Method of controlling the amount of Cu doping when forming a back contact of a photovoltaic cell
View Patent ↗Methods for preparing an exposed surface of a p-type absorber layer of a p-n junction for coupling to a back contact in the manufacture of a thin film photovoltaic device are provided. The method can include: applying a treatment solution onto the exposed surface defined by the p-type absorber layer of cadmium telluride; and annealing the device with the p-type absorber layer in contact with the treatment solution to form a tellurium-enriched region in the p-type absorber layer at the exposed surface. The treatment solution comprises a chlorinated compound component that is substantially free from copper, a copper-containing metal salt, and a solvent.
1. A method of preparing an exposed surface of a p-type absorber layer of a p-n junction for coupling to a back contact in the manufacture of a thin film photovoltaic device, the method comprising:
applying a treatment solution onto the exposed surface defined by the p-type absorber layer, wherein the p-type absorber layer comprises cadmium telluride, and wherein the treatment solution comprises a chlorinated compound component, a copper-containing metal salt, and a solvent, wherein the chlorinated compound component is substantially free from copper and comprises a mixture of a first chlorinated salt and a second chlorinated salt, wherein the second chlorinated salt has a different chemical composition than the first chlorinated salt; and,
annealing the device at a temperature of about 45° C. to about 250° C. with the p-type absorber layer in contact with the treatment solution to simultaneously form a tellurium-enriched region in the p-type absorber layer at the exposed surface and a copper-telluride phase in the tellurium enriched region.
2. The method as in claim 1 , further comprising:
after annealing, directly coupling a back contact to the tellurium-enriched region.
3. The method as in claim 2 , wherein the back contact is applied without any additional copper treatment to the p-type absorber layer.
4. The method as in claim 2 , further comprising:
prior to applying the treatment solution on the exposed surface, annealing the p-type absorber layer in the presence of cadmium chloride; and,
washing the exposed surface to remove any cadmium oxide formed thereon.
5. The method as in claim 4 , wherein washing the exposed surface is achieved with ethylenediamine.
6. The method as in claim 2 , wherein the back contact comprises a metal or an inert graphite, and wherein the back contact is substantially free from a chemically active graphite.
7. The method as in claim 2 , wherein the back contact is applied without any additional etchant applied to the exposed surface of the p-type absorber layer.
8. The method as in claim 1 , wherein the copper containing metal salt is in the treatment solution at a concentration of about 0.001 g/L to about 10 g/L.
9. The method as in claim 1 , wherein the copper containing metal salt is in the treatment solution at a concentration of about 0.01 g/L to about 1 g/L.
10. The method as in claim 1 , wherein the chlorinated compound component is in the treatment solution at a concentration of about 10 g/L to about 1000 g/L.
11. The method as in claim 1 , wherein the chlorinated compound component is in the treatment solution at a concentration of about 25 g/L to about 500 g/L.
12. The method as in claim 1 , wherein the treatment solution includes the chlorinated compound component and the copper-containing metal salt at a weight ratio of about 100 to about 10,000 by weight.
13. The method as in claim 1 , wherein the treatment solution is acidic and has a pH of about 0 up to 7.
14. The method as in claim 1 , wherein the chlorinated compound component comprises ZnCl 2 , CdCl 2 , MnCl 2 , SbCl 2 , CaCl 2 , MgCl 2 , NaCl, KCl, RbCl, BeCl 2 , SrCl 2 , BaCl 2 , AsCl 3 , BiCl 3 , or a mixture thereof.
15. The method as in claim 1 , wherein the chlorinated compound component comprises a mixture of a first chlorinated salt, a second chlorinated salt, and a third chlorinated salt, wherein the each of the first chlorinated salt, the second chlorinated salt, and the third chlorinated salt has a different chemical composition.
16. The method as in claim 1 , wherein the copper-containing metal salt comprises a copper halide, a copper acetate, a copper-sulfur compound, or a mixture thereof.
17. The method as in claim 1 , wherein the copper-containing metal salt comprises a copper halide selected from the group consisting of CuF 2 , CuCl 2 , CuBr 2 , CuI 2 , and mixtures thereof.
18. The method as in claim 1 , wherein the chlorinated compound component comprises ZnCl 2 , CdCl 2 , MnCl 2 , or a mixture thereof, and wherein the copper copper-containing metal salt comprises a copper halide.
19. The method as in claim 1 , wherein annealing the device comprises heating the device to a temperature of about 45° C. to about 250° C. for about 0.5 minutes to about 60 minutes.