Flux enhancing agent for improving composite polyamide reverse osmosis membrane performance
View Patent ↗The present disclosure describes an additive that may be used in the manufacture of thin-film polyamide composite membranes. Thin-film polyamide composite membranes are used in filtration processes, such as reverse osmosis and nanofiltration. The additive may be an amino-siloxane compound. The amino-siloxane compound includes repeated groups of silicon bonded to oxygen with at least one amine functional group. Optionally, the amino-siloxane compound may also include a hydrophilic group. The additive reacts with an aqueous phase and an organic phase to form a thin polyamide film on a porous substrate.
1. A method for preparing a polyamide composite membrane, the method comprising: reacting an aqueous phase, an organic phase and an additive, wherein the aqueous phase comprises an amine that is different than the additive, the organic phase comprises a polyacyl halide and the additive is a compound selected from the group consisting of:
wherein a and b are integers between 1 and 100 and the sum of a+b is not greater than 100;
wherein a, b and c are integers between 1 and 100, the sum of a+b+c is not greater than 100 and x is an integer between 1 and 50;
wherein R is CH 3 to C 15 H 31 ; X is 75% of —CH 2 CH(OH)CH 2 OH and 25% H; and n is an integer between 1 and 100;
wherein x is either —CH 2 CH(OH)CH 2 OH or H; and n is an integer between 4 and 100;
wherein the reaction occurs at or near the surface of a substrate.
2. The method of claim 1 , wherein the additive is a compound of the formula:
wherein a and b are integers between 1 and 100 and the sum of a+b is less than about 100.
3. The method of claim 1 , wherein the additive is a compound of the formula:
wherein a, b and c are integers between 1 and 100, the sum of a+b+c is less than about 100; and x is an integer between 1 and 50.
4. The method of claim 1 , wherein the additive is a compound of the formula:
wherein R is CH 3 to C 15 H 31 ; X is 75% of —CH 2 CH(OH)CH 2 OH and 25% H; and n is an integer between 1 and about 100.
5. The method of claim 1 , wherein the amine is selected from the group consisting of: cyclic polyfunctional amines; acyclic polyfunctional amines; substituted cyclic polyfunctional amines; aromatic polyfunctional amines; substituted aromatic polyfunctional amines; multi-aromatic ring polyfunctional amines; substituted multi-aromatic ring polyfunctional amines; and combinations thereof.
6. The method of claim 1 , wherein the amine is selected from the group consisting of: piperazine; 1,2-ethanediamaine; methyl piperazine; dimethyl piperazine; m-phenylenediamine; o-phenylenediamine; p-phenylenedamine; chlorophenylenediamine; N,N 1 -dimethyl-1,3-phenylenediamine; benzidine; 3,3 1 -dimethylbenzidene, 3,3 1 -dichlorobenzidine, and combinations thereof.
7. The method of claim 1 , wherein the organic phase comprises a compound selected from the group consisting of: di-carboxylic acid halides; tri-carboxylic acid halides; di-tri carboxylic acid halides; tri-tri carboxylic acid halides; isomeric phthaloyl halides; aromatic di-sulfonyl halides; tri-sulfonyl halides; aromatic di-isocyanates; aromatic tri-isocyanates, aromatic di-chloroformates; aromatic tri-chloroformates, aromatic rings substituted with mixtures of the above and combinations thereof.
8. The method of claim 1 , wherein the organic phase comprises a compound selected from the group consisting of: trimesoyl chloride (1,3,5-benzene tricarboxylic acid chloride), isophthaloyl chloride, terephthaloyl chloride, 1,3,5-cyclohexanetricarbonyl chloride, 1,2,3,4-cyclopentanetetracarbonyl chloride, trimesoyl bromide (1,3,5-benzene tricarboxylic acid bromide), isophthaloyl bromide, terephthaloyl bromide, trimesoyl iodine (1,3,5-benzene tricarboxylic acid iodide), isophthaloyl iodide, terephthaloyl iodide and combinations thereof.
9. The method of claim 1 , wherein the substrate is selected from the group consisting of: fibrous and nanofibrous webs; sintered metals; sintered ceramics; polysulfones; polycarbonates; micro-porous polyolefins; polyamides; polyimides; polynitriles; polyimines; polyphenylene ethers; polyketones; polyetherketones; halogenated polymers; polyvinylidine fluoride and combinations thereof.
10. A method for preparing a polyamide composite membrane, the method comprising: reacting an aqueous phase, an organic phase and an additive, wherein the aqueous phase comprises an amine, the organic phase comprises a polyacyl halide and the additive is a compound of the formula:
wherein R1 and R2 may be the same or different, and are C1-C20 alkyl or alkoxy groups; R3 may be a C1-C4 alkyl group, or H; Q is either —(CH 2 ) 3 — or —CH 2 CH(CH 3 )CH 2 —; X is either —CH 2 CH(OH)CH 2 OH or H; a, b, c, d, e are integers such that the sum of a+b+c+d+e is less than 100, if b is 0, then d or e must be greater than 0, if d is 0, then b or e must be greater than 0; and if e is 0, then b or d must be greater than 0; and, y1, y2, z1, z2 are each integers between 0 to 10;
wherein the reaction occurs at or near the surface of a substrate.
11. A method of filtering an aqueous solution, the method comprising:
filtering the aqueous solution through a polyamide composite membrane prepared by the method of claim 1 in a reverse osmosis process or a nanofiltration process.
12. A composite membrane for reverse osmosis or nanofiltration, the membrane comprising:
a porous substrate;
a polymer layer on a surface of the porous substrate, wherein the polymer layer comprises a polyamide that is a reaction product of an aqueous phase, an organic phase and an additive, wherein the aqueous phase comprises an amine that is different than the additive, the organic phase comprises a polyacyl halide, and the additive is selected from the group consisting of:
wherein a and b are integers between 1 and 100 and the sum of a+b is not greater than 100;
wherein a, b and c are integers between 1 and 100, the sum of a+b+c is not greater than 100 and x is an integer between 1 and 50;
wherein R is CH 3 to C 15 H 31 ; X is 75% of —CH 2 CH(OH)CH 2 OH and 25% H; and n is an integer between 1 and 100;
wherein x is either —CH 2 CH(OH)CH 2 OH or H; and n is an integer between 4 and 100;
13. The membrane of claim 12 , wherein the porous substrate is selected from the group consisting of: fibrous and nanofibrous webs; sintered metals; sintered ceramics; polysulfones; polycarbonates; micro-porous polyolefins; polyamides; polyimides; polynitriles; polyimines; polyphenylene ethers; polyketones; polyetherketones; halogenated polymers; polyvinylidine fluoride and combinations thereof.
14. The membrane of claim 12 , wherein the additive is a compound of the formula:
wherein a and b are integers between 1 and 100 and the sum of a+b is less than about 100.
15. The membrane of claim 12 , wherein the additive is a compound of the formula:
wherein a, b and c are integers between 1 and 100, the sum of a+b+c is less than about 100; and x is an integer between 1 and 50.
16. The membrane of claim 12 , wherein the additive is a compound of the formula:
wherein R is CH 3 to C 15 H 31 ; X is 75% of —CH 2 CH(OH)CH 2 OH and 25% H; and n is an integer between 1 and about 100.
17. A composite membrane for reverse osmosis or nanofiltration, the membrane comprising:
a porous substrate;
a polymer layer on a surface of the porous substrate, wherein the polymer layer comprises a reaction product of an organic phase, an aqueous phase and an additive, wherein the organic phase comprises polyacyl halides, the aqueous phase comprises amines and the additive is a compound of the formula:
wherein R1 and R2 may be the same or different, and are C1-C20 alkyl or alkoxy groups; R3 may be a C1-C4 alkyl group, or H; Q is either —(CH 2 ) 3 — or —CH 2 CH(CH 3 )CH 2 —; X is either —CH 2 CH(OH)CH 2 OH or H; a, b, c, d, e are integers such that the sum of a+b+c+d+e is less than 100, if b is 0, then d or e must be greater than 0, if d is 0, then b or e must be greater than 0; and if e is 0, then b or d must be greater than 0; and, y1, y2, z1, z2 are each integers between 0 to 10.