Particles slurried in oil for viscoelastic surfactant gelled fluids
View Patent ↗Fluids viscosified with viscoelastic surfactants (VESs) may have their fluid loss properties improved with the presence of at least one mineral oil slurried together in combination with at least one particulate fluid loss control agent that may be an alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof. The mineral oil having the particulate fluid loss control agents slurried within it may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the slurry is added to the fluid after it has been substantially gelled. The mineral oil/particulate slurry may enhance the ability of a particulate fluid loss control agent to reduce fluid loss. The presence of the mineral oil may also eventually reduce the viscosity of the VES-gelled aqueous fluid.
1. An aqueous fluid comprising:
water;
about 0.5 to about 25% by volume, based on the total aqueous fluid, of at least one amine oxide viscoelastic surfactant (VES) in an amount effective to increase the viscosity of the aqueous fluid; and
based on the total aqueous fluid, from about 0.1 to about 200 pounds per thousand gallons (pptg) (about 0.012 to about 24 kg/m 3 ) of at least one particulate fluid loss control agent slurried in from about 0.2 to about 10% by volume (bv) of at least one mineral oil fluid loss control agent to give a slurry of microscopic oil droplets dispersed in the water, where all of the particulate fluid loss control agent is coated by the mineral oil in an amount effective to reduce fluid loss of the aqueous fluid, where the at least one mineral oil fluid loss control agent has a dynamic viscosity greater than 20 cps at ambient temperature, and where the at least one particulate fluid loss control agent is present in an amount effective to reduce fluid loss of the aqueous fluid, where the at least one particulate fluid loss control agent is selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof, where the at least one particulate fluid loss control agent has a particle size equal to or less than about 0.2 millimeter,
where the slurried fluid loss control agents are present in amounts effective to synergistically reduce the viscosity of the gelled aqueous fluid as compared to using the mineral oil fluid loss control agent or the particulate fluid loss control agents independently.
2. The aqueous fluid of claim 1 where the at least one mineral oil fluid loss control agent is at least about 99 wt % paraffin.
3. The aqueous fluid of claim 1 where the at least one mineral oil fluid loss control agent has a distillation temperature above about 300° C.
4. An aqueous fluid comprising:
water;
about 1 to about 10% by volume, based on the total aqueous fluid, of at least one amine oxide viscoelastic surfactant (VES) in an amount effective to increase the viscosity of the aqueous fluid; and
from about 1 to about 40 pptg (from about 0.12 to about 4.8 kg/m 3 ) based on the total fluid of at least one particulate fluid loss control agent slurried in from about 0.4 to about 2% bv based on the total fluid of at least one mineral oil fluid loss control agent to give a slurry of microscopic oil droplets dispersed in the water, where all of the particulate fluid loss control agent is coated by the mineral oil, and where the at least one mineral oil fluid loss control agent has a dynamic viscosity greater than 20 cps at ambient temperature, and where the at least one particulate fluid loss control agent is selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof, where the at least one particulate fluid loss control agent has a particle size equal to or less than about 0.2 millimeter,
where the slurried fluid loss control agents are present in amounts effective to synergistically reduce the viscosity of the gelled aqueous fluid as compared to using the mineral oil fluid loss control agent or the particulate fluid loss control agents independently.
5. The aqueous fluid of claim 4 where the at least one mineral oil fluid loss control agent is at least about 99 wt % paraffin.
6. The aqueous fluid of claim 4 where the at least one mineral oil fluid loss control agent has a distillation temperature above about 300° C.
7. An aqueous fluid comprising:
water;
about 1 to about 10% by volume, based on the total aqueous fluid, of at least one amine oxide viscoelastic surfactant (VES) in an amount effective to increase the viscosity of the aqueous fluid;
from about 1 to about 40 pptg (from about 0.12 to about 4.8 kg/m 3 ) based on the total fluid of at least one particulate fluid loss control agent slurried in from about 0.1 to about 5% bv based on the total fluid of at least one mineral oil fluid loss control agent to give a slurry of microscopic oil droplets dispersed in the water, where all of the particulate fluid loss control agent is coated by the mineral oil, and where the at least one mineral oil fluid loss control agent has a dynamic viscosity greater than 20 cps at ambient temperature is at least about 99 wt % paraffin, and has a distillation temperature above about 300° C., and where the at least one particulate fluid loss control agent is selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof, where the at least one particulate fluid loss control agent has a particle size equal to or less than about 0.2 millimeter, and
an absence of a slurry of MgO in propylene glycol;
where the slurried fluid loss control agents are present in amounts effective to synergistically reduce the viscosity of the gelled aqueous fluid as compared to using the mineral oil fluid loss control agent or the particulate fluid loss control agents independently.