Devices comprising coated semiconductor nanocrystal heterostructures
View Patent ↗A semiconductor nanocrystal heterostructure has a core of a first semiconductor material surrounded by an overcoating of a second semiconductor material. Upon excitation, one carrier can be substantially confined to the core and the other carrier can be substantially confined to the overcoating.
1. A nanocrystal having a type II heterostructure, comprising a core of a first semiconductor material surrounded by a shell of a second semiconductor material and a second shell of a third semiconductor material, wherein the first semiconductor material and the second semiconductor materials are selected so that upon excitation both charge carriers of an exciton are not confined in one semiconductor material and a surface of the nanocrystal includes an organic layer.
2. A nanocrystal in accordance with claim 1 wherein one carrier is confined to the core, while the other is mostly confined to the shell.
3. A nanocrystal in accordance with claim 1 wherein photoluminescence emission from the nanocrystal occurs at a longer wavelength than photoluminescent emission from the core without the shell.
4. A nanocrystal in accordance with claim 1 wherein photoluminescence emission from the nanocrystal occurs at a longer wavelength than photoluminescent emission from a nanocrystal core comprising the first semiconductor material without a nanocrystal shell.
5. A nanocrystal in accordance with claim 1 wherein photoluminescence emission from the nanocrystal occurs at a longer wavelength than photoluminescent emission from a nanocrystal core comprising the second semiconductor material without a nanocrystal shell.
6. A nanocrystal in accordance with claim 1 wherein emission from the nanocrystal originates from radiative recombination of the carriers across the core-shell interface.
7. A device comprising the nanocrystal of claim 1 .