Ink containing anthraquinone based dye, dye used in the ink, and display
View Patent ↗An object of the present invention is to provide an anthraquinone based dye having excellent solubility in a low polar solvent and having high absorption coefficient and high light resistance and an ink containing the same. The present invention relates to an ink comprising a specific anthraquinone based dye.
1. An ink comprising an anthraquinone based dye represented by the following general formula (I) and a low polar solvent:
wherein X represents a COOR 3 group; and each of R 1 to R 3 independently represents an optionally substituted alkyl group having a carbon number of from 1 to 20, provided that at least one of R 1 to R 3 is an optionally substituted branched-chain alkyl group having a carbon number of from 4 to 20, and the anthraquinone ring may have an arbitrary substituent other than X, NHR 1 , and NHR 2 .
2. The ink according to claim 1 , wherein the low polar solvent has a specific dielectric constant of not more than 2.2.
3. The ink according to claim 1 , wherein the low polar solvent includes one or more members selected from the group consisting of hydrocarbon based solvents, fluorocarbon based solvents, and silicone oils.
4. The ink according to claim 1 , wherein the anthraquinone based dye is a dye represented by the following general formula (II):
wherein X 2 represents COOR 23 ; each of R 21 and R 22 independently represents an optionally substituted branched-chain alkyl group having a carbon number of from 4 to 20; and R 23 represents an optionally substituted alkyl group having a carbon number of from 1 to 20.
5. The ink according to claim 1 , wherein in the anthraquinone based dye, when the dye is dissolved in n-decane, an absorption maximum wavelength in a wavelength region of from 350 to 750 nm falls within the range of from 600 to 720 nm, and a product εC of a molar absorption coefficient ε (L mole −1 cm −1 ) at the absorption maximum wavelength and a concentration C (mole L −1 ) of a saturated solution with the same solvent at room temperature (25° C.) is 500 (cm −1 ) or more.
6. The ink according to claim 1 , which is for a display or optical shutter.
7. The ink according to claim 1 , wherein a viscosity of the low polar solvent is 1.0 cP or more and 10.00 cP or less at 30° C.
8. The ink according to claim 1 , wherein a surface tension of the low polar solvent is 5 mN·m −1 or more and 50 mN·m −1 or less.
9. A display, which comprises a display portion containing the ink according to claim 1 , and which displays an image by controlling voltage impression in the display portion.
10. The display according to claim 9 , wherein the display portion contains electrophoretic particles or an aqueous medium.
11. The display according to claim 9 , wherein the image is displayed by changing a colored state by the voltage impression.
12. The display according to claim 9 , wherein the image is displayed by an electrowetting system or an electrophoresis system.
13. An electronic paper comprising the display according to claim 9 .