Solid oxide fuel cell power plant having a bootstrap start-up system
View Patent ↗The bootstrap start-up system ( 42 ) achieves an efficient start-up of the power plant ( 10 ) that minimizes formation of soot within a reformed hydrogen rich fuel. A burner ( 48 ) receives un-reformed fuel directly from the fuel supply ( 30 ) and combusts the fuel to heat cathode air which then heats an electrolyte ( 24 ) within the fuel cell ( 12 ). A dilute hydrogen forming gas ( 68 ) cycles through a sealed heat-cycling loop ( 66 ) to transfer heat and generated steam from an anode side ( 32 ) of the electrolyte ( 24 ) through fuel processing system ( 36 ) components ( 38, 40 ) and back to an anode flow field ( 26 ) until fuel processing system components ( 38, 40 ) achieve predetermined optimal temperatures and steam content. Then, the heat-cycling loop ( 66 ) is unsealed and the un-reformed fuel is admitted into the fuel processing system ( 36 ) and anode flow ( 26 ) field to commence ordinary operation of the power plant ( 10 ).
1. A solid oxide fuel cell power plant, comprising:
at least one solid oxide fuel cell having:
an electrolyte;
a cathode flow field configured to direct an oxidant reactant flow adjacent to a cathode electrode side of the electrolyte; and
an anode flow field configured to direct a reducing fuel flow adjacent to an anode electrode side of the electrolyte;
a fuel supply;
a fuel processing system in fluid communication with the fuel supply and the anode flow field, the fuel processing system configured to process a hydrogen-rich fuel;
a bootstrap start-up system that includes:
a burner;
a cathode air heat exchanger;
a forming gas supply;
a burner exhaust line in fluid communication between the burner and the cathode air heat exchanger;
a heat-cycling loop blower; and
a heat-cycling loop configured to receive a predetermined fill-volume of a forming gas from the forming gas supply and to circulate the forming gas through the heat -cycling loop blower, through the fuel processing system, through the anode flow field adjacent to the anode electrode side of the electrolyte, and back to the heat-cycling loop blower, the heat -cycling loop configured to cycle heat from the electrolyte during a start-up phase of the power plant until the fuel cell and the fuel processing system reach predetermined start-up temperatures.
2. The solid oxide fuel cell power plant of claim 1 , further comprising a direct fuel cathode air heater including a burner feed line in fluid communication between the fuel supply and the burner.
3. The solid oxide fuel cell power plant of claim 1 , further comprising a cathode inlet line configured to direct heated air from the cathode air heat exchanger to the cathode flow field.
4. The solid oxide fuel cell power plant of claim 1 , wherein the fuel processing system includes a reformer that is configured to be heated to a first operating temperature by the forming gas circulated through a return line of the heat-cycling loop, and the heat-cycling loop further includes a reformer heat exchanger, placed in a first return segment of the heat-cycling loop, upstream of the reformer, the reformer heat exchanger being dimensioned to transfer heat from the forming gas circulated through a middle segment of the heat-cycling loop to the forming gas that flows through the first return segment of the heat -cycling loop to increase a temperature of the reformer.
5. The solid oxide fuel cell power plant of claim 4 , wherein the fuel processing system further includes a desulfurizer configured to be heated to a first operating temperature by the forming gas circulated through the heat-cycling loop through a second return segment of the heat-cycling loop, and the heat-cycling loop further includes a desulfurizer heat exchanger, placed in the second return segment of the heat-cycling loop, upstream of the desulfurizer, the desulfurizer heat exchanger being dimensioned to transfer heat from the forming gas circulating through the middle segment of the heat-cycling loop to the forming gas flowing through the second return segment of the heat-cycling loop to increase a temperature of the desulfurizer.
6. The solid oxide fuel cell power plant of claim 1 , wherein the fuel processing system further includes a first component configured to be heated to a first operating temperature by the forming gas circulated through the heat-cycling loop through a return segment of the heat-cycling loop, and the heat-cycling loop further includes a heat exchanger, placed in the return segment of the heat-cycling loop, upstream of the first component, and the heat-cycling loop also comprises a bypass configured to direct flow of all or a portion of the forming gas through one of the heat exchanger and the return segment of the heat-cycling loop downstream of the first component.