Positive electrode material
View Patent ↗A positive-electrode material includes lithium vanadium phosphate particles having an average primary particle diameter from 0.3 μm to 2.6 μm and crystallite sizes from 24 nm to 33 nm. The lithium vanadium phosphate particles are coated with a conductive carbon of a range of 0.5 mass % to 2.4 mass % with respect to a total lithium vanadium phosphate particles.
1. A positive-electrode material comprising:
lithium vanadium phosphate particles, an average primary particle diameter of which is 0.3 μm or more and 2.6 μm or less, and crystallite sizes of which are 24 nm or more and 33 nm or less,
wherein a crystallization degree of the lithium vanadium phosphate particles is 98% or more, and
wherein the lithium vanadium phosphate particles are coated with a conductive carbon of a range of 0.5 mass % to 2.4 mass % with respect to a total mass of the lithium vanadium phosphate particles.
2. The positive-electrode material according to claim 1 , wherein the lithium vanadium phosphate particles have an average primary particle diameter of from 0.35 μm to 2.0 μm, and crystallite sizes of 26.5 nm to 30 nm, and wherein the lithium vanadium phosphate particles are coated with a conductive carbon in the range of 0.6 mass % to 1.8 mass % with respect to a total mass of the lithium vanadium phosphate particles.
3. The positive-electrode material according to claim 1 , wherein the lithium vanadium phosphate is expressed as Li x V 2-y M y (PO 4 ) z ,
wherein M is one or more selected from a group formed by Fe, Co, Mn, Cu, Zn, Al, Sn, B, Ga, Cr, V, Ti, Mg, Ca, Sr, and Zr, and
wherein a relation of x, y and z satisfies 1≦x≦3, 0≦y<2, and 2≦z≦3.
4. The positive-electrode material according to claim 1 , wherein the lithium vanadium phosphate is Li 3 V 2 (PO 4 ) 3 .
5. The battery according to claim 3 , wherein the lithium vanadium phosphate is expressed as Li 3 V 2 (PO 4 ) 3 .
6. A lithium-ion secondary battery comprising:
a positive-electrode including the positive-electrode material according to claim 1 ;
a negative-electrode; and
a non-aqueous electrolyte.
7. The battery according to claim 6 , wherein the lithium vanadium phosphate is expressed as Li 3 V 2 (PO 4 ) 3 .
8. The battery according to claim 6 , wherein the lithium vanadium phosphate is expressed as Li x V 2-y M y (PO 4 ) z ,
wherein M is one or more selected from a group formed by Fe, Co, Mn, Cu, Zn, Al, Sn, B, Ga, Cr, V, Ti, Mg, Ca, Sr, and Zr, and
wherein a relation of x, y and z satisfies 1≦x≦3, 0≦y<2, and 2≦z≦3.
9. The battery according to claim 6 , wherein the lithium vanadium phosphate particles have an average primary particle diameter of from 0.35 μm to 2.0 μm, and crystallite sizes of 26.5 nm to 30 nm, and wherein the lithium vanadium phosphate particles are coated with a conductive carbon in the range of 0.6 mass % to 1.8 mass % with respect to a total mass of the lithium vanadium phosphate particles.