer, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the total carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising sodium cations.
1. A method for producing an aqueous dispersion comprising an ionomer composition, the method comprising
(a) providing a solid ionomer composition comprising a parent acid copolymer that comprises copolymerized units of ethylene, about 18 to about 30 weight % of copolymerized units of acrylic acid or methacrylic acid, based on the total weight of the parent acid copolymer, the acid copolymer having a melt flow rate (MFR) from about 200 to about 1000 g/10 min., measured according to ASTM D1238 at 190° C. with a 2160 g load, wherein about 50% to about 70% of the carboxylic acid groups of the copolymer, based on the total carboxylic acid content of the parent acid copolymer as calculated for the non-neutralized parent acid copolymer, are neutralized to carboxylic acid salts comprising sodium cations;
(b) mixing the solid ionomer composition with water heated to a temperature from about 80 to about 90° C. under low shear conditions to provide a heated aqueous ionomer dispersion; and
(c) optionally cooling the heated aqueous ionomer dispersion to a temperature of about 20 to 30° C., wherein the ionomer remains dispersed in the liquid phase.
2. The method of claim 1 wherein the ionomer composition comprises about 0.001 to about 20 weight % of the aqueous dispersion.
3. The method of claim 1 wherein the ionomer composition has a MFR from about 1 to about 20 g/10 min.
4. The method of claim 1 wherein the parent acid copolymer has a MFR from about 250 to about 400 g/10 min.
5. The method of claim 1 wherein the parent acid copolymer is an ethylene methacrylic acid dipolymer having about 18 to about 25 weight % of copolymerized units of methacrylic acid.
6. The method of claim 1 wherein the ionomer composition comprises at least 11 weight % methacrylic acid salt and has a MFR of at least 1 g/10 min.
7. The method of claim 1 wherein about 55% to about 60% of the total carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts and wherein the heating is to a temperature from about 80 to about 85° C.
8. The method of claim 1 wherein (b) comprises (i) adding an article formed from the preformed solid ionomer composition to water at a temperature of about 20 to 30° C. to form a mixture of solid ionomer and water; and subsequently (ii) heating the mixture to a temperature from about 80 to about 90° C.
9. The method of claim 1 wherein (b) comprises adding an article formed from the preformed solid ionomer composition to water preheated to a temperature from about 80 to about 90° C.