Hydrogen generator having reactant pellet with concentration gradient
View Patent ↗A hydrogen generator is provided for generating hydrogen gas for a fuel cell stack. The hydrogen generator includes a container, and a liquid reactant storage area configured to contain a liquid including a first reactant. The hydrogen generator also includes a reaction area within the container, and a solid containing a second reactant within the reaction area and having a concentration gradient that varies along an axis such as length of the solid. The hydrogen generator further includes a liquid delivery member for delivering the liquid to the solid in the reaction area to generate hydrogen. The concentration gradient controls a reaction rate of the first and second reactants.
1. A hydrogen generator comprising:
a container;
a liquid reactant storage area configured to contain a liquid comprising a first reactant;
a reaction area within the container;
a solid containing a second reactant within the reaction area and comprising a concentration gradient that varies along an axis of the solid; and
a liquid delivery member for delivering the liquid to the solid in the reaction area to generate hydrogen, wherein the concentration gradient controls a reaction rate of the first and second reactants,
wherein the liquid delivery member comprises a liquid distribution portion having a plurality of liquid outlets, and
wherein the liquid distribution portion has first and second ends, and a liquid flow outlet greater at the first end than the second end, wherein the concentration gradient has a reactant concentration that is lowest at the first end and higher at the second end.
2. The hydrogen generator of claim 1 , wherein the solid comprises an acid having an acid concentration that varies along the axis of the solid to provide the concentration gradient.
3. The hydrogen generator of claim 1 , wherein the solid comprises a catalyst, wherein the catalyst varies along the axis of the solid to provide the concentration gradient.
4. The hydrogen generator of claim 1 , wherein the solid comprises a hydrophilic material that varies along the axis of the solid to provide the concentration gradient.
5. The hydrogen generator of claim 1 , wherein the solid has at least one of density or porosity that varies along the axis of the solid to provide the concentration gradient.
6. The hydrogen generator of claim 1 , wherein the solid comprises a first portion having a first reactant concentration and a second portion comprising a second reactant concentration, and wherein the first reactant concentration is different than the second reactant concentration.
7. The hydrogen generator of claim 6 , wherein the first portion is closer to an inlet of the liquid delivery member and the second portion is closer to a distal outlet of the liquid delivery member.
8. The hydrogen generator of claim 7 further comprising a third portion having a third reactant concentration and a fourth portion having a fourth reactant concentration.
9. The hydrogen generator of claim 1 , wherein the axis is along a length of the solid.
10. The hydrogen generator of claim 1 , wherein the solid is a solid body comprising one or more pellets.
11. The hydrogen generator of claim 1 , wherein the second reactant comprises sodium borohydride and the first reactant includes water.
12. The hydrogen generator of claim 1 , wherein the liquid reactant storage area is contained within the container.
13. The hydrogen generator of claim 1 further comprising a hydrogen outlet for outputting the generated hydrogen.